Mineral insulated skin effect heating cable

ABSTRACT

Certain embodiments provide a heater. A heater device includes a skin effect component having at least one insulated electrical core conductor in electrical communication with an adjacent and substantially parallel, elongated ferromagnetic shape having a reduction and localization of the depth and width of the effective conductor path in the cross-section of the ferromagnetic wall; and, an inorganic ceramic insulation component.

PRIORITY CLAIM

This application is a continuation of U.S. patent application Ser. No.11/112,881 entitled “TEMPERATURE LIMITED HEATERS WITH HIGH POWERFACTORS” to Vinegar et al., filed Apr. 22, 2005, now U.S. Pat. No.8,355,623 to Vinegar et al., issued Jan. 26, 2013, which claims priorityto Provisional Patent Application No. 60/565,077 entitled “THERMALPROCESSES FOR SUBSURFACE FORMATIONS” to Vinegar et al. filed on Apr. 23,2004.

RELATED PATENTS

This patent application incorporates by reference in its entirety eachof U.S. Pat. Nos. 6,688,387 to Wellington et al.; 6,698,515 to Karanikaset al.; 6,880,633 to Wellington et al.; 6,782,947 to de Rouffignac etal. 6,991,036 to Sumnu-Dindoruk et al.; 7,066,257 to Wellington et al.;7,121,342 to Vinegar et al.; and 8,200,072 to Vinegar et al.

BACKGROUND

1. Field of the Invention

The present invention relates generally to methods and systems forproduction of hydrocarbons, hydrogen, and/or other products from varioussubsurface formations such as hydrocarbon containing formations.

2. Description of Related Art

Hydrocarbons obtained from subterranean (e.g., sedimentary) formationsare often used as energy resources, as feedstocks, and as consumerproducts. Concerns over depletion of available hydrocarbon resources andconcerns over declining overall quality of produced hydrocarbons haveled to development of processes for more efficient recovery, processingand/or use of available hydrocarbon resources. In situ processes may beused to remove hydrocarbon materials from subterranean formations.Chemical and/or physical properties of hydrocarbon material in asubterranean formation may need to be changed to allow hydrocarbonmaterial to be more easily removed from the subterranean formation. Thechemical and physical changes may include in situ reactions that produceremovable fluids, composition changes, solubility changes, densitychanges, phase changes, and/or viscosity changes of the hydrocarbonmaterial in the formation. A fluid may be, but is not limited to, a gas,a liquid, an emulsion, a slurry, and/or a stream of solid particles thathas flow characteristics similar to liquid flow.

A wellbore may be formed in a formation. In some embodiments wellboresmay be formed using reverse circulation drilling methods. Reversecirculation methods are suggested, for example, in published U.S. PatentApplication Publication Nos. 2003-0173088 to Livingstone, 2004-0104030to Livingstone, 2004-0079553 to Livingstone, and U.S. Pat. Nos.6,854,534 to Livingstone, and 4,823,890 to Lang, the disclosures ofwhich are incorporated herein by reference. Reverse circulation methodsgenerally involve circulating a drilling fluid to a drilling bit throughan annulus between concentric tubulars to the borehole in the vicinityof the drill bit, and then through openings in the drill bit and to thesurface through the center of the concentric tubulars, with cuttingsfrom the drilling being carried to the surface with the drilling fluidrising through the center tubular. A wiper or shroud may be providedabove the drill bit and above a point where the drilling fluid exits theannulus to prevent the drilling fluid from mixing with formation fluids.The drilling fluids may be, but is not limited to, air, water, brinesand/or conventional drilling fluids.

In some embodiments, a casing or other pipe system may be placed orformed in a wellbore. U.S. Pat. No. 4,572,299 issued to Van Egmond etal., which is incorporated by reference as if fully set forth herein,describes spooling an electric heater into a well. In some embodiments,components of a piping system may be welded together. Quality of formedwells may be monitored by various techniques. In some embodiments,quality of welds may be inspected by a hybrid electromagnetic acoustictransmission technique known as EMAT. EMAT is described in U.S. Pat.Nos. 5,652,389 to Schaps et al.; 5,760,307 to Latimer et al.; 5,777,229to Geier et al.; and 6,155,117 to Stevens et al., each of which isincorporated by reference as if fully set forth herein.

In some embodiments, an expandable tubular may be used in a wellbore.Expandable tubulars are described in U.S. Pat. Nos. 5,366,012 toLohbeck, and 6,354,373 to Vercaemer et al., each of which isincorporated by reference as if fully set forth herein.

Heaters may be placed in wellbores to heat a formation during an in situprocess. Examples of in situ processes utilizing downhole heaters areillustrated in U.S. Pat. Nos. 2,634,961 to Ljungstrom; 2,732,195 toLjungstrom; 2,780,450 to Ljungstrom; 2,789,805 to Ljungstrom; 2,923,535to Ljungstrom; and 4,886,118 to Van Meurs et al.; each of which isincorporated by reference as if fully set forth herein.

Application of heat to oil shale formations is described in U.S. Pat.Nos. 2,923,535 to Ljungstrom and 4,886,118 to Van Meurs et al. Heat maybe applied to the oil shale formation to pyrolyze kerogen in the oilshale formation. The heat may also fracture the formation to increasepermeability of the formation. The increased permeability may allowformation fluid to travel to a production well where the fluid isremoved from the oil shale formation. In some processes disclosed byLjungstrom, for example, an oxygen containing gaseous medium isintroduced to a permeable stratum, preferably while still hot from apreheating step, to initiate combustion.

A heat source may be used to heat a subterranean formation. Electricheaters may be used to heat the subterranean formation by radiationand/or conduction. An electric heater may resistively heat an element.U.S. Pat. No. 2,548,360 to Germain, which is incorporated by referenceas if fully set forth herein, describes an electric heating elementplaced in a viscous oil in a wellbore. The heater element heats andthins the oil to allow the oil to be pumped from the wellbore. U.S. Pat.No. 4,716,960 to Eastlund et al., which is incorporated by reference asif fully set forth herein, describes electrically heating tubing of apetroleum well by passing a relatively low voltage current through thetubing to prevent formation of solids. U.S. Pat. No. 5,065,818 to VanEgmond, which is incorporated by reference as if fully set forth herein,describes an electric heating element that is cemented into a wellborehole without a casing surrounding the heating element.

U.S. Pat. No. 6,023,554 to Vinegar et al., which is incorporated byreference as if fully set forth herein, describes an electric heatingelement that is positioned in a casing. The heating element generatesradiant energy that heats the casing. A granular solid fill material maybe placed between the casing and the formation. The casing mayconductively heat the fill material, which in turn conductively heatsthe formation.

U.S. Pat. No. 4,570,715 to Van Meurs et al., which is incorporated byreference as if fully set forth herein, describes an electric heatingelement. The heating element has an electrically conductive core, asurrounding layer of insulating material, and a surrounding metallicsheath. The conductive core may have a relatively low resistance at hightemperatures. The insulating material may have electrical resistance,compressive strength, and heat conductivity properties that arerelatively high at high temperatures. The insulating layer may inhibitarcing from the core to the metallic sheath. The metallic sheath mayhave tensile strength and creep resistance properties that arerelatively high at high temperatures.

U.S. Pat. No. 5,060,287 to Van Egmond, which is incorporated byreference as if fully set forth herein, describes an electrical heatingelement having a copper-nickel alloy core.

Obtaining permeability in an oil shale formation (e.g., betweeninjection and production wells) tends to be difficult because oil shaleis often substantially impermeable. Many methods have attempted to linkinjection and production wells. These methods include: hydraulicfracturing such as methods investigated by Dow Chemical and LaramieEnergy Research Center; electrical fracturing (e.g., by methodsinvestigated by Laramie Energy Research Center); acid leaching oflimestone cavities (e.g., by methods investigated by Dow Chemical);steam injection into permeable nahcolite zones to dissolve the nahcolite(e.g., by methods investigated by Shell Oil and Equity Oil); fracturingwith chemical explosives (e.g., by methods investigated by Talley EnergySystems); fracturing with nuclear explosives (e.g., by methodsinvestigated by Project Bronco); and combinations of these methods. Manyof these methods, however, have relatively high operating costs and lacksufficient injection capacity.

Large deposits of heavy hydrocarbons (e.g., heavy oil and/or tar)contained in relatively permeable formations (e.g., in tar sands) arefound in North America, South America, Africa, and Asia. Tar can besurface-mined and upgraded to lighter hydrocarbons such as crude oil,naphtha, kerosene, and/or gas oil. Surface milling processes may furtherseparate the bitumen from sand. The separated bitumen may be convertedto light hydrocarbons using conventional refinery methods. Mining andupgrading tar sand is usually substantially more expensive thanproducing lighter hydrocarbons from conventional oil reservoirs.

In situ production of hydrocarbons from tar sand may be accomplished byheating and/or injecting a gas into the formation. U.S. Pat. Nos.5,211,230 to Ostapovich et al. and 5,339,897 to Leaute, which areincorporated by reference as if fully set forth herein, describe ahorizontal production well located in an oil-bearing reservoir. Avertical conduit may be used to inject an oxidant gas into the reservoirfor in situ combustion.

U.S. Pat. No. 2,780,450 to Ljungstrom describes heating bituminousgeological formations in situ to convert or crack a liquid tar-likesubstance into oils and gases.

U.S. Pat. No. 4,597,441 to Ware et al., which is incorporated byreference as if fully set forth herein, describes contacting oil, heat,and hydrogen simultaneously in a reservoir. Hydrogenation may enhancerecovery of oil from the reservoir.

U.S. Pat. Nos. 5,046,559 to Glandt and 5,060,726 to Glandt et al., whichare incorporated by reference as if fully set forth herein, describepreheating a portion of a tar sand formation between an injector welland a producer well. Steam may be injected from the injector well intothe formation to produce hydrocarbons at the producer well.

As outlined above, there has been a significant amount of effort todevelop methods and systems to economically produce hydrocarbons,hydrogen, and/or other products from hydrocarbon containing formations.At present, however, there are still many hydrocarbon containingformations from which hydrocarbons, hydrogen, and/or other productscannot be economically produced. Thus, there is still a need forimproved methods and systems for production of hydrocarbons, hydrogen,and/or other products from various hydrocarbon containing formations.

SUMMARY

Embodiments described herein generally relate to systems, methods, andheaters for treating a subsurface formation. Embodiments describedherein also generally relate to heaters that have novel componentstherein. Such heaters can be obtained by using the systems and methodsdescribed herein.

In certain embodiments, the invention provides one or more systems,methods, and/or heaters. In some embodiments, the systems, methods,and/or heaters are used for treating a subsurface formation.

In certain embodiments, the invention provides a heater, including: aferromagnetic member; an electrical conductor electrically coupled tothe ferromagnetic member, the electrical conductor configured to conducta majority of time-varying electrical current passing through the heaterat about 25° C.; and wherein the heater is configured to provide a firstheat output below the Curie temperature of the ferromagnetic member, andthe heater is configured to automatically provide a second heat outputapproximately at and above the Curie temperature of the ferromagneticmember, the second heat output being reduced compared to the first heatoutput.

In certain embodiments, the invention provides a heater, including: aferromagnetic member; an electrical conductor electrically coupled tothe ferromagnetic member; wherein the heater is configured to provide afirst heat output below the Curie temperature of the ferromagneticmember when time-varying electrical current is applied to the heater,and the heater is configured to automatically provide a second heatoutput approximately at and above the Curie temperature of theferromagnetic member, the second heat output being reduced compared tothe first heat output; and wherein the ferromagnetic member and theelectrical conductor are electrically coupled such that a power factorof the heater remains above 0.85 during use of the heater.

In certain embodiments, the invention provides a method for heating,including: applying electrical current to a heater section to provide anelectrically resistive heat output, the heater section including anelectrical conductor electrically coupled to a ferromagnetic member, theelectrical conductor configured to conduct a majority of the electricalcurrent passing through the cross section of the heater section at about25° C.; providing a first heat output when electrical current is appliedto the heater section below a selected temperature; providing a secondheat output approximately at and above the selected temperature duringuse, the second heat output being reduced compared to the first heatoutput; and allowing heat to transfer from the heater section.

In further embodiments, features from specific embodiments may becombined with features from other embodiments. For example, featuresfrom one embodiment may be combined with features from any of the otherembodiments.

In further embodiments, treating a subsurface formation is performedusing any of the methods, systems, or heaters described herein.

In further embodiments, additional features may be added to the specificembodiments described herein.

BRIEF DESCRIPTION OF THE DRAWINGS

Advantages of the present invention may become apparent to those skilledin the art with the benefit of the following detailed description andupon reference to the accompanying drawings in which:

FIG. 1 depicts an illustration of stages of heating a hydrocarboncontaining formation.

FIG. 2 depicts a diagram that presents several properties of kerogenresources.

FIG. 3 shows a schematic view of an embodiment of a portion of an insitu conversion system for treating a hydrocarbon containing formation.

FIG. 4 depicts a schematic representation of an embodiment of a systemfor producing pipeline gas.

FIG. 5 depicts a schematic representation of an embodiment of amagnetostatic drilling operation.

FIG. 6 depicts an embodiment of a section of a conduit with two magnetsegments.

FIG. 7 depicts a schematic of a portion of a magnetic string.

FIG. 8 depicts an embodiment of a freeze well for a circulated liquidrefrigeration system, wherein a cutaway view of the freeze well isrepresented below ground surface.

FIG. 9 depicts a schematic representation of an embodiment of arefrigeration system for forming a low temperature zone around atreatment area.

FIG. 10 depicts a schematic representation of a double barriercontainment system.

FIG. 11 depicts a cross-sectional view of a double barrier containmentsystem.

FIG. 12 depicts a schematic representation of a breach in the firstbarrier of a double barrier containment system.

FIG. 13 depicts a schematic representation of a breach in the secondbarrier of a double barrier containment system.

FIG. 14 depicts a schematic representation of a fiber optic cable systemused to monitor temperature in and near freeze wells.

FIG. 15 depicts a schematic view of a well layout including heatinterceptor wells.

FIG. 16 depicts a schematic representation of an embodiment of adiverter device in the production well.

FIG. 17 depicts a schematic representation of an embodiment of thebaffle in the production well.

FIG. 18 depicts a schematic representation of an embodiment of thebaffle in the production well.

FIG. 19 depicts an embodiment for providing a controlled explosion in anopening.

FIG. 20 depicts an embodiment of an opening after a controlled explosionin the opening.

FIG. 21 depicts an embodiment of a liner in the opening.

FIG. 22 depicts an embodiment of the liner in a stretched configuration.

FIG. 23 depicts an embodiment of the liner in an expanded configuration.

FIG. 24 depicts an embodiment of an apparatus for forming a compositeconductor, with a portion of the apparatus shown in cross section.

FIG. 25 depicts a cross-sectional representation of an embodiment of aninner conductor and an outer conductor formed by a tube-in-tube millingprocess.

FIGS. 26, 27, and 28 depict cross-sectional representations of anembodiment of a temperature limited heater with an outer conductorhaving a ferromagnetic section and a non-ferromagnetic section.

FIGS. 29, 30, 31, and 32 depict cross-sectional representations of anembodiment of a temperature limited heater with an outer conductorhaving a ferromagnetic section and a non-ferromagnetic section placedinside a sheath.

FIGS. 33, 34, and 35 depict cross-sectional representations of anembodiment of a temperature limited heater with a ferromagnetic outerconductor.

FIGS. 36, 37, and 38 depict cross-sectional representations of anembodiment of a temperature limited heater with an outer conductor.

FIGS. 39, 40, 41, and 42 depict cross-sectional representations of anembodiment of a temperature limited heater.

FIGS. 43, 44, and 45 depict cross-sectional representations of anembodiment of a temperature limited heater with an overburden sectionand a heating section.

FIGS. 46A and 46B depict cross-sectional representations of anembodiment of a temperature limited heater.

FIGS. 47A and 47B depict cross-sectional representations of anembodiment of a temperature limited heater.

FIGS. 48A and 48B depict cross-sectional representations of anembodiment of a temperature limited heater.

FIGS. 49A and 49B depict cross-sectional representations of anembodiment of a temperature limited heater.

FIGS. 50A and 50B depict cross-sectional representations of anembodiment of a temperature limited heater.

FIGS. 51A and 51B depict cross-sectional representations of anembodiment of a temperature limited heater.

FIG. 52 depicts an embodiment of a coupled section of a compositeelectrical conductor.

FIG. 53 depicts an end view of an embodiment of a coupled section of acomposite electrical conductor.

FIG. 54 depicts an embodiment for coupling together sections of acomposite electrical conductor.

FIG. 55 depicts a cross-sectional representation of an embodiment of acomposite conductor with a support member.

FIG. 56 depicts a cross-sectional representation of an embodiment of acomposite conductor with a support member separating the conductors.

FIG. 57 depicts a cross-sectional representation of an embodiment of acomposite conductor surrounding a support member.

FIG. 58 depicts a cross-sectional representation of an embodiment of acomposite conductor surrounding a conduit support member.

FIG. 59 depicts a cross-sectional representation of an embodiment of aconductor-in-conduit heat source.

FIG. 60 depicts a cross-sectional representation of an embodiment of aremovable conductor-in-conduit heat source.

FIG. 61 depicts an embodiment of a sliding connector.

FIG. 62A depicts an embodiment of contacting sections for aconductor-in-conduit heater.

FIG. 62B depicts an aerial view of the upper contact section of theconductor-in-conduit heater in FIG. 62A.

FIG. 63 depicts an embodiment of a fiber optic cable sleeve in aconductor-in-conduit heater.

FIG. 64 depicts an embodiment of a conductor-in-conduit temperaturelimited heater.

FIG. 65A and FIG. 65B depict an embodiment of an insulated conductorheater.

FIG. 66A and FIG. 66B depict an embodiment of an insulated conductorheater.

FIG. 67 depicts an embodiment of an insulated conductor located inside aconduit.

FIG. 68 depicts an embodiment of a temperature limited heater in whichthe support member provides a majority of the heat output below theCurie temperature of the ferromagnetic conductor.

FIGS. 69 and 70 depict embodiments of temperature limited heaters inwhich the jacket provides a majority of the heat output below the Curietemperature of the ferromagnetic conductor.

FIG. 71 depicts a high temperature embodiment of a temperature limitedheater.

FIG. 72 depicts hanging stress versus outside diameter for thetemperature limited heater shown in FIG. 68 with 347H as the supportmember.

FIG. 73 depicts hanging stress versus temperature for several materialsand varying outside diameters of the temperature limited heater.

FIGS. 74, 75, and 76 depict examples of embodiments for temperaturelimited heaters that vary the materials of the support member along thelength of the heaters to provide desired operating properties andsufficient mechanical properties.

FIGS. 77 and 78 depict examples of embodiments for temperature limitedheaters that vary the diameter and/or materials of the support memberalong the length of the heaters to provide desired operating propertiesand sufficient mechanical properties.

FIGS. 79A and 79B depict cross-sectional representations of anembodiment of a temperature limited heater component used in aninsulated conductor heater.

FIGS. 80A and 80B depict an embodiment for installing heaters in awellbore.

FIGS. 81A and 81B depict an embodiment of a three conductor-in-conduitheater.

FIG. 82 depicts an embodiment of a temperature limited heater with a lowtemperature ferromagnetic outer conductor.

FIG. 83 depicts an embodiment of a temperature limitedconductor-in-conduit heater.

FIG. 84 depicts a cross-sectional representation of an embodiment of aconductor-in-conduit temperature limited heater.

FIG. 85 depicts a cross-sectional representation of an embodiment of aconductor-in-conduit temperature limited heater.

FIG. 86 depicts a cross-sectional view of an embodiment of aconductor-in-conduit temperature limited heater.

FIG. 87 depicts a cross-sectional representation of an embodiment of aconductor-in-conduit temperature limited heater with an insulatedconductor.

FIG. 88 depicts a cross-sectional representation of an embodiment of aninsulated conductor-in-conduit temperature limited heater.

FIG. 89 depicts a cross-sectional representation of an embodiment of aninsulated conductor-in-conduit temperature limited heater.

FIG. 90 depicts a cross-sectional representation of an embodiment of aconductor-in-conduit temperature limited heater with an insulatedconductor.

FIGS. 91 and 92 depict cross-sectional views of an embodiment of atemperature limited heater that includes an insulated conductor.

FIGS. 93 and 94 depict cross-sectional views of an embodiment of atemperature limited heater that includes an insulated conductor.

FIG. 95 depicts a schematic of an embodiment of a temperature limitedheater.

FIG. 96 depicts an embodiment of an “S” bend in a heater.

FIG. 97 depicts an embodiment of a three-phase temperature limitedheater, with a portion shown in cross section.

FIG. 98 depicts an embodiment of a three-phase temperature limitedheater, with a portion shown in cross section.

FIG. 99 depicts an embodiment of temperature limited heaters coupledtogether in a three-phase configuration.

FIG. 100 depicts an embodiment of two temperature limited heaterscoupled together in a single contacting section.

FIG. 101 depicts an embodiment of two temperature limited heaters withlegs coupled in a contacting section.

FIG. 102 depicts an embodiment of two temperature limited heaters withlegs coupled in a contacting section with contact solution.

FIG. 103 depicts an embodiment of two temperature limited heaters withlegs coupled without a contactor in a contacting section.

FIG. 104 depicts an embodiment of a temperature limited heater withcurrent return through the formation.

FIG. 105 depicts a representation of an embodiment of a three-phasetemperature limited heater with current connection through theformation.

FIG. 106 depicts an aerial view of the embodiment shown in FIG. 105.

FIG. 107 depicts an embodiment of three temperature limited heaterselectrically coupled to a horizontal wellbore in the formation.

FIG. 108 depicts a representation of an embodiment of a three-phasetemperature limited heater with a common current connection through theformation.

FIG. 109 depicts an embodiment for heating and producing from aformation with a temperature limited heater in a production wellbore.

FIG. 110 depicts an embodiment for heating and producing from aformation with a temperature limited heater and a production wellbore.

FIG. 111 depicts an embodiment of a heating/production assembly that maybe located in a wellbore for gas lifting.

FIG. 112 depicts an embodiment of a heating/production assembly that maybe located in a wellbore for gas lifting.

FIG. 113 depicts another embodiment of a heating/production assemblythat may be located in a wellbore for gas lifting.

FIG. 114 depicts an embodiment of a production conduit and a heater.

FIG. 115 depicts an embodiment for treating a formation.

FIG. 116 depicts an embodiment of a dual concentric rod pump system.

FIG. 117 depicts an embodiment of a dual concentric rod pump system witha 2-phase separator.

FIG. 118 depicts an embodiment of a dual concentric rod pump system witha gas/vapor shroud and sump.

FIG. 119 depicts an embodiment of a gas lift system.

FIG. 120 depicts an embodiment of a gas lift system with an additionalproduction conduit.

FIG. 121 depicts an embodiment of a gas lift system with an injectiongas supply conduit.

FIG. 122 depicts an embodiment of a gas lift system with an additionalcheck valve.

FIG. 123 depicts an embodiment of a gas lift system that allows mixingof the gas/vapor stream into the production conduit without a separategas/vapor conduit for gas.

FIG. 124 depicts an embodiment of a gas lift system with a checkvalve/vent assembly below a packer/reflux seal assembly.

FIG. 125 depicts an embodiment of a gas lift system with concentricconduits.

FIG. 126 depicts an embodiment of a gas lift system with a gas/vaporshroud and sump.

FIG. 127 depicts an embodiment of a heater well with selective heating.

FIG. 128 depicts electrical resistance versus temperature at variousapplied electrical currents for a 446 stainless steel rod.

FIG. 129 shows resistance profiles as a function of temperature atvarious applied electrical currents for a copper rod contained in aconduit of Sumitomo HCM12A.

FIG. 130 depicts electrical resistance versus temperature at variousapplied electrical currents for a temperature limited heater.

FIG. 131 depicts raw data for a temperature limited heater.

FIG. 132 depicts electrical resistance versus temperature at variousapplied electrical currents for a temperature limited heater.

FIG. 133 depicts power versus temperature at various applied electricalcurrents for a temperature limited heater.

FIG. 134 depicts electrical resistance versus temperature at variousapplied electrical currents for a temperature limited heater.

FIG. 135 depicts data of electrical resistance versus temperature for asolid 2.54 cm diameter, 1.8 m long 410 stainless steel rod at variousapplied electrical currents.

FIG. 136 depicts data of electrical resistance versus temperature for acomposite 1.9 cm, 1.8 m long alloy 42-6 rod with a copper core (the rodhas an outside diameter to copper diameter ratio of 2:1) at variousapplied electrical currents.

FIG. 137 depicts data of power output versus temperature for a composite1.9 cm, 1.8 m long alloy 42-6 rod with a copper core (the rod has anoutside diameter to copper diameter ratio of 2:1) at various appliedelectrical currents.

FIG. 138 depicts data of electrical resistance versus temperature for acomposite 0.75″ diameter, 6 foot long Alloy 52 rod with a 0.375″diameter copper core at various applied electrical currents.

FIG. 139 depicts data of power output versus temperature for a composite10.75″ diameter, 6 foot long Alloy 52 rod with a 0.375″ diameter coppercore at various applied electrical currents.

FIG. 140 depicts data for values of skin depth versus temperature for asolid 2.54 cm diameter, 1.8 m long 410 stainless steel rod at variousapplied AC electrical currents.

FIG. 141 depicts temperature versus time for a temperature limitedheater.

FIG. 142 depicts temperature versus log time data for a 2.5 cm solid 410stainless steel rod and a 2.5 cm solid 304 stainless steel rod.

FIG. 143 depicts experimentally measured resistance versus temperatureat several currents for a temperature limited heater with a copper core,a carbon steel ferromagnetic conductor, and a stainless steel 347Hstainless steel support member.

FIG. 144 depicts experimentally measured resistance versus temperatureat several currents for a temperature limited heater with a copper core,an iron-cobalt ferromagnetic conductor, and a stainless steel 347Hstainless steel support member.

FIG. 145 depicts experimentally measured power factor versus temperatureat two AC currents for a temperature limited heater with a copper core,a carbon steel ferromagnetic conductor, and a 347H stainless steelsupport member.

FIG. 146 depicts experimentally measured turndown ratio versus maximumpower delivered for a temperature limited heater with a copper core, acarbon steel ferromagnetic conductor, and a 347H stainless steel supportmember.

FIG. 147 depicts examples of relative magnetic permeability versusmagnetic field for both the found correlations and raw data for carbonsteel.

FIG. 148 shows the resulting plots of skin depth versus magnetic fieldfor four temperatures and 400 A current.

FIG. 149 shows a comparison between the experimental and numerical(calculated) results for currents of 300 A, 400 A, and 500 A.

FIG. 150 shows the AC resistance per foot of the heater element as afunction of skin depth at 1100° F. calculated from the theoreticalmodel.

FIG. 151 depicts the power generated per unit length in each heatercomponent versus skin depth for a temperature limited heater.

FIGS. 152A-C compare the results of theoretical calculations withexperimental data for resistance versus temperature in a temperaturelimited heater.

FIG. 153 displays temperature of the center conductor of aconductor-in-conduit heater as a function of formation depth for a Curietemperature heater with a turndown ratio of 2:1.

FIG. 154 displays heater heat flux through a formation for a turndownratio of 2:1 along with the oil shale richness profile.

FIG. 155 displays heater temperature as a function of formation depthfor a turndown ratio of 3:1.

FIG. 156 displays heater heat flux through a formation for a turndownratio of 3:1 along with the oil shale richness profile.

FIG. 157 displays heater temperature as a function of formation depthfor a turndown ratio of 4:1.

FIG. 158 depicts heater temperature versus depth for heaters used in asimulation for heating oil shale.

FIG. 159 depicts heater heat flux versus time for heaters used in asimulation for heating oil shale.

FIG. 160 depicts accumulated heat input versus time in a simulation forheating oil shale.

FIG. 161 shows heater rod temperature as a function of the powergenerated within a rod.

FIG. 162 shows heater rod temperature as a function of the powergenerated within a rod.

FIG. 163 shows heater rod temperature as a function of the powergenerated within a rod.

FIG. 164 shows heater rod temperature as a function of the powergenerated within a rod.

FIG. 165 shows heater rod temperature as a function of the powergenerated within a rod.

FIG. 166 shows heater rod temperature as a function of the powergenerated within a rod.

FIG. 167 shows heater rod temperature as a function of the powergenerated within a rod.

FIG. 168 shows heater rod temperature as a function of the powergenerated within a rod.

FIG. 169 shows a plot of center heater rod temperature versus conduittemperature for various heater powers with air or helium in the annulus.

FIG. 170 shows a plot of center heater rod temperature versus conduittemperature for various heater powers with air or helium in the annulus.

FIG. 171 depicts spark gap breakdown voltages versus pressure atdifferent temperatures for a conductor-in-conduit heater with air in theannulus.

FIG. 172 depicts spark gap breakdown voltages versus pressure atdifferent temperatures for a conductor-in-conduit heater with helium inthe annulus.

FIG. 173 depicts data of leakage current measurements versus voltage foralumina and silicon nitride centralizers at selected temperatures.

FIG. 174 depicts leakage current measurements versus temperature for twodifferent types of silicon nitride.

FIG. 175 depicts a schematic representation of an embodiment of adownhole oxidizer assembly.

FIG. 176 depicts an embodiment of an ignition system positioned in across-sectional representation of an oxidizer.

FIG. 177 depicts a cross-sectional representation of an embodiment of atransitional piece of an ignition system.

FIG. 178 depicts a cross-sectional representation of an embodiment of anignition system.

FIG. 179 depicts a catalytic material proximate an oxidizer in adownhole oxidizer assembly.

FIG. 180 depicts an embodiment of a catalytic igniter system.

FIG. 181 depicts a cross-sectional representation of a portion of anoxidizer that uses a catalytic igniter system.

FIG. 182 depicts a schematic representation of a closed loop circulationsystem for heating a portion of a formation.

FIG. 183 depicts a plan view of wellbore entries and exits from aportion of a formation to be heated using a closed loop circulationsystem.

While the invention is susceptible to various modifications andalternative forms, specific embodiments thereof are shown by way ofexample in the drawings and may herein be described in detail. Thedrawings may not be to scale. It should be understood, however, that thedrawings and detailed description thereto are not intended to limit theinvention to the particular form disclosed, but on the contrary, theintention is to cover all modifications, equivalents and alternativesfalling within the spirit and scope of the present invention as definedby the appended claims.

DETAILED DESCRIPTION

The following description generally relates to systems and methods fortreating hydrocarbons in the formations. Such formations may be treatedto yield hydrocarbon products, hydrogen, and other products.

“Hydrocarbons” are generally defined as molecules formed primarily bycarbon and hydrogen atoms. Hydrocarbons may also include other elementssuch as, but not limited to, halogens, metallic elements, nitrogen,oxygen, and/or sulfur. Hydrocarbons may be, but are not limited to,kerogen, bitumen, pyrobitumen, oils, natural mineral waxes, andasphaltites. Hydrocarbons may be located in or adjacent to mineralmatrices in the earth. Matrices may include, but are not limited to,sedimentary rock, sands, silicilytes, carbonates, diatomites, and otherporous media. “Hydrocarbon fluids” are fluids that include hydrocarbons.Hydrocarbon fluids may include, entrain, or be entrained innon-hydrocarbon fluids such as hydrogen, nitrogen, carbon monoxide,carbon dioxide, hydrogen sulfide, water, and ammonia.

A “formation” includes one or more hydrocarbon containing layers, one ormore non-hydrocarbon layers, an overburden, and/or an underburden. The“overburden” and/or the “underburden” include one or more differenttypes of impermeable materials. For example, overburden and/orunderburden may include rock, shale, mudstone, or wet/tight carbonate.In some embodiments of in situ conversion processes, the overburdenand/or the underburden may include a hydrocarbon containing layer orhydrocarbon containing layers that are relatively impermeable and arenot subjected to temperatures during in situ conversion processing thatresult in significant characteristic changes of the hydrocarboncontaining layers of the overburden and/or the underburden. For example,the underburden may contain shale or mudstone, but the underburden isnot allowed to heat to pyrolysis temperatures during the in situconversion process. In some cases, the overburden and/or the underburdenmay be somewhat permeable.

“Kerogen” is a solid, insoluble hydrocarbon that has been converted bynatural degradation and that principally contains carbon, hydrogen,nitrogen, oxygen, and sulfur. Coal and oil shale are typical examples ofmaterials that contain kerogen. “Bitumen” is a non-crystalline solid orviscous hydrocarbon material that is substantially soluble in carbondisulfide. “Oil” is a fluid containing a mixture of condensablehydrocarbons.

“Formation fluids” and “produced fluids” refer to fluids removed fromthe formation and may include pyrolyzation fluid, synthesis gas,mobilized hydrocarbon, and water (steam). Formation fluids may includehydrocarbon fluids as well as non-hydrocarbon fluids. The term“mobilized fluid” refers to fluids in a hydrocarbon containing formationthat are able to flow as a result of thermal treatment of the formation.

“Thermally conductive fluid” includes fluid that has a higher thermalconductivity than air at standard temperature and pressure (STP) (0° C.and 101.325 kPa).

“Carbon number” refers to the number of carbon atoms in a molecule. Ahydrocarbon fluid may include various hydrocarbons with different carbonnumbers. The hydrocarbon fluid may be described by a carbon numberdistribution. Carbon numbers and/or carbon number distributions may bedetermined by true boiling point distribution and/or gas-liquidchromatography.

A “heat source” is any system for providing heat to at least a portionof a formation substantially by conductive and/or radiative heattransfer. For example, a heat source may include electric heaters suchas an insulated conductor, an elongated member, and/or a conductordisposed in a conduit. A heat source may also include systems thatgenerate heat by burning a fuel external to or in a formation, such assurface burners, downhole gas burners, nameless distributed combustors,and natural distributed combustors. In some embodiments, heat providedto or generated in one or more heat sources may be supplied by othersources of energy. The other sources of energy may directly heat aformation, or the energy may be applied to a transfer medium thatdirectly or indirectly heats the formation. It is to be understood thatone or more heat sources that are applying heat to a formation may usedifferent sources of energy. Thus, for example, for a given formationsome heat sources may supply heat from electric resistance heaters, someheat sources may provide heat from combustion, and some heat sources mayprovide heat from one or more other energy sources (e.g., chemicalreactions, solar energy, wind energy, biomass, or other sources ofrenewable energy). A chemical reaction may include an exothermicreaction (e.g., an oxidation reaction). A heat source may also include aheater that provides heat to a zone proximate and/or surrounding aheating location such as a heater well.

A “heater” is any system for generating heat in a well or a nearwellbore region. Heaters may be, but are not limited to, electricheaters, burners, combustors that react with material in or producedfrom a formation, and/or combinations thereof.

“Insulated conductor” refers to any elongated material that is able toconduct electricity and that is covered, in whole or in part, by anelectrically insulating material.

“Temperature limited heater” generally refers to a heater that regulatesheat output (for example, reduces heat output) above a specifiedtemperature without the use of external controls such as temperaturecontrollers, power regulators, rectifiers, or other devices. Temperaturelimited heaters may be AC (alternating current) or modulated (forexample, “chopped”) DC (direct current) powered electrical resistanceheaters.

“Curie temperature” is the temperature above which a ferromagneticmaterial loses all of its ferromagnetic properties. In addition tolosing all of its ferromagnetic properties above the Curie temperature,the ferromagnetic material begins to lose its ferromagnetic propertieswhen an increasing electrical current is passed through theferromagnetic material.

“Time-varying current” refers to electrical current that produces skineffect electricity flow in a ferromagnetic conductor and has a magnitudethat varies with time. Time-varying current includes both alternatingcurrent (AC) and modulated direct current (DC).

“Alternating current (AC)” refers to a time-varying current thatreverses direction substantially sinusoidally. AC produces skin effectelectricity flow in a ferromagnetic conductor.

“Modulated direct current (DC)” refers to any substantiallynon-sinusoidal time-varying current that produces skin effectelectricity flow in a ferromagnetic conductor.

“Turndown ratio” for the temperature limited heater is the ratio of thehighest AC or modulated DC resistance below the Curie temperature to thelowest resistance above the Curie temperature for a given current.

In the context of reduced heat output heating systems, apparatus, andmethods, the term “automatically” means such systems, apparatus, andmethods function in a certain way without the use of external control(for example, external controllers such as a controller with atemperature sensor and a feedback loop, PID controller, or predictivecontroller).

“Nitride” refers to a compound of nitrogen and one or more otherelements of the Periodic Table. Nitrides include, but are not limitedto, silicon nitride, boron nitride, or alumina nitride.

The term “wellbore” refers to a hole in a formation made by drilling orinsertion of a conduit into the formation. A wellbore may have asubstantially circular cross section, or another cross-sectional shape.As used herein, the terms “well” and “opening,” when referring to anopening in the formation may be used interchangeably with the term“wellbore.”

“Orifices” refer to openings (e.g., openings in conduits) having a widevariety of sizes and cross-sectional shapes including, but not limitedto, circles, ovals, squares, rectangles, triangles, slits, or otherregular or irregular shapes.

“Pyrolysis” is the breaking of chemical bonds due to the application ofheat. For example, pyrolysis may include transforming a compound intoone or more other substances by heat alone. Heat may be transferred to asection of the formation to cause pyrolysis.

“Pyrolyzation fluids” or “pyrolysis products” refers to fluid producedsubstantially during pyrolysis of hydrocarbons. Fluid produced bypyrolysis reactions may mix with other fluids in a formation. Themixture would be considered pyrolyzation fluid or pyrolyzation product.As used herein, “pyrolysis zone” refers to a volume of a formation(e.g., a relatively permeable formation such as a tar sands formation)that is reacted or reacting to form a pyrolyzation fluid.

“Cracking” refers to a process involving decomposition and molecularrecombination of organic compounds to produce a greater number ofmolecules than were initially present. In cracking, a series ofreactions take place accompanied by a transfer of hydrogen atoms betweenmolecules. For example, naphtha may undergo a thermal cracking reactionto form ethene and H₂.

“Superposition of heat” refers to providing heat from two or more heatsources to a selected section of a formation such that the temperatureof the formation at least at one location between the heat sources isinfluenced by the heat sources.

“Thermal conductivity” is a property of a material that describes therate at which heat flows, in steady state, between two surfaces of thematerial for a given temperature difference between the two surfaces.

“Fluid pressure” is a pressure generated by a fluid in a formation.“Lithostatic pressure” (sometimes referred to as “lithostatic stress”)is a pressure in a formation equal to a weight per unit area of anoverlying rock mass. “Hydrostatic pressure” is a pressure in a formationexerted by a column of water.

“Condensable hydrocarbons” are hydrocarbons that condense at 25° C. andone atmosphere absolute pressure. Condensable hydrocarbons may include amixture of hydrocarbons having carbon numbers greater than 4.“Non-condensable hydrocarbons” are hydrocarbons that do not condense at25° C. and one atmosphere absolute pressure. Non-condensablehydrocarbons may include hydrocarbons having carbon numbers less than 5.

“Olefins” are molecules that include unsaturated hydrocarbons having oneor more non-aromatic carbon-carbon double bonds.

“Synthesis gas” is a mixture including hydrogen and carbon monoxide.Additional components of synthesis gas may include water, carbondioxide, nitrogen, methane, and other gases. Synthesis gas may begenerated by a variety of processes and feedstocks. Synthesis gas may beused for synthesizing a wide range of compounds.

A “dipping” formation refers to a formation that slopes downward orinclines from a plane parallel to the Earth's surface, assuming theplane is flat (i.e., a “horizontal” plane).

“Subsidence” is a downward movement of a portion of a formation relativeto an initial elevation of the surface.

“Thickness” of a layer refers to the thickness of a cross section of thelayer, wherein the cross section is normal to a face of the layer.

“Coring” is a process that generally includes drilling a hole into aformation and removing a substantially solid mass of the formation fromthe hole.

“Enriched air” refers to air having a larger mole fraction of oxygenthan air in the atmosphere. Air is typically enriched to increasecombustion-supporting ability of the air.

“Rich layers” in a hydrocarbon containing formation are relatively thinlayers (typically about 0.2 m to about 0.5 m thick). Rich layersgenerally have a richness of about 0.150 L/kg or greater. Some richlayers have a richness of about 0.170 L/kg or greater, of about 0.190L/kg or greater, or of about 0.210 L/kg or greater. Lean layers of theformation have a richness of about 0.100 L/kg or less and are generallythicker than rich layers. The richness and locations of layers aredetermined, for example, by coring and subsequent Fischer assay of thecore, density or neutron logging, or other logging methods. Rich layershave a lower initial thermal conductivity than other layers of theformation. Typically, rich layers have a thermal conductivity 1.5 timesto 3 times lower than the thermal conductivity of lean layers. Inaddition, rich layers have a higher thermal expansion coefficient thanlean layers of the formation.

“API gravity” refers to API gravity at 15.5° C. (60° F.). API gravity isas determined by ASTM Method D6822. “ASTM” refers to American StandardTesting and Materials.

“Heavy hydrocarbons” are viscous hydrocarbon fluids. Heavy hydrocarbonsmay include highly viscous hydrocarbon fluids such as heavy oil, tar,and/or asphalt. Heavy hydrocarbons may include carbon and hydrogen, aswell as smaller concentrations of sulfur, oxygen, and nitrogen.Additional elements may also be present in heavy hydrocarbons in traceamounts. Heavy hydrocarbons may be classified by API gravity. Heavyhydrocarbons generally have an API gravity below about 20°. Heavy oil,for example, generally has an API gravity of about 10-20°, whereas targenerally has an API gravity below about 10°. The viscosity of heavyhydrocarbons is generally greater than about 100 centipoise at 15° C.Heavy hydrocarbons may also include aromatics or other complex ringhydrocarbons.

Heavy hydrocarbons may be found in a relatively permeable formation. Therelatively permeable formation may include heavy hydrocarbons entrainedin, for example, sand or carbonate. “Relatively permeable” is defined,with respect to formations or portions thereof, as an averagepermeability of 10 millidarcy or more (e.g., 10 or 100 millidarcy).“Relatively low permeability” is defined, with respect to formations orportions thereof, as an average permeability of less than about 10millidarcy. One darcy is equal to about 0.99 square micrometers. Animpermeable layer generally has a permeability of less than about 0.1millidarcy.

“Tar” is a viscous hydrocarbon that generally has a viscosity greaterthan about 10,000 centipoise at 15° C. The specific gravity of targenerally is greater than 1.000. Tar may have an API gravity less than10°.

A “tar sands formation” is a formation in which hydrocarbons arepredominantly present in the form of heavy hydrocarbons and/or tarentrained in a mineral grain framework or other host lithology (e.g.,sand or carbonate).

In some cases, a portion or all of a hydrocarbon portion of a relativelypermeable formation may be predominantly heavy hydrocarbons and/or tarwith no supporting mineral grain framework and only floating (or no)mineral matter (e.g., asphalt lakes).

Certain types of formations that include heavy hydrocarbons may also be,but are not limited to, natural mineral waxes, or natural asphaltites.“Natural mineral waxes” typically occur in substantially tubular veinsthat may be several meters wide, several kilometers long, and hundredsof meters deep. “Natural asphaltites” include solid hydrocarbons of anaromatic composition and typically occur in large veins. In siturecovery of hydrocarbons from formations such as natural mineral waxesand natural asphaltites may include melting to form liquid hydrocarbonsand/or solution mining of hydrocarbons from the formations.

“Upgrade” refers to increasing the quality of hydrocarbons. For example,upgrading heavy hydrocarbons may result in an increase in the APIgravity of the heavy hydrocarbons.

“Thermal fracture” refers to fractures created in a formation caused byexpansion or contraction of a formation and/or fluids in the formation,which is in turn caused by increasing/decreasing the temperature of theformation and/or fluids in the formation, and/or byincreasing/decreasing a pressure of fluids in the formation due toheating.

Hydrocarbons in formations may be treated in various ways to producemany different products. In certain embodiments, hydrocarbons informations are treated in stages. FIG. 1 depicts an illustration ofstages of heating the hydrocarbon containing formation. FIG. 1 alsodepicts an example of yield (“Y”) in barrels of oil equivalent per ton(y axis) of formation fluids from the formation versus temperature (“T”)of the heated formation in degrees Celsius (x axis).

Desorption of methane and vaporization of water occurs during stage 1heating. Heating of the formation through stage 1 may be performed asquickly as possible. For example, when the hydrocarbon containingformation is initially heated, hydrocarbons in the formation desorbadsorbed methane. The desorbed methane may be produced from theformation. If the hydrocarbon containing formation is heated further,water in the hydrocarbon containing formation is vaporized. Water mayoccupy, in some hydrocarbon containing formations, between 10% and 50%of the pore volume in the formation. In other formations, water occupieslarger or smaller portions of the pore volume. Water typically isvaporized in a formation between 160° C. and 285° C. at pressures of 600kPa absolute to 7000 kPa absolute. In some embodiments, the vaporizedwater produces wettability changes in the formation and/or increasedformation pressure. The wettability changes and/or increased pressuremay affect pyrolysis reactions or other reactions in the formation. Incertain embodiments, the vaporized water is produced from the formation.In other embodiments, the vaporized water is used for steam extractionand/or distillation in the formation or outside the formation. Removingthe water from and increasing the pore volume in the formation increasesthe storage space for hydrocarbons in the pore volume.

In certain embodiments, after stage 1 heating, the formation is heatedfurther, such that a temperature in the formation reaches (at least) aninitial pyrolyzation temperature (such as a temperature at the lower endof the temperature range shown as stage 2). Hydrocarbons in theformation may be pyrolyzed throughout stage 2. A pyrolysis temperaturerange varies depending on the types of hydrocarbons in the formation.The pyrolysis temperature range may include temperatures between 250° C.and 900° C. The pyrolysis temperature range for producing desiredproducts may extend through only a portion of the total pyrolysistemperature range. In some embodiments, the pyrolysis temperature rangefor producing desired products may include temperatures between 250° C.and 400° C. or temperatures between 270° C. and 350° C. If a temperatureof hydrocarbons in a formation is slowly raised through the temperaturerange from 250° C. to 400° C., production of pyrolysis products may besubstantially complete when the temperature approaches 400° C. Averagetemperature of the hydrocarbons may be raised at a rate of less than 5°C. per day, less than 2° C. per day, less than 1° C. per day, or lessthan 0.5° C. per day through the pyrolysis temperature range forproducing desired products. Heating the hydrocarbon containing formationwith a plurality of heat sources may establish thermal gradients aroundthe heat sources that slowly raise the temperature of hydrocarbons inthe formation through the pyrolysis temperature range.

The rate of temperature increase through the pyrolysis temperature rangefor desired products may affect the quality and quantity of theformation fluids produced from the hydrocarbon containing formation.Raising the temperature slowly through the pyrolysis temperature rangefor desired products may inhibit mobilization of large chain moleculesin the formation. Raising the temperature slowly through the pyrolysistemperature range for desired products may limit reactions betweenmobilized hydrocarbons that produce undesired products. Slowly raisingthe temperature of the formation through the pyrolysis temperature rangefor desired products may allow for the production of high quality, highAPI gravity hydrocarbons from the formation. Slowly raising thetemperature of the formation through the pyrolysis temperature range fordesired products may allow for the removal of a large amount of thehydrocarbons present in the formation as hydrocarbon product.

In some in situ conversion embodiments, a portion of a formation isheated to a desired temperature instead of slowly heating thetemperature through a temperature range. In some embodiments, thedesired temperature is 300° C., 325° C., or 350° C. Other temperaturesmay be selected as the desired temperature. Superposition of heat fromheat sources allows the desired temperature to be relatively quickly andefficiently established in the formation. Energy input into theformation from the heat sources may be adjusted to maintain thetemperature in the formation substantially at the desired temperature.The heated portion of the formation is maintained substantially at thedesired temperature until pyrolysis declines such that production ofdesired formation fluids from the formation becomes uneconomical. Partsof a formation that are subjected to pyrolysis may include regionsbrought into a pyrolysis temperature range by heat transfer from onlyone heat source.

In certain embodiments, formation fluids including pyrolyzation fluidsare produced from the formation. As the temperature of the formationincreases, the amount of condensable hydrocarbons in the producedformation fluid may decrease. At high temperatures, the formation mayproduce mostly methane and/or hydrogen. If the hydrocarbon containingformation is heated throughout an entire pyrolysis range, the formationmay produce only small amounts of hydrogen towards an upper limit of thepyrolysis range. After all of the available hydrogen is depleted, aminimal amount of fluid production from the formation will typicallyoccur.

After pyrolysis of hydrocarbons, a large amount of carbon and somehydrogen may still be present in the formation. A significant portion ofcarbon remaining in the formation can be produced from the formation inthe form of synthesis gas. Synthesis gas generation may take placeduring stage 3 heating depicted in FIG. 1. Stage 3 may include heating ahydrocarbon containing formation to a temperature sufficient to allowsynthesis gas generation. For example, synthesis gas may be produced ina temperature range from about 400° C. to about 1200° C., about 500° C.to about 1100° C., or about 550° C. to about 1000° C. The temperature ofthe heated portion of the formation when the synthesis gas generatingfluid is introduced to the formation determines the composition ofsynthesis gas produced in the formation. The generated synthesis gas maybe removed from the formation through a production well or productionwells.

Total energy content of fluids produced from the hydrocarbon containingformation may stay relatively constant throughout pyrolysis andsynthesis gas generation. During pyrolysis at relatively low formationtemperatures, a significant portion of the produced fluid may becondensable hydrocarbons that have a high energy content. At higherpyrolysis temperatures, however, less of the formation fluid may includecondensable hydrocarbons. More non-condensable formation fluids may beproduced from the formation. Energy content per unit volume of theproduced fluid may decline slightly during generation of predominantlynon-condensable formation fluids. During synthesis gas generation,energy content per unit volume of produced synthesis gas declinessignificantly compared to energy content of pyrolyzation fluid. Thevolume of the produced synthesis gas, however, will in many instancesincrease substantially, thereby compensating for the decreased energycontent.

FIG. 2 depicts a van Krevelen diagram. The van Krevelen diagram is aplot of atomic hydrogen to carbon ratio (H/C y axis) versus atomicoxygen to carbon ratio (O/C x axis) for various types of kerogen. Thevan Krevelen diagram shows the maturation sequence for various types ofkerogen that typically occurs over geological time due to temperature,pressure, and biochemical degradation. The maturation sequence may beaccelerated by heating in situ at a controlled rate and/or a controlledpressure.

The van Krevelen diagram may be useful for selecting a resource forpracticing various in situ conversion embodiments. Treating a formationcontaining kerogen in region 200 may produce carbon dioxide,non-condensable hydrocarbons, hydrogen, and water, along with arelatively small amount of condensable hydrocarbons. Treating aformation containing kerogen in region 202 may produce condensable andnon-condensable hydrocarbons, carbon dioxide, hydrogen, and water.Treating a formation containing kerogen in region 204 will in manyinstances produce methane and hydrogen. A formation containing kerogenin region 202 may be selected for treatment because treating region 202kerogen may produce large quantities of valuable hydrocarbons, and lowquantities of undesirable products such as carbon dioxide and water. Aregion 202 kerogen may produce large quantities of valuable hydrocarbonsand low quantities of undesirable products because the region 202kerogen has already undergone dehydration and/or decarboxylation overgeological time. In addition, region 202 kerogen can be further treatedto make other useful products (e.g., methane, hydrogen, and/or synthesisgas) as the kerogen transforms to region 204 kerogen.

If a formation containing kerogen in region 200 or region 202 isselected for in situ conversion, in situ thermal treatment mayaccelerate maturation of the kerogen along paths represented by arrowsin FIG. 2. For example, region 200 kerogen may transform to region 202kerogen and possibly then to region 204 kerogen. Region 202 kerogen maytransform to region 204 kerogen. In situ conversion may expeditematuration of kerogen and allow production of valuable products from thekerogen.

If region 200 kerogen is treated, a substantial amount of carbon dioxidemay be produced due to decarboxylation of hydrocarbons in the formation.In addition to carbon dioxide, region 200 kerogen may produce somehydrocarbons, such as methane. Treating region 200 kerogen may producesubstantial amounts of water due to dehydration of kerogen in theformation. Production of water from kerogen may leave hydrocarbonsremaining in the formation enriched in carbon. Oxygen content of thehydrocarbons may decrease faster than hydrogen content of thehydrocarbons during production of water and carbon dioxide from theformation. Therefore, production of water and carbon dioxide from region200 kerogen may result in a larger decrease in the atomic oxygen tocarbon ratio than in the atomic hydrogen to carbon ratio (see region 200arrows in FIG. 2 which depict more horizontal than vertical movement).

If region 202 kerogen is treated, some of the hydrocarbons in theformation may be pyrolyzed to produce condensable and non-condensablehydrocarbons. For example, treating region 202 kerogen may result inproduction of oil from hydrocarbons, as well as some carbon dioxide andwater. In situ conversion of region 202 kerogen may producesignificantly less carbon dioxide and water than is produced during insitu conversion of region 200 kerogen. Therefore, the atomic hydrogen tocarbon ratio of the kerogen may decrease rapidly as the kerogen inregion 202 is treated. The atomic oxygen to carbon ratio of region 202kerogen may decrease much slower than the atomic hydrogen to carbonratio of region 202 kerogen.

Kerogen in region 204 may be treated to generate methane and hydrogen.For example, if such kerogen was previously treated (e.g., the kerogenwas previously region 202 kerogen), then after pyrolysis longerhydrocarbon chains of the hydrocarbons may have cracked and beenproduced from the formation. Carbon and hydrogen, however, may still bepresent in the formation.

If kerogen in region 204 is heated to a synthesis gas generatingtemperature and a synthesis gas generating fluid such as steam is addedto the kerogen of region 204, then at least a portion of remaininghydrocarbons in the formation may be produced from the formation in theform of synthesis gas. For kerogen in region 204, the atomic hydrogen tocarbon ratio and the atomic oxygen to carbon ratio in the hydrocarbonsmay significantly decrease as the temperature rises. Hydrocarbons in theformation may be transformed into relatively pure carbon in region 204.Heating region 204 kerogen to still higher temperatures may transformsuch kerogen into graphite 206.

The van Krevelen diagram shown in FIG. 2 classifies various naturaldeposits of kerogen. For example, kerogen may be classified into fourdistinct groups: type I, type II, type III, and type IV, which areillustrated by the four branches of the van Krevelen diagram. The vanKrevelen diagram shows the maturation sequence for kerogen thattypically occurs over geological time due to temperature and pressure.Classification of kerogen type may depend upon precursor materials ofthe kerogen. The precursor materials transform over time into macerals.Macerals are microscopic structures that have different structures andproperties depending on the precursor materials from which they arederived.

The dashed lines in FIG. 2 correspond to vitrinite reflectance.Vitrinite reflectance is a measure of maturation. As kerogen undergoesmaturation, the composition of the kerogen usually changes due toexpulsion of volatile matter such as carbon dioxide, methane, water, andoil. Vitrinite reflectance of kerogen indicates the level to whichkerogen has matured. As vitrinite reflectance increases, the volatilematter in, and producible from, the kerogen tends to decrease. Inaddition, the moisture content of kerogen generally decreases as therank increases.

FIG. 3 depicts a schematic view of an embodiment of a portion of the insitu conversion system for treating the hydrocarbon containingformation. The in situ conversion system may include barrier wells 208.Barrier wells are used to form a barrier around a treatment area. Thebarrier inhibits fluid flow into and/or out of the treatment area.Barrier wells include, but are not limited to, dewatering wells, vacuumwells, capture wells, injection wells, grout wells, freeze wells, orcombinations thereof. In some embodiments, barrier wells 208 aredewatering wells. Dewatering wells may remove liquid water and/orinhibit liquid water from entering a portion of the formation to beheated, or to the formation being heated. In the embodiment depicted inFIG. 3, the dewatering wells are shown extending only along one side ofheat sources 210, but dewatering wells typically encircle all heatsources 210 used, or to be used, to heat the formation.

Heat sources 210 are placed in at least a portion of the formation. Heatsources 210 may include electric heaters such as insulated conductors,conductor-in-conduit heaters, surface burners, flameless distributedcombustors, and/or natural distributed combustors. Heat sources 210 mayalso include other types of heaters. Heat sources 210 provide heat to atleast a portion of the formation to heat hydrocarbons in the formation.Energy may be supplied to heat sources 210 through supply lines 212.Supply lines 212 may be structurally different depending on the type ofheat source or heat sources used to heat the formation. Supply lines 212for heat sources may transmit electricity for electric heaters, maytransport fuel for combustors, or may transport heat exchange fluid thatis circulated in the formation.

When the formation is heated, the heat input into the formation maycause expansion of the formation and geomechanical motion. Computersimulations may model formation response to heating. The computersimulations may be used to develop a pattern and time sequence foractivating heat sources in the formation so that geomechanical motion ofthe formation does not adversely affect the functionality of heatsources, production wells, and other equipment in the formation.

Heating the formation may cause an increase in permeability and/orporosity of the formation. Increases in permeability and/or porosity mayresult from a reduction of mass in the formation due to vaporization andremoval of water, removal of hydrocarbons, and/or creation of fractures.Fluid may flow more easily in the heated portion of the formationbecause of the increased permeability and/or porosity of the formation.Fluid in the heated portion of the formation may move a considerabledistance through the formation because of the increased permeabilityand/or porosity. The considerable distance may be over 1000 m dependingon various factors, such as permeability of the formation, properties ofthe fluid, temperature of the formation, and pressure gradient allowingmovement of the fluid. The ability of fluid to travel considerabledistance in the formation allows production wells 214 to be spacedrelatively far apart in the formation.

Production wells 214 are used to remove formation fluid from theformation. In some embodiments, production well 214 includes a heatsource. The heat source in the production well may heat one or moreportions of the formation at or near the production well. In some insitu conversion process embodiments, the amount of heat supplied to theformation from the production well per meter of the production well isless than the amount of heat applied to the formation from a heat sourcethat heats the formation per meter of the heat source. Heat applied tothe formation from the production well may increase formationpermeability adjacent to the production well by vaporizing and removingliquid phase fluid adjacent to the production well and/or by increasingthe permeability of the formation adjacent to the production well byformation of macro and/or micro fractures.

More than one heat source may be positioned in the production well. Aheat source in a lower portion of the production well may be turned offwhen superposition of heat from adjacent heat sources heats theformation sufficiently to counteract benefits provided by heating theformation with the production well. In some embodiments, the heat sourcein an upper portion of the production well may remain on after the heatsource in the lower portion of the production well is deactivated. Theheat source in the upper portion of the well may inhibit condensationand reflux of formation fluid.

In some embodiments, the heat source in production well 214 allows forvapor phase removal of formation fluids from the formation. Providingheating at or through the production well may: (1) inhibit condensationand/or refluxing of production fluid when such production fluid ismoving in the production well proximate the overburden, (2) increaseheat input into the formation, (3) increase production rate from theproduction well as compared to a production well without a heat source,(4) inhibit condensation of high carbon number compounds (C₆ and above)in the production well, (5) and/or (3) increase formation permeabilityat or proximate the production well.

Subsurface pressure in the formation may correspond to the fluidpressure generated in the formation. As temperatures in the heatedportion of the formation increase, the pressure in the heated portionmay increase as a result of increased fluid generation and vaporizationof water. Controlling rate of fluid removal from the formation may allowfor control of pressure in the formation. Pressure in the formation maybe determined at a number of different locations, such as near or atproduction wells, near or at heat sources, or at monitor wells.

In some hydrocarbon containing formations, production of hydrocarbonsfrom the formation is inhibited until at least some hydrocarbons in theformation have been pyrolyzed. Formation fluid may be produced from theformation when the formation fluid is of a selected quality. In someembodiments, the selected quality includes an API gravity of at leastabout 20°, 30°, or 40°. Inhibiting production until at least somehydrocarbons are pyrolyzed may increase conversion of heavy hydrocarbonsto light hydrocarbons Inhibiting initial production may minimize theproduction of heavy hydrocarbons from the formation. Production ofsubstantial amounts of heavy hydrocarbons may require expensiveequipment and/or reduce the life of production equipment.

In some hydrocarbon containing formations, hydrocarbons in the formationmay be heated to pyrolysis temperatures before substantial permeabilityhas been generated in the heated portion of the formation. An initiallack of permeability may inhibit the transport of generated fluids toproduction wells 214. During initial heating, fluid pressure in theformation may increase proximate the heat sources 210. The increasedfluid pressure may be released, monitored, altered, and/or controlledthrough one or more heat sources 210. For example, selected heat sources210 or separate pressure relief wells may include pressure relief valvesthat allow for removal of some fluid from the formation.

In some embodiments, pressure generated by expansion of pyrolysis fluidsor other fluids generated in the formation may be allowed to increasealthough an open path to production wells 214 or any other pressure sinkmay not yet exist in the formation. The fluid pressure may be allowed toincrease towards a lithostatic pressure. Fractures in the hydrocarboncontaining formation may form when the fluid approaches the lithostaticpressure. For example, fractures may form from heat sources 210 toproduction wells 214 in the heated portion of the formation. Thegeneration of fractures in the heated portion may relieve some of thepressure in the portion. Pressure in the formation may have to bemaintained below a selected pressure to inhibit unwanted production,fracturing of the overburden or underburden, and/or coking ofhydrocarbons in the formation.

After pyrolysis temperatures are reached and production from theformation is allowed, pressure in the formation may be varied to alterand/or control a composition of formation fluid produced, to control apercentage of condensable fluid as compared to non-condensable fluid inthe formation fluid, and/or to control an API gravity of formation fluidbeing produced. For example, decreasing pressure may result inproduction of a larger condensable fluid component. The condensablefluid component may contain a larger percentage of olefins.

In some in situ conversion process embodiments, pressure in theformation may be maintained high enough to promote production offormation fluid with an API gravity of greater than 20°. Maintainingincreased pressure in the formation may inhibit formation subsidenceduring in situ conversion. Maintaining increased pressure may facilitatevapor phase production of fluids from the formation. Vapor phaseproduction may allow for a reduction in size of collection conduits usedto transport fluids produced from the formation. Maintaining increasedpressure may reduce or eliminate the need to compress formation fluidsat the surface to transport the fluids in collection conduits totreatment facilities.

Maintaining increased pressure in a heated portion of the formation maysurprisingly allow for production of large quantities of hydrocarbons ofincreased quality and of relatively low molecular weight. Pressure maybe maintained so that formation fluid produced has a minimal amount ofcompounds above a selected carbon number. The selected carbon number maybe at most 25, at most 20, at most 12, or at most 8. Some high carbonnumber compounds may be entrained in vapor in the formation and may beremoved from the formation with the vapor. Maintaining increasedpressure in the formation may inhibit entrainment of high carbon numbercompounds and/or multi-ring hydrocarbon compounds in the vapor. Highcarbon number compounds and/or multi-ring hydrocarbon compounds mayremain in a liquid phase in the formation for significant time periods.The significant time periods may provide sufficient time for thecompounds to pyrolyze to form lower carbon number compounds.

Generation of relatively low molecular weight hydrocarbons is believedto be due, in part, to autogenous generation and reaction of hydrogen ina portion of the hydrocarbon containing formation. For example,maintaining an increased pressure may force hydrogen generated duringpyrolysis into the liquid phase within the formation. Heating theportion to a temperature in a pyrolysis temperature range may pyrolyzehydrocarbons in the formation to generate liquid phase pyrolyzationfluids. The generated liquid phase pyrolyzation fluids components mayinclude double bonds and/or radicals. H₂ in the liquid phase may reducedouble bonds of the generated pyrolyzation fluids, thereby reducing apotential for polymerization or formation of long chain compounds fromthe generated pyrolyzation fluids. In addition, H₂ may also neutralizeradicals in the generated pyrolyzation fluids. Therefore, H₂ in theliquid phase may inhibit the generated pyrolyzation fluids from reactingwith each other and/or with other compounds in the formation.

Formation fluid produced from production wells 214 may be transportedthrough collection piping 216 to treatment facilities 218. Formationfluids may also be produced from heat sources 210. For example, fluidmay be produced from heat sources 210 to control pressure in theformation adjacent to the heat sources. Fluid produced from heat sources210 may be transported through tubing or piping to collection piping 216or the produced fluid may be transported through tubing or pipingdirectly to treatment facilities 218. Treatment facilities 218 mayinclude separation units, reaction units, upgrading units, fuel cells,turbines, storage vessels, and/or other systems and units for processingproduced formation fluids.

Formation fluid produced from the in situ conversion process may be sentto a separator to split the stream into an in situ conversion processliquid stream and an in situ conversion process gas stream. The liquidstream and the gas stream may be further treated to yield desiredproducts. All or a portion of the gas stream may be treated to yield agas that meets natural gas pipeline specifications. FIG. 4 depicts aschematic representation of an embodiment of a system for producingpipeline gas from the in situ conversion process gas stream.

In situ conversion process gas 220 is sent to unit 222. Unit 222 scrubsin situ conversion process gas 220 to remove sulfur compounds and/orcarbon dioxide. Unit 222 may contain, but is not limited to containing,diethanolamine, diisopropanolamine, a combination of amines, and/or asulfinol composition.

Gas stream 224 from unit 222 passes to hydrogenation reactor 226.Hydrogenation reactor 226 has a nickel-based catalyst. Suitablecatalysts include, but are not limited to, Criterion 424, DN-140,DN-200, and DN-3100 available from Criterion Catalysts & Technologies(Houston, Tex.). Hydrogenation reactor 226 hydrogenates olefins andconverts carbon monoxide to methane. Hydrogenation reactor 226 mayoperate at a temperature of about 66° C. Inlet hydrogen stream 228 mayenter hydrogenation reactor 226. Hydrogenation reactor 226 includes aknockout pot. The knockout pot removes any heavy by-products 230 fromthe product gas stream.

Gas stream 232 from hydrogenation reactor 226 passes to hydrogenseparation unit 234. Hydrogen separation unit 234 may be any suitableunit capable of separating hydrogen from the incoming gas stream.Hydrogen separation unit 234 may be a membrane unit, a pressure swingadsorption unit, a liquid absorption unit or a cryogenic unit. In anembodiment, hydrogen separation unit 234 is a membrane unit. Hydrogenseparation unit 234 may include PRISM membranes available from AirProducts and Chemicals, Inc. (Allentown, Pa.). The membrane separationunit may be operated at about 66° C. Hydrogen rich stream 236 producedfrom hydrogen separation unit 234 may be used as a feed stream tohydrogenation reactor 226.

Gas stream 238 from hydrogen separation unit 234 passes to oxidationreactor 240. Oxidation reactor 240 further reduces the amount ofhydrogen in gas stream 238 by oxidation to form water. In someembodiments, the oxidation reactor is not needed. In some embodiments,inlet stream 242 may provide pure oxygen to oxidation reactor 240. Insome embodiments, inlet stream 242 may provide air or oxygen enrichedair. Air or oxygen enriched air may be provided if the amount of oxygenneeded to remove the remaining hydrogen is low enough so that thenitrogen in the inlet stream would not result in a nitrogen content ofthe product gas that exceeds pipeline specifications. Oxidation reactor240 may include a catalyst. In some embodiments, the catalyst ispalladium on alumina base with about 0.2% by weight loading. Oxidationreactor 240 may be operated at a temperature of about 66° C.

Resulting gas stream 244 from oxidation reactor 240 passes todehydration unit 246. Dehydration unit 246 may be a standard gas plantglycol dehydration unit. Pipeline gas 248 and water 250 may leavedehydration unit 246.

Wellbores may be formed in the ground using any desired method.Wellbores may be drilled, impacted, and/or vibrated in the ground. Insome embodiments, wellbores are formed using reverse circulationdrilling. Reverse circulation drilling may minimize formation damage dueto contact with drilling muds and cuttings. Reverse circulation drillingmay inhibit contamination of cuttings so that recovered cuttings can beused as a substitute for coring. Reverse circulation drilling maysignificantly reduce the volume of drilling fluid. The drilling fluidmay be, for example, air, water, brine, or a drilling mud. The reductionmay significantly reduce drilling costs. Formation water production isreduced when using reverse circulation drilling. Reverse circulationdrilling permits use of air drilling without resulting in excessive airpockets being left in the formation. Prevention of air pockets in theformation during formation of wellbores is desirable, especially if thewellbores are to be used as freeze wells for forming a barrier around atreatment area.

Reverse circulation drilling systems may include components to enabledirectional drilling. For example, steerable motors, bent subs foraltering the direction of the borehole, or autonomous drilling packagescould be included.

When drilling a wellbore, a magnet or magnets may be inserted into afirst opening to provide a magnetic field used to guide a drillingmechanism that forms an adjacent opening or adjacent openings. Themagnetic field may be detected by a 3-axis fluxgate magnetometer in theopening being drilled. A control system may use information detected bythe magnetometer to determine and implement operation parameters neededto form an opening that is a selected distance away from the firstopening (within desired tolerances).

Various types of wellbores may be formed using magnetic tracking. Forexample, wellbores formed by magnetic tracking may be used for in situconversion processes, for steam assisted gravity drainage processes, forthe formation of perimeter barriers or frozen barriers, and/or for soilremediation processes. Magnetic tracking may be used to form wellboresfor processes that require relatively small tolerances or variations indistances between adjacent wellbores. For example, vertical and/orhorizontally positioned heater wells and/or production wells may need tobe positioned parallel to each other with relatively little or novariance in parallel alignment to allow for substantially uniformheating and/or production from the treatment area in the formation.

In certain embodiments, a magnetic string is placed in a vertical well.The magnetic string in the vertical well is used to guide the drillingof a horizontal well such that the horizontal well connects to thevertical well at a desired location, or passes the vertical well at aselected distance relative to the vertical well at a selected depth inthe formation, or stops a selected distance away from the vertical well.In some embodiments, the magnetic string is placed in a horizontal well.The magnetic string in the horizontal well is used to guide the drillingof a vertical well such that the vertical well connects to thehorizontal well at a desired location, or passes the horizontal well ata selected distance relative to the horizontal well, or stops at aselected distance away from the horizontal well.

Analytical equations may be used to determine the spacing betweenadjacent wellbores using measurements of magnetic field strengths. Themagnetic field from a first wellbore may be measured by a magnetometerin a second wellbore. Analysis of the magnetic field strengths usingderivations of analytical equations may determine the coordinates of thesecond wellbore relative to the first wellbore.

FIG. 5 depicts a schematic representation of an embodiment of amagnetostatic drilling operation to form an opening that is anapproximate desired distance away from an existing opening. Opening 252may be formed in hydrocarbon layer 254. In some embodiments, opening 252may be formed in any hydrocarbon containing formation, other types ofsubsurface formations, or for any subsurface application, such as soilremediation, solution mining, or steam-assisted gravity drainage.Opening 252 may be formed substantially horizontally in hydrocarbonlayer 254. For example, opening 252 may be formed substantially parallelto a boundary of hydrocarbon layer 254. Opening 252 may be formed inother orientations in hydrocarbon layer 254 depending on, for example, adesired use of the opening, formation depth, a formation type, etc.Opening 252 may include casing 256. In certain embodiments, opening 252may be an open (or uncased) wellbore. In some embodiments, magneticstring 258 may be inserted into opening 252. Magnetic string 258 may beunwound from a reel into opening 252. In an embodiment, magnetic string258 includes one or more magnet segments 260. In other embodiments,magnetic string 258 may include one or more movable permanentlongitudinal magnets. The movable permanent longitudinal magnet may havea north and a south pole. Magnetic string 258 may have a longitudinalaxis that is substantially parallel (for example, within about 5% ofparallel) or coaxial with a longitudinal axis of opening 252.

Magnetic strings may be moved through an opening using a variety ofmethods. In an embodiment, the magnetic string is coupled to a drillstring and moved through the opening as the drill string moves throughthe opening. Alternatively, magnetic strings may be installed usingcoiled tubing. Some embodiments may include coupling the magnetic stringto a tractor system that moves through the opening. For example,commercially available tractor systems from Welltec Well Technologies(Denmark) or Schlumberger Technology Co. (Houston, Tex.) may be used. Incertain embodiments, magnetic strings may be pulled by cable or wirelinefrom either end of the opening. In an embodiment, magnetic strings maybe pumped through the opening using air and/or water. For example, a pigmay be moved through the opening by pumping air and/or water through theopening when the magnetic string is coupled to the pig.

In some embodiments, casing 256 may be a conduit. Casing 256 may be madeof a material that is not significantly influenced by a magnetic field(e.g., non-magnetic alloy such as non-magnetic stainless steel (e.g.,304, 310, 316 stainless steel), reinforced polymer pipe, or brasstubing). The casing may be the conduit of a conductor-in-conduit heater,or the casing may be a perforated liner. If the casing is notsignificantly influenced by a magnetic field, then the magnetic fluxwill not be shielded.

In some embodiments, drilling apparatus 262 may include a magneticguidance sensor probe. The magnetic guidance sensor probe may contain a3-axis fluxgate magnetometer and a 3-axis inclinometer. The inclinometeris typically used to determine the rotation of the sensor probe relativeto Earth's gravitational field. A general magnetic guidance sensor probemay be obtained from Tensor Energy Products (Round Rock, Tex.). Themagnetic guidance sensor may be placed inside the drilling stringcoupled to a drill bit. In certain embodiments, the magnetic guidancesensor probe may be located inside the drilling string of a rivercrossing rig.

Magnet segments 260 may be placed in conduit 264. Conduit 264 may be athreaded or seamless coiled tubular. Conduit 264 may be formed bycoupling one or more sections 266. Sections 266 may include non-magneticmaterials such as, but not limited to, stainless steel. In certainembodiments, conduit 264 is formed by coupling several threaded tubularsections. Sections 266 may have any length desired. Sections 266 mayhave a length chosen to produce magnetic fields with selected distancesbetween junctions of opposing poles in magnetic string 258. The distancebetween junctions of opposing poles may determine the accuracy indetermining the distance between adjacent wellbores. Typically, thedistance between junctions of opposing poles is chosen to be on the samescale as the distance between adjacent wellbores. The distance betweenjunctions may range from about 1 m to about 100 m, from about 5 m toabout 90 m, or from about 20 m to about 70 m.

Conduit 264 may be a threaded stainless steel tubular. In an embodiment,conduit 264 is 2 1/2 inch Schedule 40, 304 stainless steel tubularformed from 20 ft. long sections 266. With 20 ft. long sections 266, thedistance between opposing poles will be about 20 ft. In someembodiments, sections 266 may be coupled as the conduit is formed and/orinserted into opening 252. Conduit 264 may have a length between about375 ft. and about 525 ft. Shorter or longer lengths of conduit 264 maybe used depending on a desired application of the magnetic string.

In an embodiment, sections 266 of conduit 264 may include two magnetsegments 260. More or less than two segments may also be used insections 266. Magnet segments 260 may be arranged in sections 266 suchthat adjacent magnet segments have opposing polarities at the junctionof the segments, as shown in FIG. 5. In an embodiment, one section 266includes two magnet segments 260 of opposing polarities. The polaritybetween adjacent sections 266 may be arranged such that the sectionshave attracting polarities, as shown in FIG. 5. Arranging the opposingpoles approximate the center of each section may make assembly of themagnet segments in each section relatively easy. In an embodiment, theapproximate centers of adjacent sections 266 have opposite poles. Forexample, the approximate center of one section may have north poles andthe adjacent section (or sections on each end of the one section) mayhave south poles as shown in FIG. 5.

Fasteners 268 may be placed at the ends of sections 266 to hold magnetsegments 260 in the sections. Fasteners 268 may include, but are notlimited to, pins, bolts, or screws. Fasteners 268 may be made ofnon-magnetic materials. In some embodiments, ends of sections 266 may beclosed off (e.g., end caps placed on the ends) to enclose magnetsegments 260 in the sections. In certain embodiments, fasteners 268 mayalso be placed at junctions of opposing poles of adjacent magnetsegments 260 to inhibit the adjacent segments from moving apart.

FIG. 6 depicts an embodiment of section 266 with two magnet segments 260with opposing poles. Magnet segments 260 may include one or more magnets270 coupled to form a single magnet segment. Magnet segments 260 and/ormagnets 270 may be positioned in a linear array. Magnets 270 may beAlnico magnets or other types of magnets (such as neodymium iron orsamarium cobalt) with sufficient magnetic strength to produce a magneticfield that can be sensed in a nearby wellbore. Alnico magnets are madeprimarily from alloys of aluminum, nickel and cobalt and may beobtained, for example, from Adams Magnetic Products Co. (Elmhurst,Ill.). Using permanent magnets in magnet segments 260 may reduce theinfrastructure associated with magnetic tracking compared to usinginductive coils or magnetic field producing wires since there is no needto provide electrical current. In an embodiment, magnets 270 are Alnicomagnets about 6 cm in diameter and about 15 cm in length. Assembling amagnet segment from several individual magnets increases the strength ofthe magnetic field produced by the magnet segment. Increasing thestrength of the magnetic fields produced by magnet segments mayadvantageously increase the maximum distance for sensing the magneticfields. The pole strength of a magnet segment may be between about 100Gauss and about 2000 Gauss, or between about 1000 Gauss and about 2000Gauss. In an embodiment, the pole strength of the magnet segment is 1500Gauss. Magnets 270 may be coupled with attracting poles coupled suchthat magnet segment 260 is formed with a south pole at one end and anorth pole at a second end. In one embodiment, 40 magnets 270 of about15 cm in length are coupled to form magnet segment 260 of about 6 m inlength. Opposing poles of magnet segments 260 may be aligned proximatethe center of section 266 as shown in FIGS. 5 and 6. Magnet segments 260may be placed in section 266 and the magnet segments may be held in thesection with fasteners 268. One or more sections 266 may be coupled asshown in FIG. 5 to form a magnetic string. In certain embodiments,un-magnetized magnet segments 260 may be coupled together insidesections 266. Sections 266 may be magnetized with a magnetizing coilafter magnet segments 260 have been assembled together into thesections.

FIG. 7 depicts a schematic of an embodiment of a portion of magneticstring 258. Magnet segments 260 may be positioned such that adjacentsegments have opposing poles. In some embodiments, force may be appliedto minimize distance 272 between magnet segments 260. Additionalsegments may be added to increase the length of magnetic string 258. Incertain embodiments, magnet segments 260 may be located in sections 266,as shown in FIG. 5. Magnetic strings may be coiled after assembling.Installation of the magnetic string may include uncoiling the magneticstring. Coiling and uncoiling of the magnetic string may also be used tochange position of the magnetic string relative to a sensor in a nearbywellbore, for example, drilling apparatus 262 in opening 274, as shownin FIG. 5.

Magnetic strings may include multiple south-south and north-northopposing pole junctions. As shown in FIG. 7, the multiple opposing polejunctions may induce a series of magnetic fields 276. Alternating thepolarity of portions in the magnetic string may provide a sinusoidalvariation of the magnetic field along the length of the magnetic string.The magnetic field variations may allow for control of the desiredspacing between drilled wellbores. In certain embodiments, a series ofmagnetic fields 276 may be sensed at greater distances than individualmagnetic fields. Increasing the distance between opposing pole junctionsin the magnetic string may increase the radial distance at which amagnetometer may detect the magnetic field. In some embodiments, thedistance between opposing pole junctions in the magnetic string may bevaried. For example, more magnets may be used in portions proximateEarth's surface than in portions positioned deeper in the formation.

Some wellbores formed in the formation may be used to facilitateformation of a perimeter barrier around a treatment area. Heat sourcesin the treatment area may heat hydrocarbons in the formation within thetreatment area. The perimeter barrier may be, but is not limited to, afrozen barrier formed by freeze wells, dewatering wells, a grout wallformed in the formation, a sulfur cement barrier, a barrier formed by agel produced in the formation, a barrier formed by precipitation ofsalts in the formation, a barrier formed by a polymerization reaction inthe formation, and/or sheets driven into the formation. Heat sources,production wells, injection wells, dewatering wells, and/or monitoringwells may be installed in the treatment area defined by the barrierprior to, simultaneously with, or after installation of the barrier.

A frozen barrier defining the treatment area may be formed by freezewells. In an embodiment, refrigerant is circulated through freeze wellsto form low temperature zones around each freeze well. The freeze wellsare placed in the formation so that the low temperature zones overlapand form a low temperature zone around the treatment area. The lowtemperature zone established by freeze wells is maintained below thefreezing temperature of aqueous formation fluid in the formation.Aqueous formation fluid entering the low temperature zone freezes andforms the frozen barrier. In other embodiments, the freeze barrier isformed by batch operated freeze wells. A cold fluid, such as liquidnitrogen, is introduced into the freeze wells to form low temperaturezones around the freeze wells. The fluid is replenished as needed.

In some embodiments, two or more rows of freeze wells are located aboutall or a portion of the perimeter of the treatment area to form a thickinterconnected low temperature zone. Thick low temperature zones may beformed adjacent to areas in the formation where there is a high flowrate of aqueous fluid in the formation. The thick barrier may ensurethat breakthrough of the frozen barrier established by the freeze wellsdoes not occur.

Vertically positioned freeze wells and/or horizontally positioned freezewells may be positioned around sides of the treatment area. If the upperlayer (the overburden) or the lower layer (the underburden) of theformation is likely to allow fluid flow into the treatment area or outof the treatment area, horizontally positioned freeze wells may be usedto form an upper and/or a lower barrier for the treatment area. In someembodiments, an upper barrier and/or a lower barrier may not benecessary if the upper layer and/or the lower layer are substantiallyimpermeable. If the upper freeze barrier is formed, portions of heatsources, production wells, injection wells, and/or dewatering wells thatpass through the low temperature zone created by the freeze wellsforming the upper freeze barrier wells may be insulated and/or heattraced so that the low temperature zone does not adversely affect thefunctioning of the heat sources, production wells, injection wellsand/or dewatering wells passing through the low temperature zone.

Spacing between adjacent freeze wells may be a function of a number ofdifferent factors. The factors may include, but are not limited to,physical properties of formation material, type of refrigeration system,coldness and thermal properties of the refrigerant, flow rate ofmaterial into or out of the treatment area, time for forming the lowtemperature zone, and economic considerations. Consolidated or partiallyconsolidated formation material may allow for a large separationdistance between freeze wells. A separation distance between freezewells in consolidated or partially consolidated formation material maybe from about 3 m to about 20 m, about 4 m to about 15 m, or about 5 mto about 10 m. In an embodiment, the spacing between adjacent freezewells is about 5 m. Spacing between freeze wells in unconsolidated orsubstantially unconsolidated formation material, such as in tar sand,may need to be smaller than spacing in consolidated formation material.A separation distance between freeze wells in unconsolidated materialmay be from about 1 m to about 5 m.

Freeze wells may be placed in the formation so that there is minimaldeviation in orientation of one freeze well relative to an adjacentfreeze well. Excessive deviation may create a large separation distancebetween adjacent freeze wells that may not permit formation of aninterconnected low temperature zone between the adjacent freeze wells.Factors that influence the manner in which freeze wells are insertedinto the ground include, but are not limited to, freeze well insertiontime, depth that the freeze wells are to be inserted, formationproperties, desired well orientation, and economics.

Relatively low depth wellbores for freeze wells may be impacted and/orvibrationally inserted into some formations. Wellbores for freeze wellsmay be impacted and/or vibrationally inserted into formations to depthsfrom about 1 m to about 100 m without excessive deviation in orientationof freeze wells relative to adjacent freeze wells in some types offormations.

Wellbores for freeze wells placed deep in the formation, or wellboresfor freeze wells placed in formations with layers that are difficult toimpact or vibrate a well through, may be placed in the formation bydirectional drilling and/or geosteering. Acoustic signals, electricalsignals, magnetic signals, and/or other signals produced in a firstwellbore may be used to guide directional drilling of adjacent wellboresso that desired spacing between adjacent wells is maintained. Tightcontrol of the spacing between wellbores for freeze wells is animportant factor in minimizing the time for completion of barrierformation.

After formation of the wellbore for the freeze well, the wellbore may bebackflushed with water adjacent to the part of the formation that is tobe reduced in temperature to form a portion of the freeze barrier. Thewater may displace drilling fluid remaining in the wellbore. The watermay displace indigenous gas in cavities adjacent to the formation. Insome embodiments, the wellbore is filled with water from a conduit up tothe level of the overburden. In some embodiments, the wellbore isbackflushed with water in sections. The wellbore maybe treated insections having lengths of about 20 ft., about 30 ft., about 40 ft.,about 50 ft., or greater. Pressure of the water in the wellbore ismaintained below the fracture pressure of the formation. In someembodiments, the water, or a portion of the water is removed from thewellbore, and a freeze well is placed in the formation.

FIG. 8 depicts an embodiment of freeze well 278. Freeze well 278 mayinclude canister 280, inlet conduit 282, spacers 284, and wellcap 286.Spacers 284 may position inlet conduit 282 in canister 280 so that anannular space is formed between the casing and the conduit. Spacers 284may promote turbulent flow of refrigerant in the annular space betweeninlet conduit 282 and canister 280, but the spacers may also cause asignificant fluid pressure drop. Turbulent fluid flow in the annularspace may be promoted by roughening the inner surface of canister 280,by roughening the outer surface of inlet conduit 282, and/or by having asmall cross-sectional area annular space that allows for highrefrigerant velocity in the annular space. In some embodiments, spacersare not used.

Formation refrigerant may flow through cold side conduit 288 from arefrigeration unit to inlet conduit 282 of freeze well 278. Theformation refrigerant may flow through an annular space between inletconduit 282 and canister 280 to warm side conduit 290. Heat may transferfrom the formation to canister 280 and from the casing to the formationrefrigerant in the annular space. Inlet conduit 282 may be insulated toinhibit heat transfer to the formation refrigerant during passage of theformation refrigerant into freeze well 278. In an embodiment, inletconduit 282 is a high density polyethylene tube. At cold temperatures,some polymers may exhibit a large amount of thermal contraction. Forexample, an 800 ft. initial length of polyethylene conduit subjected toa temperature of about −25° C. may contract by 20 ft. or more. If a highdensity polyethylene conduit, or other polymer conduit, is used, thelarge thermal contraction of the material must be taken into account indetermining the final depth of the freeze well. For example, the freezewell may be drilled deeper than needed, and the conduit may be allowedto shrink back during use. In some embodiments, inlet conduit 282 is aninsulated metal tube. In some embodiments, the insulation may be apolymer coating, such as, but not limited to, polyvinylchloride, highdensity polyethylene, and/or polystyrene.

Freeze well 278 may be introduced into the formation using a coiledtubing rig. In an embodiment, canister 280 and inlet conduit 282 arewound on a single reel. The coiled tubing rig introduces the canisterand inlet conduit 282 into the formation. In an embodiment, canister 280is wound on a first reel and inlet conduit 282 is wound on a secondreel. The coiled tubing rig introduces canister 280 into the formation.Then, the coiled tubing rig is used to introduce inlet conduit 282 intothe canister. In other embodiments, freeze well is assembled in sectionsat the wellbore site and introduced into the formation.

Various types of refrigeration systems may be used to form a lowtemperature zone. Determination of an appropriate refrigeration systemmay be based on many factors, including, but not limited to: type offreeze well; a distance between adjacent freeze wells; refrigerant; timeframe in which to form a low temperature zone; depth of the lowtemperature zone; temperature differential to which the refrigerant willbe subjected; chemical and physical properties of the refrigerant;environmental concerns related to potential refrigerant releases, leaks,or spills; economics; formation water flow in the formation; compositionand properties of formation water, including the salinity of theformation water; and various properties of the formation such as thermalconductivity, thermal diffusivity, and heat capacity.

A circulated fluid refrigeration system may utilize a liquid refrigerant(formation refrigerant) that is circulated through freeze wells. Some ofthe desired properties for the formation refrigerant are: a low workingtemperature, a low viscosity at the working temperature, a high density,a high specific heat capacity, a high thermal conductivity, a low cost,low corrosiveness, and a low toxicity. A low working temperature of theformation refrigerant allows a large low temperature zone to beestablished around a freeze well. The low working temperature offormation refrigerant should be about −20° C. or lower. Formationrefrigerants having low working temperatures of at least −60° C. mayinclude aqua ammonia, potassium formate solutions such as Dynalene®HC-50 (Dynalene® Heat Transfer Fluids (Whitehall, Pa.)) or FREEZIUM®(Kemira Chemicals (Helsinki, Finland)); silicone heat transfer fluidssuch as Syltherm XLT® (Dow Corning Corporation (Midland, Mich.);hydrocarbon refrigerants such as propylene; and chlorofluorocarbons suchas R-22. Aqua ammonia is a solution of ammonia and water with a weightpercent of ammonia between about 20% and about 40%. Aqua ammonia hasseveral properties and characteristics that make use of aqua ammonia asthe formation refrigerant desirable. Such properties and characteristicsinclude, but are not limited to, a very low freezing point, a lowviscosity, ready availability, and low cost.

Formation refrigerant that is capable of being chilled below a freezingtemperature of aqueous formation fluid may be used to form the lowtemperature zone around the treatment area. The following equation (theSanger equation) may be used to model the time t₁ needed to form afrozen barrier of radius R around a freeze well having a surfacetemperature of T_(s):

$\begin{matrix}{{t_{1} = {\frac{R^{2}L_{1}}{4\; k_{f}v_{s}}\left( {{2\; \ln \frac{R}{r_{o}}} - 1 + \frac{c_{vf}v_{s}}{L_{1}}} \right)}}{{in}\mspace{14mu} {which}\text{:}}{L_{1} = {L\frac{a_{r}^{2} - 1}{2\; \ln \; a_{r}}c_{vu}v_{o}}}{a_{r} = {\frac{R_{A}}{R}.}}} & (1)\end{matrix}$

In these equations, k_(f) is the thermal conductivity of the frozenmaterial; c_(vf) and c_(vu) are the volumetric heat capacity of thefrozen and unfrozen material, respectively; r_(o) is the radius of thefreeze well; v_(s) is the temperature difference between the freeze wellsurface temperature T_(s) and the freezing point of water T_(o); v_(o)is the temperature difference between the ambient ground temperatureT_(g) and the freezing point of water T_(o); L is the volumetric latentheat of freezing of the formation; R is the radius at thefrozen-unfrozen interface; and R_(A) is a radius at which there is noinfluence from the refrigeration pipe. The temperature of the formationrefrigerant is an adjustable variable that may significantly affect thespacing between freeze wells.

EQN. 1 implies that a large low temperature zone may be formed by usinga refrigerant having an initial temperature that is very low. The use offormation refrigerant having an initial cold temperature of about −50°C. or lower is desirable. Formation refrigerants having initialtemperatures warmer than about −50° C. may also be used, but suchformation refrigerants require longer times for the low temperaturezones produced by individual freeze wells to connect. In addition, suchformation refrigerants may require the use of closer freeze wellspacings and/or more freeze wells.

The physical properties of the material used to construct the freezewells may be a factor in the determination of the coldest temperature ofthe formation refrigerant used to form the low temperature zone aroundthe treatment area. Carbon steel may be used as a construction materialof freeze wells. ASTM A333 grade 6 steel alloys and ASTM A333 grade 3steel alloys may be used for low temperature applications. ASTM A333grade 6 steel alloys typically contain little or no nickel and have alow working temperature limit of about −50° C. ASTM A333 grade 3 steelalloys typically contain nickel and have a much colder low workingtemperature limit. The nickel in the ASTM A333 grade 3 alloy addsductility at cold temperatures, but also significantly raises the costof the metal. In some embodiments, the coldest temperature of therefrigerant is from about −35° C. to about −55° C., from about −38° C.to about −47° C., or from about −40° C. to about −45° C. to allow forthe use of ASTM A333 grade 6 steel alloys for construction of canistersfor freeze wells. Stainless steels, such as 304 stainless steel, may beused to form freeze wells, but the cost of stainless steel is typicallymuch more than the cost of ASTM A333 grade 6 steel alloy.

A refrigeration unit may be used to reduce the temperature of formationrefrigerant to the low working temperature. In some embodiments, therefrigeration unit may utilize an ammonia vaporization cycle.Refrigeration units are available from Cool Man Inc. (Milwaukee, Wis.),Gartner Refrigeration & Manufacturing (Minneapolis, Minn.), and othersuppliers. In some embodiments, a cascading refrigeration system may beutilized with a first stage of ammonia and a second stage of carbondioxide. The circulating refrigerant through the freeze wells may be 30%by weight ammonia in water (aqua ammonia). Alternatively, a single stagecarbon dioxide refrigeration system may be used.

FIG. 9 depicts an embodiment of refrigeration system 292 used to coolformation refrigerant that forms a low temperature zone around treatmentarea 294. Refrigeration system 292 may include a high stagerefrigeration system and a low stage refrigeration system arranged in acascade relationship. The high stage refrigeration system and the lowstage refrigeration system may utilize conventional vapor compressionrefrigeration cycles.

The high stage refrigeration system includes compressor 296, condenser298, expansion valve 300, and heat exchanger 302. In some embodiments,the high stage refrigeration system uses ammonia as the refrigerant. Thelow stage refrigeration system includes compressor 304, heat exchanger302, expansion valve 306, and heat exchanger 308. In some embodiments,the low stage refrigeration system uses carbon dioxide as therefrigerant. High stage refrigerant from high stage expansion valve 300cools low stage refrigerant exiting low stage compressor 304 in heatexchanger 302.

Low stage refrigerant exiting low stage expansion valve 306 is used tocool formation refrigerant in heat exchanger 308. The formationrefrigerant passes from heat exchanger 308 to storage vessel 310. Pump312 transports formation refrigerant from storage vessel 310 to freezewells 278 in formation 314. Refrigeration system 292 is operated so thatthe formation refrigerant from pump 312 is at the desired temperature.The desired temperature may be in the range from about −35° C. to about−55° C.

Formation refrigerant passes from the freeze wells 278 to storage vessel316. Pump 318 is used to transport the formation refrigerant fromstorage vessel 316 to heat exchanger 308. In some embodiments, storagevessel 310 and storage vessel 316 are a single tank with a warm side forformation refrigerant returning from the freeze wells, and a cold sidefor formation refrigerant from heat exchanger 308.

In some embodiments, a double barrier containment system is used toisolate a contained area. The double barrier containment system may beformed with a first barrier and a second barrier. The first barrier maybe formed around at least a portion of the contained zone to inhibitfluid from entering or exiting the contained zone. The second barriermay be formed around at least a portion of the first barrier to isolatean inter-barrier zone between the first barrier and the second barrier.In some embodiments, the treatment area of the in situ conversionprocess is a portion of the contained zone. The double barriercontainment system may allow greater project depths than a singlebarrier containment system. Greater depths are possible with the doublebarrier containment system because the stepped differential pressuresacross the first barrier and the second barrier is less than thedifferential pressure across a single barrier. The smaller differentialpressures across the first barrier and the second barrier make a breachof the double barrier containment system less likely to occur at depthfor the double barrier containment system as compared to the singlebarrier containment system.

The double barrier containment system reduces the probability that abarrier breach will affect the contained zone or the formation on theoutside of the double barrier. That is, the probability that thelocation and/or time of occurrence of the breach in the first barrierwill coincide with the location and/or time of occurrence of the breachin the second barrier is low, especially if the distance between thefirst barrier and the second barrier is relatively large (for example,greater than about 15 m). Having a double barrier may reduce oreliminate influx of fluid into the contained zone following a breach ofthe first barrier or the second barrier. The contained zone may not beaffected if the second barrier breaches. If the first barrier breaches,only a portion of the fluid in the inter-barrier zone is able to enterthe contained zone. Also, fluid from the contained zone will not passthe second barrier. Recovery from a breach of a barrier of the doublebarrier containment system may require less time and fewer resourcesthan recovery from a breach of a single barrier containment system. Forexample, reheating a contained zone following a breach of a doublebarrier containment system may require less energy than reheating asimilarly sized contained zone following a breach of a single barriercontainment system.

The first barrier and the second barrier may be the same type of barrieror different types of barriers. In some embodiments, the first barrierand the second barrier are formed by freeze wells. In some embodiments,the first barrier is formed by freeze wells, and the second barrier is agrout wall. The grout wall may be formed of cement, sulfur, sulfurcement, or combinations thereof. In some embodiments, a portion of thefirst barrier and/or a portion of the second barrier is a naturalbarrier, such as an impermeable rock formation.

FIG. 10 depicts an embodiment of double barrier containment system 320.The perimeter of contained zone 322 may be surrounded by first barrier324. First barrier 324 may be surrounded by second barrier 326.Inter-barrier zones 328 may be isolated between first barrier 324,second barrier 326 and partitions 330. Creating sections with partitions330 between first barrier 324 and second barrier 326 limits the amountof fluid held in individual inter-barrier zones 328. Partitions 330 maystrengthen double barrier containment system 320. In some embodiments,the double barrier containment system may not include any partitions.

The inter-barrier zone may have a thickness from about 1 m to about 300m. In some embodiments, the thickness of the inter-barrier zone is fromabout 10 m to about 100 m, or from about 20 m to about 50 m.

Pumping/monitor wells 332 may be positioned in contained zone 322,inter-barrier zones 328, and/or outer zone 334 outside of second barrier326. Pumping/monitor wells 332 allow for removal of fluid from containedzone 322, inter-barrier zones 328, or outer zone 334. Pumping/monitorwells 332 also allow for monitoring of fluid levels in contained zone322, inter-barrier zones 328, and outer zone 334.

In some embodiments, a portion of contained zone 322 is heated by heatsources. The closest heat sources to first barrier 324 may be installeda desired distance away from the first barrier. In some embodiments, thedesired distance between the closest heat sources and first barrier 324is in a range between about 5 m and about 300 m, between about 10 m andabout 200 m, or between about 15 m and about 50 m. For example, thedesired distance between the closest heat sources and first barrier 324may be about 40 m.

FIG. 11 depicts a cross-sectional view of double barrier containmentsystem 320 used to isolate contained zone 322 in formation 314.Formation 314 may include one or more fluid bearing zones 336 and one ormore impermeable zones 338. First barrier 324 may at least partiallysurround contained zone 322. Second barrier 326 may at least partiallysurround first barrier 324. In some embodiments, impermeable zones 338are located above and/or below contained zone 322. Thus, contained zone322 is sealed around the sides and from the top and bottom. In someembodiments, one or more paths 340 are formed to allow communicationbetween two or more fluid bearing zones 336 in contained zone 322. Fluidin contained zone 322 may be pumped from the zone. Fluid ininter-barrier zone 328 and fluid in outer zone 334 is inhibited fromreaching the contained zone. During in situ conversion of hydrocarbonsin contained zone 322, formation fluid generated in the contained zoneis inhibited from passing into inter-barrier zone 328 and outer zone334.

After sealing contained zone 322, fluid levels in a given fluid bearingzone 336 may be changed so that the fluid head in inter-barrier zone 328and the fluid head in outer zone 334 are different. The amount of fluidand/or the pressure of the fluid in individual fluid bearing zones 336may be adjusted after first barrier 324 and second barrier 326 areformed. Having different fluid head levels in contained zone 322, fluidbearing zones 336 in inter-barrier zone 328, and in the fluid bearingzones in outer zone 334 allows for determination of the occurrence of abreach in first barrier 324 and/or second barrier 326. In someembodiments, the differential pressure across first barrier 324 andsecond barrier 326 is adjusted to reduce stresses applied to firstbarrier 324 and/or second barrier 326, or stresses on certain strata ofthe formation.

Some fluid bearing zones 336 may contain native fluid that is difficultto freeze because of a high salt content or compounds that reduce thefreezing point of the fluid. If first barrier 324 and/or second barrier326 are low temperature zones established by freeze wells, the nativefluid that is difficult to freeze may be removed from fluid bearingzones 336 in inter-barrier zone 328 through pumping/monitor wells 332.The native fluid is replaced with a fluid that the freeze wells are ableto more easily freeze.

In some embodiments, pumping/monitor wells 332 may be positioned incontained zone 322, inter-barrier zone 328, and/or outer zone 334.Pumping/monitor wells 332 may be used to test for freeze completion offrozen barriers and/or for pressure testing frozen barriers and/orstrata. Pumping/monitor wells 332 may be used to remove fluid and/or tomonitor fluid levels in contained zone 322, inter-barrier zone 328,and/or outer zone 334. Using pumping/monitor wells 332 to monitor fluidlevels in contained zone 322, inter-barrier zone 328, and/or outer zone334 may allow detection of a breach in first barrier 324 and/or secondbarrier 326. Pumping/monitor wells 332 allow pressure in contained zone322, each fluid bearing zone 336 in inter-barrier zone 328, and eachfluid bearing zone in outer zone 334 to be independently monitored sothat the occurrence and/or the location of a breach in first barrier 324and/or second barrier 326 can be determined.

In some embodiments, fluid pressure in inter-barrier zone 328 ismaintained greater than the fluid pressure in contained zone 322, andless than the fluid pressure in outer zone 334. If a breach of firstbarrier 324 occurs, fluid from inter-barrier zone 328 flows intocontained zone 322, resulting in a detectable fluid level drop in theinter-barrier zone. If a breach of second barrier 326 occurs, fluid fromthe outer zone flows into inter-barrier zone 328, resulting in adetectable fluid level rise in the inter-barrier zone.

A breach of first barrier 324 may allow fluid from inter-barrier zone328 to enter contained zone 322. FIG. 12 depicts breach 342 in firstbarrier 324 of double barrier containment system 320. Arrow 344indicates flow direction of fluid 346 from inter-barrier zone 328 tocontained zone 322 through breach 342. The fluid level in fluid bearingzone 336 proximate breach 342 of inter-barrier zone 328 falls to theheight of the breach.

Path 340 allows fluid 346 to flow from breach 342 to the bottom ofcontained zone 322, increasing the fluid level in the bottom of thecontained zone. The volume of fluid that flows into contained zone 322from inter-barrier zone 328 is typically small compared to the volume ofthe contained zone. The volume of fluid able to flow into contained zone322 from inter-barrier zone 328 is limited because second barrier 326inhibits recharge of fluid 346 into the affected fluid bearing zone. Insome embodiments, the fluid that enters contained zone 322 may be pumpedfrom the contained zone using pumping/monitor wells 332 in the containedzone. In some embodiments, the fluid that enters contained zone 322 maybe evaporated by heaters in the contained zone that are part of the insitu conversion process system. The recovery time for the heated portionof contained zone 322 from cooling caused by the introduction of fluidfrom inter-barrier zone 328 is brief. The recovery time may be less thana month, less than a week, or less than a day.

Pumping/monitor wells 332 in inter-barrier zone 328 may allow assessmentof the location of breach 342. When breach 342 initially forms, fluidflowing into contained zone 322 from fluid bearing zone 336 proximatethe breach creates a cone of depression in the fluid level of theaffected fluid bearing zone in inter-barrier zone 328. Time analysis offluid level data from pumping/monitor wells 332 in the same fluidbearing zone as breach 342 can be used to determine the general locationof the breach.

When breach 342 of first barrier 324 is detected, pumping/monitor wells332 located in the fluid bearing zone that allows fluid to flow intocontained zone 322 may be activated to pump fluid out of theinter-barrier zone. Pumping the fluid out of the inter-barrier zonereduces the amount of fluid 346 that can pass through breach 342 intocontained zone 322.

Breach 342 may be caused by ground shift. If first barrier 324 is a lowtemperature zone formed by freeze wells, the temperature of theformation at breach 342 in the first barrier is below the freezing pointof fluid 346 in inter-barrier zone 328. Passage of fluid 346 frominter-barrier zone 328 through breach 342 may result in freezing of thefluid in the breach and self-repair of first barrier 324.

A breach of the second barrier may allow fluid in the outer zone toenter the inter-barrier zone. The first barrier may inhibit fluidentering the inter-barrier zone from reaching the contained zone. FIG.13 depicts breach 342 in second barrier 326 of double barriercontainment system 320. Arrow 344 indicates flow direction of fluid 346from outside of second barrier 326 to inter-barrier zone 328 throughbreach 342. As fluid 346 flows through breach 342 in second barrier 326,the fluid level in the portion of inter-barrier zone 328 proximate thebreach rises from initial level 348 to a level that is equal to level350 of fluid in the same fluid bearing zone in outer zone 334. Anincrease of fluid 346 in fluid bearing zone 336 may be detected bypumping/monitor well 332 positioned in the fluid bearing zone proximatebreach 342.

Breach 342 may be caused by ground shift. If second barrier 326 is a lowtemperature zone formed by freeze wells, the temperature of theformation at breach 342 in the second barrier is below the freezingpoint of fluid 346 entering from outer zone 334. Fluid from outer zone334 in breach 342 may freeze and self-repair second barrier 326.

First barrier and second barrier of the double barrier containmentsystem may be formed by freeze wells. In an embodiment, first barrier isformed first. The cooling load needed to maintain the first barrier issignificantly less than the cooling load needed to form the firstbarrier. After formation of the first barrier, the excess coolingcapacity that the refrigeration system used to form the first barriermay be used to form a portion of the second barrier. In someembodiments, the second barrier is formed first and the excess coolingcapacity that the refrigeration system used to form the second barrieris used to form a portion of the first barrier. After the first andsecond barriers are formed, excess cooling capacity supplied by therefrigeration system or refrigeration systems used to form the firstbarrier and the second barrier may be used to form a barrier or barriersaround the next contained zone that is to be processed by the in situconversion process.

Grout may be used in combination with freeze wells to provide a barrierfor the in situ conversion process. The grout fills cavities (vugs) inthe formation and reduces the permeability of the formation. Grout mayhave better thermal conductivity than gas and/or formation fluid thatfills cavities in the formation. Placing grout in the cavities may allowfor faster low temperature zone formation. The grout forms a perpetualbarrier in the formation that may strengthen the formation. The use ofgrout in unconsolidated or substantially unconsolidated formationmaterial may allow for larger well spacing than is possible without theuse of grout. The combination of grout and the low temperature zoneformed by freeze wells may constitute a double barrier for environmentalregulation purposes.

Grout may be injected into the formation at a pressure that is high, butbelow the fracture pressure of the formation. Grout may be applied tothe formation from a freeze wellbore. In some embodiments, grouting isperformed in 50 foot increments in the freeze wellbore. Larger orsmaller increments may be used if desired. In some embodiments, grout isonly applied to certain portions of the formation. For example, groutmay be applied to the formation through the freeze wellbore onlyadjacent to aquifer zones and/or to relatively high permeability zones(for example, zones with a permeability greater than about 0.1 darcy).Applying grout to aquifers may inhibit water from one aquifer migratingto a different aquifer when an established low temperature zone thaws.

Grout used in the formation may be any type of grout including, but notlimited to, fine cement, micro fine cement, sulfur, sulfur cement,viscous thermoplastics, or combinations thereof. Fine cement may be ASTMtype 3 Portland cement. Fine cement may be less expensive than microfine cement. In an embodiment, a freeze wellbore is formed in theformation. Selected portions of the freeze wellbore are grouted usingfine cement. Then, micro fine cement is injected into the formationthrough the freeze wellbore. The fine cement may reduce the permeabilitydown to about 10 millidarcy. The micro fine cement may further reducethe permeability to about 0.1 millidarcy. After the grout is introducedinto the formation, a freeze wellbore canister may be inserted into theformation. The process may be repeated for each freeze well that will beused to form the barrier.

In some embodiments, fine cement is introduced into every other freezewellbore. Micro fine cement is introduced into the remaining wellbores.For example, grout may be used in a formation with freeze wellbores setat about 5 m spacing. A first wellbore is drilled and fine cement isintroduced into the formation through the wellbore. A freeze wellcanister is positioned in the first wellbore. A second wellbore isdrilled 10 m away from the first wellbore. Fine cement is introducedinto the formation through the second wellbore. A freeze well canisteris positioned in the second wellbore. A third wellbore is drilledbetween the first wellbore and the second wellbore. In some embodiments,grout from the first and/or second wellbores may be detected in thecuttings of the third wellbore. Micro fine cement is introduced into theformation through the third wellbore. A freeze wellbore canister ispositioned in the third wellbore. The same procedure is used to form theremaining freeze wells that will form the barrier around the treatmentarea.

A temperature monitoring system may be installed in wellbores of freezewells and/or in monitor wells adjacent to the freeze wells to monitorthe temperature profile of the freeze wells and/or the low temperaturezone established by the freeze wells. The monitoring system may be usedto monitor progress of low temperature zone formation. The monitoringsystem may be used to determine the location of high temperature areas,potential breakthrough locations, or breakthrough locations after thelow temperature zone has formed. Periodic monitoring of the temperatureprofile of the freeze wells and/or low temperature zone established bythe freeze wells may allow additional cooling to be provided topotential trouble areas before breakthrough occurs. Additional coolingmay be provided at or adjacent to breakthroughs and high temperatureareas to ensure the integrity of the low temperature zone around thetreatment area. Additional cooling may be provided by increasingrefrigerant flow through selected freeze wells, installing an additionalfreeze well or freeze wells, and/or by providing a cryogenic fluid, suchas liquid nitrogen, to the high temperature areas. Providing additionalcooling to potential problem areas before breakthrough occurs may bemore time efficient and cost efficient than sealing a breach, reheatinga portion of the treatment area that has been cooled by influx of fluid,and/or remediating an area outside of the breached frozen barrier.

In some embodiments, a traveling thermocouple may be used to monitor thetemperature profile of selected freeze wells or monitor wells. In someembodiments, the temperature monitoring system includes thermocouplesplaced at discrete locations in the wellbores of the freeze wells, inthe freeze wells, and/or in the monitoring wells. In some embodiments,the temperature monitoring system comprises a fiber optic temperaturemonitoring system.

Fiber optic temperature monitoring systems are available from Sensornet(London, United Kingdom), Sensa (Houston, Tex.), Luna Energy(Blacksburg, Va.), Lios Technology GMBH (Cologne, Germany), OxfordElectronics Ltd. (Hampshire, United Kingdom), and Sabeus Sensor Systems(Calabasas, Calif.). The fiber optic temperature monitoring systemincludes a data system and one or more fiber optic cables. The datasystem includes one or more lasers for sending light to the fiber opticcable; and one or more computers, software and peripherals forreceiving, analyzing, and outputting data. The data system may becoupled to one or more fiber optic cables.

A single fiber optic cable may be several kilometers long. The fiberoptic cable may be installed in many freeze wells and/or monitor wells.In some embodiments, two fiber optic cables may be installed in eachfreeze well and/or monitor well. The two fiber optic cables may becoupled together. Using two fiber optic cables per well allows forcompensation due to optical losses that occur in the wells and allowsfor better accuracy of measured temperature profiles.

A fiber of a fiber optic cable may be placed in a polymer tube. Thepolymer tube may be filled with a heat transfer fluid. The heat transferfluid may be a gel or liquid that does not freeze at or above thetemperature of formation refrigerant used to cool the formation. In someembodiments the heat transfer fluid in the polymer tube is the same asthe formation refrigerant, for example, a fluid available from Dynalene®Heat Transfer Fluids or aqua ammonia. In some embodiments, the fiber isblown into the tube using the heat transfer fluid. Using the heattransfer fluid to insert the fiber into the polymer tube removesmoisture from the polymer tube.

The polymer tube and fiber may be placed in stainless steel tubing, suchas ¼ inch 304 stainless steel tubing, to form the fiber optic cable. Thestainless steel tubing may be prestressed to accommodate thermalcontraction at low temperatures. The stainless steel tubing may befilled with the heat transfer fluid. In some embodiments, the polymertube is blown into the stainless steel tubing with the heat transferfluid. Using the heat transfer fluid to insert the polymer tube andfiber into the stainless steel tubing removes moisture from thestainless steel tubing. In some embodiments, two fibers are positionedin the same stainless steel tubing.

In some embodiments, the fiber optic cable is strapped to the canisterof the freeze well as the canister is inserted into the formation. Thefiber optic cable may be coiled around the canister adjacent to theportions of the formation that are to be reduced to low temperature toform the low temperature zone. Coiling the fiber optic cable around thecanister allows a large length of the fiber optic cable to be adjacentto areas that are to be reduced to low temperature. The large lengthallows for better resolution of the temperature profile for the areas tobe reduced to low temperatures. In some embodiments, the fiber opticcable is placed in the canister of the freeze well.

FIG. 14 depicts a schematic representation of a fiber optic temperaturemonitoring system. Data system 352 includes laser 354 and analyzer 356.Laser 354 injects short, intense laser pulses into fiber optic cable358. Fiber optic cable 358 is positioned in plurality of freeze wells278 and monitor wells 360. Backscattering and reflection of light infiber optic cable 358 may be measured as a function of time by analyzer356 of the data system 352. Analysis of the backscattering andreflection of light data yields a temperature profile along the lengthof fiber optic cable 358.

In some embodiments, the fiber optic temperature monitoring systemutilizes Brillouin or Raman scattering systems. Such systems providespatial resolution of about 1 m and temperature resolution of about 0.1°C. With sufficient averaging and temperature calibration, the systemsmay be accurate to about 0.5° C.

In some embodiments, the fiber optic temperature monitoring system maybe a Bragg system that uses a fiber optic cable etched with closelyspaced Bragg gratings. The Bragg gratings may be formed in 1 footincrements along selected lengths of the fiber. Fibers with Bragggratings are available from Luna Energy. The Bragg system only requiresa single fiber optic cable to be placed in each well that is to bemonitored. The Bragg system is able to measure the fiber temperature ina few seconds.

The fiber optic temperature monitoring system may be used to detect thelocation of a breach or a potential breach. The search for potentialbreaches may be performed at scheduled intervals, for example, every twoor three months. To determine the location of the breach or potentialbreach, flow of formation refrigerant to the freeze wells of interest isstopped. In some embodiments, the flow of formation refrigerant to allof the freeze wells is stopped. The rise in the temperature profiles aswell as the rate of change of the temperature profiles provided by thefiber optic temperature monitoring system for each freeze well can beused to determine the location of any breaches or hot spots in the lowtemperature zone maintained by the freeze wells. The temperature profilemonitored by the fiber optic temperature monitoring system for the twofreeze wells closest to the hot spot or fluid flow will show thequickest and greatest change in temperature. A temperature change of afew degrees Centigrade in the temperature profiles of the freeze wellsclosest to a troubled area may be sufficient to isolate the location ofthe trouble area. The shut down time of flow of circulation fluid in thefreeze wells of interest needed to detect breaches, potential breaches,and hot spots may be on the order of a few hours or days, depending onthe well spacing and the amount of fluid flow affecting the lowtemperature zone.

Fiber optic temperature monitoring systems may also be used to monitortemperatures in heated portions of the formation during in situconversion processes. The fiber of a fiber optic cable used in theheated portion of the formation may be clad with a reflective materialto facilitate retention of a signal or signals transmitted down thefiber. In some embodiments, the fiber is clad with gold, copper, nickel,and/or alloys thereof. The cladding may be formed of a material that isable to withstand chemical and temperature conditions in the heatedportion of the formation. For example, gold cladding may allow anoptical sensor to be used up to temperatures of about 700° C. In someembodiments, the fiber is clad with nickel. The fiber may be dipped inor run through a bath of liquid nickel. The clad fiber may then beallowed to cool to secure the nickel to the fiber.

In some embodiments, heaters that heat hydrocarbons in the formation maybe close to the low temperature zone established by freeze wells. Insome embodiments, heaters may be may be 20 m, 10 m, 5 m or less from anedge of the low temperature zone established by freeze wells. In someembodiments, heat interceptor wells may be positioned between the lowtemperature zone and the heaters to reduce the heat load applied to thelow temperature zone from the heated part of the formation. FIG. 15depicts a schematic view of the well layout plan for heater wells 362,production wells 214, heat interceptor wells 364, and freeze wells 278for a portion of an in situ conversion system embodiment. Heatinterceptor wells 364 are positioned between heater wells 362 and freezewells 278.

Some heat interceptor wells may be formed in the formation specificallyfor the purpose of reducing the heat load applied to the low temperaturezone established by freeze wells. Some heat interceptor wells may beheater wellbores, monitor wellbores, production wellbores, dewateringwellbores or other type of wellbores that are converted for use as heatinterceptor wells.

In some embodiments, heat interceptor wells may function as heat pipesto reduce the heat load applied to the low temperature zone. A liquidheat transfer fluid may be placed in the heat interceptor wellbores. Theliquid may include, but is not limited to, water, alcohol, and/oralkanes. Heat supplied to the formation from the heaters may advance tothe heat interceptor wellbores and vaporize the liquid heat transferfluid in the heat interceptor wellbores. The resulting vapor may rise inthe wellbores. Above the heated portion of the formation adjacent to theoverburden, the vapor may condense and flow by gravity back to the areaadjacent to the heated part of the formation. The heat absorbed bychanging the phase of the liquid heat transfer fluid reduces the heatload applied to the low temperature zone. Using heat interceptor wellsthat function as heat pipes may be advantageous for formations withthick overburdens that are able to absorb the heat applied as the heattransfer fluid changes phase from vapor to liquid. The wellbore mayinclude wicking material, packing to increase surface area adjacent to aportion of the overburden, or other material to promote heat transfer toor from the formation and the heat transfer fluid.

In some embodiments, a heat transfer fluid is circulated through theheat interceptor wellbores in a closed loop system. A heat exchangerreduces the temperature of the heat transfer fluid after the heattransfer fluid leaves the heat interceptor wellbores. Cooled heattransfer fluid is pumped through the heat interceptor wellbores. In someembodiments, the heat transfer fluid does not undergo a phase changeduring use. In some embodiments, the heat transfer fluid may changephases during use. The heat transfer fluid may be, but is not limitedto, water, alcohol, and/or glycol.

A potential source of heat loss from the heated formation is due toreflux in wells. Refluxing occurs when vapors condense in a well andflow into a portion of the well adjacent to the heated portion of theformation. Vapors may condense in the well adjacent to the overburden ofthe formation to form condensed fluid. Condensed fluid flowing into thewell adjacent to the heated formation absorbs heat from the formation.Heat absorbed by condensed fluids cools the formation and necessitatesadditional energy input into the formation to maintain the formation ata desired temperature. Some fluids condensed in the overburden andflowing into the portion of the well adjacent to the heated formationmay react to produce undesired compounds and/or coke Inhibiting fluidsfrom refluxing may significantly improve the thermal efficiency of thein situ conversion system and/or the quality of the product producedfrom the in situ conversion system.

For some well embodiments, the portion of the well adjacent to theoverburden section of the formation is cemented to the formation. Insome well embodiments, the well includes packing material placed nearthe transition from the heated section of the formation to theoverburden. The packing material inhibits formation fluid from passingfrom the heated section of the formation into the section of thewellbore adjacent to the overburden. Cables, conduits, devices, and/orinstruments may pass through the packing material, but the packingmaterial inhibits formation fluid from passing up the wellbore adjacentto the overburden section of the formation.

The flow of production fluid up the well to the surface is desired forsome types of wells, especially for production wells. Flow of productionfluid up the well is also desirable for some heater wells that are usedto control pressure in the formation. The overburden, or a conduit inthe well, used to transport formation fluid from the heated portion ofthe formation to the surface may be heated to inhibit condensation on orin the conduit. Providing heat in the overburden, however, may be costlyand/or may lead to increased cracking or coking of formation fluid asthe formation fluid is being produced from the formation.

To avoid the need to heat the overburden or to heat the conduit passingthrough the overburden, one or more diverters may be placed in thewellbore to inhibit fluid from refluxing into the wellbore adjacent tothe heated portion of the formation. In some embodiments, the diverterretains fluid above the heated portion of the formation. Fluids retainedin the diverter may be removed from the diverter using a pump, gaslifting, and/or other fluid removal technique. In some embodiments, thediverter directs fluid to a pump, gas lift assembly, or other fluidremoval device located below the heated portion of the formation.

FIG. 16 depicts an embodiment of a diverter in a production well.Production well 214 includes conduit 366. In some embodiments, diverter368 is coupled to or located proximate production conduit 366 inoverburden 370. In some embodiments, the diverter is placed in theheated portion of the formation. Diverter 368 may be located at or nearan interface of overburden 370 and hydrocarbon layer 254. Hydrocarbonlayer 254 is heated by heat sources located in the formation. Diverter368 may include packing 372, riser 374, and seal 376 in productionconduit 366. Formation fluid in the vapor phase from the heatedformation moves from hydrocarbon layer 254 into riser 374. In someembodiments, riser 374 is perforated below packing 372 to facilitatemovement of fluid into the riser. Packing 372 inhibits passage of thevapor phase formation fluid into an upper portion of production well214. Formation fluid in the vapor phase moves through riser 374 intoproduction conduit 366. A non-condensable portion of the formation fluidrises through production conduit 366 to the surface. The vapor phaseformation fluid in production conduit 366 may cool as it rises towardsthe surface in the production conduit. If a portion of the vapor phaseformation fluid condenses to liquid in production conduit 366, theliquid flows by gravity towards seal 376. Seal 376 inhibits liquid fromentering the heated portion of the formation. Liquid collected aboveseal 376 is removed by pump 378 through conduit 380. Pump 378 may be,but is not limited to being, a sucker rod pump, an electrical pump, or aprogressive cavity pump (Moyno style). In some embodiments, liquid aboveseal 376 is gas lifted through conduit 380. Producing condensed fluidmay reduce costs associated with removing heat from fluids at thewellhead of the production well.

In some embodiments, production well 214 includes heater 382. Heater 382provides heat to vaporize liquids in a portion of production well 214proximate hydrocarbon layer 254. Heater 382 may be located in productionconduit 366 or may be coupled to the outside of the production conduit.In embodiments where the heater is located outside of the productionconduit, a portion of the heater passes through the packing material.

In some embodiments, a diluent may be introduced into production conduit366 and/or conduit 380. The diluent is used to inhibit clogging inproduction conduit 366, pump 378, and/or conduit 380. The diluent maybe, but is not limited to being, water, an alcohol, a solvent, or asurfactant.

In some embodiments, riser 374 extends to the surface of production well214. Perforations and a baffle in riser 374 located above seal 376direct condensed liquid from the riser into production conduit 366.

In certain embodiments, two or more diverters may be located in theproduction well. Two or more diverters provide a simple way ofseparating initial fractions of condensed fluid produced from the insitu conversion system. A pump may be placed in each diverters to removecondensed fluid from the diverters.

In some embodiments, fluids (gases and liquids) may be directed towardsthe bottom of the production well using the diverter. The fluids may beproduced from the bottom of the production well. FIG. 17 depicts anembodiment of the diverter that directs fluid towards the bottom of theproduction well. Diverter 368 may include packing material 372 andbaffle 384 positioned in production conduit 366. Baffle may be a pipepositioned around conduit 380. Production conduit 366 may have openings386 that allow fluids to enter the production conduit from hydrocarbonlayer 254. In some embodiments, all or a portion of the openings areadjacent to a non-hydrocarbon layer of the formation through whichheated formation fluid flows. Openings 386 include, but are not limitedto, screens, perforations, slits, and/or slots. Hydrocarbon layer 254may be heated using heaters located in other portions of the formationand/or a heater located in production conduit 366.

Baffle 384 and packing material 372 direct formation fluid enteringproduction conduit 366 to unheated zone 388. Unheated zone 388 is in theunderburden of the formation. A portion of the formation fluid maycondense on the outer surface of baffle 384 or on walls of productionconduit 366 adjacent to unheated zone 388. Liquid fluid from theformation and/or condensed fluid may flow by gravity to a bottom portionof production conduit 366. Liquid and condensate in the bottom portionof production conduit 366 may be pumped to the surface through conduit380 using pump 378. Pump 378 may be placed 1 m, 5 m, 10 m, 20 m or moreinto the underburden. In some embodiments, the pump may be placed in anon-cased (open) portion of the wellbore. Non-condensed fluid initiallytravels through the annular space between baffle 384 and conduit 380,and then through the annular space between production conduit 366 andconduit 380 to the surface, as indicated by arrows in FIG. 17. If aportion of the non-condensed fluid condenses adjacent to overburden 370while traveling to the surface, the condensed fluid will flow by gravitytoward the bottom portion of production conduit 366 to the intake forpump 378. Heat absorbed by the condensed fluid as the fluid passesthrough the heated portion of the formation is from contact with baffle384, not from direct contact with the formation. Baffle 384 is heated byformation fluid and radiative heat transfer from the formation.Significantly less heat from the formation is transferred to thecondensed fluid as the fluid flows through baffle 384 adjacent to theheated portion than if the condensed fluid was able to contact theformation. The condensed fluid flowing down the baffle may absorb enoughheat from the vapor in the wellbore to condense a portion of the vaporon the outer surface of baffle 384. The condensed portion of the vapormay flow down the baffle to the bottom portion of the wellbore.

In some embodiments, diluent may be introduced into production conduit366 and/or conduit 380. The diluent is used to inhibit clogging inproduction conduit 366, pump 378, and conduit 380. The diluent mayinclude, but is not limited to, water, an alcohol, a solvent, asurfactant, or combinations thereof. Different diluents may beintroduced at different times. For example, a solvent may be introducedwhen production first begins to put into solution high molecular weighthydrocarbons that are initially produced from the formation. At a latertime, water may be substituted for the solvent.

In some embodiments, a separate conduit may introduce the diluent to thewellbore near the underburden, as depicted in FIG. 18. Productionconduit 366 directs vapor produced from the formation to the surfacethrough overburden 370. If a portion of the vapor condenses inproduction conduit 366, the condensate can flow down baffle 384 to theintake for pump 378. Diverter 368, comprising packing material 372 andbaffle 384, directs formation fluid flow from heated hydrocarbon layer254 to unheated zone 388. Liquid formation fluid is transported by pump378 through conduit 380 to the surface. Vapor formation fluid istransported through baffle 384 to production conduit 366. Conduit 390may be strapped to baffle 384. Conduit 390 may introduce the diluent towellbore 392 adjacent to unheated zone 388. The diluent may promotecondensation of formation fluid and/or inhibit clogging of pump 378.Diluent in conduit 390 may be at a high pressure. If the diluent changesphase from liquid to vapor while passing through the heated portion ofthe formation, the change in pressure as the diluent leaves conduit 390allows the diluent to condense.

Some formation layers may have material characteristics that lead tosloughing in a wellbore. For example, lean clay-rich layers of an oilshale formation may slough when heated. Sloughing refers to the sheddingor casting off of formation material (for example, rock or clay) intothe wellbore. Layers rich in expanding clays (for example, smectites orillites) have a high tendency for sloughing. Clays may reducepermeability in lean layers. When heat is rapidly provided to layerswith reduced permeability, water and/or other fluids may be unable toescape from the layer. Water and/or other fluids that cannot escape thelayer build up pressure in the layer until the pressure causes amechanical failure of material. This mechanical failure occurs when theinternal pressure exceeds the tensile strength of rock in the layer andproduces sloughing.

Sloughing of material in the wellbore may lead to overheating, plugging,equipment deformation, and/or fluid flow problems in the wellbore.Sloughed material may catch or be trapped in or around the heater in thewellbore. For example, sloughed material may get trapped between theheater and the wall of the formation above an expanded rich layer thatcontacts or approaches the heater. The sloughed material may be looselypacked and have low thermal conductivity. Low thermal conductivitysloughed material may lead to overheating of the heater and/or slow heattransfer to the formation. Sloughed material in a hydrocarbon containingformation (such as an oil shale formation) may have an average particlediameter between 1 millimeter (“mm”) and 2.5 centimeter (“cm”), between1.5 mm and 2 cm, or between 5 mm and 1 cm.

Volumes of the subsurface formation with very low permeability (forexample, 10 microdarcy (“μdarcy”) or less, 20 μdarcy or less, or 50μdarcy or less) may have a tendency to slough. For oil shale, thesevolumes are typically lean layers with clay contents of 5% by volume orgreater. The clay may be smectite clay or illite clay. Material involumes with very low permeability may rubbilize during heating of thesubsurface formation. The rubbilization may be caused by expansion ofclay bound water, other clay bound fluids, and/or gases in the rockmatrix.

Several techniques may be used to inhibit sloughing or problemsassociated with sloughing. The techniques include initially heating thewellbore so that there is an initial slow temperature increase in thenear wellbore region, pretreating the wellbore with a stabilizing fluidprior to heating, providing a controlled explosion in the wellbore priorto heating, placing a liner or screen in the wellbore, and sizing thewellbore and equipment placed in the wellbore so that sloughed materialdoes not cause problems in the wellbore. The various techniques may beused independently or in combination with each other.

In some embodiments, the permeability of a volume (a zone) of thesubsurface formation is assessed. In certain embodiments, clay contentof the zone of the subsurface formation is assessed. The volume or zonesof assessed permeability and/or clay content are at or near a wellbore(for example, within 1 m, 0.5 m, or 0.3 m of the wellbore). Thepermeability may be assessed by, for example, Stoneley wave attenuationacoustic logging. Clay content may be assessed by, for example, a pulsedneutron logging system, such as RST (Reservoir Saturation Tool) loggingfrom Schlumberger Oilfield Services (Houston, Tex.). The clay content isassessed from the difference between density and neutron logs. If theassessment shows that one or more zones near the wellbore have apermeability below a selected value (for example, at most 10 μdarcy, atmost 20 μdarcy, or at most 50 μdarcy) and/or a clay content above aselected value (for example, at least 5% by volume, at least 3% byvolume, or at least 2% by volume), initial heating of the formation ator near the wellbore may be controlled to maintain the heating ratebelow a selected value. The selected heating rate varies depending ontype of formation, pattern of wellbores in the formation, type of heaterused, spacing of wellbores in the formation, or other factors.

Initial heating may be maintained at or below the selected heating ratefor a specified length of time. After a certain amount of time, thepermeability at or near the wellbores may increase to a value such thatsloughing is no longer likely to occur due to slow expansion of gases inthe layer. Slower heating rates allow time for water or other fluids tovaporize and escape the layer, inhibiting rapid pressure buildup in thelayer. A slow initial heating rate allows expanding water vapor andother fluids to create microfractures in the formation instead ofwellbore failure, which may occur when the formation is heated rapidly.As a heat front moves away from the wellbore, the rate of temperaturerise lessens. For example, the rate of temperature rise is typicallygreatly reduced at distances of 0.1 m, 0.3 m, 0.5 m, 1 m, 3 m, orgreater from the wellbore. In certain embodiments, the heating rate of asubsurface formation at or near the wellbore (for example, within 3 m ofthe wellbore, within 1 m of the wellbore, within 0.5 m of the wellbore,or within 0.3 m of the wellbore) is maintained below 20° C./day for atleast 15 days. In some embodiments, the heating rate of a subsurfaceformation at or near the wellbore is maintained below 10° C./day for atleast 30 days. In some embodiments, the heating rate of a subsurfaceformation at or near the wellbore is maintained below 5° C./day for atleast 60 days. In some embodiments, the heating rate of a subsurfaceformation at or near the wellbore is maintained below 2° C./day for atleast 150 days.

In certain embodiments, the wellbore in the formation that has zones orareas that lead to sloughing is pretreated to inhibit sloughing duringheating. The wellbore may be treated before the heater is placed in thewellbore. In some embodiments, the wellbore with a selected clay contentis treated with one or more clay stabilizers. For example, claystabilizers may be added to a brine solution used during formation of awellbore. Clay stabilizers include, but are not limited to, lime orother calcium containing materials well known in the oilfield industry.In some embodiments, the use of clay stabilizers that include halogensis limited (or avoided) to reduce (or avoid) corrosion problems with theheater or other equipment used in the wellbore.

In certain embodiments, the wellbore is treated by providing acontrolled explosion in the wellbore. The controlled explosion may beprovided along selected lengths or in selected sections of the wellbore.The controlled explosion is provided by placing the controlled explosivesystem into the wellbore. The controlled explosion may be implemented bycontrolling the velocity of vertical propagation of the explosion in thewellbore. One example of a controlled explosive system is Primacord®explosive cord available from The Ensign-Bickford Company (Spanish Fork,Utah). A controlled explosive system may be set to explode alongselected lengths or selected sections of a wellbore. The explosivesystem may be controlled to limit the amount of explosion in thewellbore.

FIG. 19 depicts an embodiment for providing a controlled explosion in anopening. Opening 252 is formed in hydrocarbon layer 254. Explosivesystem 394 is placed in opening 252. In an embodiment, explosive system394 includes Primacord®. In certain embodiments, explosive system 394has explosive section 396. In some embodiments, explosive section 396 islocated proximate layers with a relatively high clay content and/orlayers with very low permeability that are to be heated (such as leanlayers 398). In some embodiments, a non-explosive portion of explosivesystem 394 may be located proximate layers rich in hydrocarbons and lowin clay content (such as rich layers 400). In some embodiments, theexplosive portion may extend adjacent to lean layers 398 and rich layers400. Explosive section 396 may be controllably exploded at or near thewellbore.

FIG. 20 depicts an embodiment of an opening after the controlledexplosion in the opening. The controlled explosion increases thepermeability of zones 402. In certain embodiments, zones 402 have awidth between 0.1 m and 3 m, between 0.2 m and 2 m, or between 0.3 m and1 m extending outward from the wall of opening 252 into lean layers 398and rich layers 400. In one embodiment, the width is 0.3 m. Thepermeabilities of zones 402 are increased by microfracturing in thezones. After zones 402 have been created, heater 404 is installed inopening 252. In some embodiments, rubble formed by the controlledexplosion in opening 252 is removed (for example, drilled out or scoopedout) before installing heater 404 in the opening. In some embodiments,opening 252 is drilled deeper (drilled beyond a needed length) beforeinitiating a controlled explosion. The overdrilled opening may allowrubble from the explosion to fall into the extra portion (the bottom) ofthe opening, and thus inhibit interference of rubble with a heaterinstalled in the opening.

Providing the controlled explosion in the wellbore createsmicrofracturing and increases permeability of the formation in a regionnear the wellbore. In an embodiment, the controlled explosion createsmicrofracturing with limited or no rubbilization of material in theformation. The increased permeability allows gas release in theformation during early stages of heating. The gas release inhibitsbuildup of gas pressure in the formation that may cause sloughing ofmaterial in the near wellbore region.

In certain embodiments, the increased permeability created by providingthe controlled explosion is advantageous in early stages of heating aformation. In some embodiments, the increased permeability includesincreased horizontal permeability and increased vertical permeability.The increased vertical permeability may connect layers (such as rich andlean layers) in the formation. As shown by the arrows in FIG. 20, fluidsproduced in rich layers 400 from heat provided by heater 404 flow fromrich layers to lean layers 398 through zones 402. The increasedpermeability of zones 402 facilitates flow from rich layers 400 to leanlayers 398. Fluids in lean layers 398 flow to the production wellbore ora lower temperature wellbore for production. This flow pattern inhibitsfluids from being overheated by heater 404. Overheating of fluids byheater 404 may lead to coking in or at opening 252. Zones 402 havewidths that extend beyond a coking radius from a wall of opening 252 toallow fluids to flow coaxially or parallel to the opening at a distanceoutside the coking radius. Reducing heating of the fluids may alsoimprove product quality by inhibiting thermal cracking and theproduction of olefins and other low quality products. More heat may beprovided to hydrocarbon layer 254 at a higher rate by heater 404 duringearly stages of heating because formation fluids flow from zones 402 andthrough lean layers 398.

In certain embodiments, a perforated liner (or a perforated conduit) isplaced in the wellbore outside of the heater to inhibit sloughedmaterial from contacting the heater. FIG. 21 depicts an embodiment of aliner in the opening. In certain embodiments, liner 406 is made ofcarbon steel or stainless steel. In some embodiments, liner 406 inhibitsexpanded material from deforming heater 404. Liner 406 has a diameterthat is only slightly smaller than an initial diameter of opening 252.Liner 406 has openings 408 that allow fluid to pass through the liner.Openings 408 are, for example, slots or slits. Openings 408 are sized sothat fluids pass through liner 406 but sloughed material or otherparticles do not pass through the liner.

In some embodiments, liner 406 is selectively placed at or near layersthat may lead to sloughing (such as rich layers 400). For example,layers with relatively low permeability (for example, at most 10 μdarcy,at most 20 μdarcy, or at most 50 μdarcy) may lead to sloughing. Incertain embodiments, liner 406 is a screen, a wire mesh or other wireconstruction, and/or a deformable liner. For example, liner 406 may bean expandable tubular with openings 408. Liner 406 may be expanded witha mandrel or “pig” after installation of the liner into the opening.Liner 406 may deform or bend when the formation is heated, but sloughedmaterial from the formation will be too large to pass through openings408 in the liner.

In some embodiments, liner 406 is an expandable screen installed in theopening in a stretched configuration. Liner 406 may be relaxed followinginstallation. FIG. 22 depicts an embodiment of liner 406 in a stretchedconfiguration. Liner 406 has weight 410 attached to a bottom of theliner. Weight 410 hangs freely and provides tension to stretch liner406. Weight 410 may stop moving when the weight contacts a bottomsurface (for example, a bottom of the opening). In some embodiments, theweight is released from the liner. With tension from weight 410 removed,liner 406 relaxes into an expanded configuration, as shown in FIG. 23.In some embodiments, liner 406 is installed in the opening in acompacted configuration and expanded with a mandrel or pig. Typically,expandable liners are perforated or slotted tubulars that are placed inthe wellbore and expanded by forcing a mandrel through the liner. Theseexpandable liners may be expanded against the wall of the wellbore toinhibit sloughing of material from the walls. Examples of typicalexpandable liners are available from Weatherford U.S., L.P. (Alice,Tex.) and Halliburton Energy Services (Houston, Tex.).

In certain embodiments, the wellbore or opening is sized such thatsloughed material in the wellbore does not inhibit heating in thewellbore. The wellbore and the heater may be sized so that an annulusbetween the heater and the wellbore is small enough to inhibit particlesof a selected size (for example, a size of sloughed material) fromfreely moving (for example, falling due to gravity, movement due tofluid pressures, or movement due to geological phenomena) in theannulus. In some embodiments, selected portions of the annulus are sizedto inhibit particles from freely moving. In certain embodiments, theannulus between the heater and the wellbore has a width of at most 2.5cm, at most 2 cm, or at most 1.5 cm. Different methods to reduce theeffects of sloughing described herein may be used either alone or incombination.

Temperature limited heaters may be in configurations and/or may includematerials that provide automatic temperature limiting properties for theheater at certain temperatures. In certain embodiments, ferromagneticmaterials are used in temperature limited heaters. Ferromagneticmaterial may self-limit temperature at or near the Curie temperature ofthe material to provide a reduced amount of heat at or near the Curietemperature when an time-varying current is applied to the material. Incertain embodiments, the ferromagnetic material self-limits temperatureof the temperature limited heater at a selected temperature that isapproximately the Curie temperature. In certain embodiments, theselected temperature is within about 35° C., within about 25° C., withinabout 20° C., or within about 10° C. of the Curie temperature. Incertain embodiments, ferromagnetic materials are coupled with othermaterials (for example, highly conductive materials, high strengthmaterials, corrosion resistant materials, or combinations thereof) toprovide various electrical and/or mechanical properties. Some parts ofthe temperature limited heater may have a lower resistance (caused bydifferent geometries and/or by using different ferromagnetic and/ornon-ferromagnetic materials) than other parts of the temperature limitedheater. Having parts of the temperature limited heater with variousmaterials and/or dimensions allows for tailoring the desired heat outputfrom each part of the heater.

Temperature limited heaters may be more reliable than other heaters.Temperature limited heaters may be less apt to break down or fail due tohot spots in the formation. In some embodiments, temperature limitedheaters allow for substantially uniform heating of the formation. Insome embodiments, temperature limited heaters are able to heat theformation more efficiently by operating at a higher average heat outputalong the entire length of the heater. The temperature limited heateroperates at the higher average heat output along the entire length ofthe heater because power to the heater does not have to be reduced tothe entire heater, as is the case with typical constant wattage heaters,if a temperature along any point of the heater exceeds, or is about toexceed, a maximum operating temperature of the heater. Heat output fromportions of a temperature limited heater approaching a Curie temperatureof the heater automatically reduces without controlled adjustment of thetime-varying current applied to the heater. The heat outputautomatically reduces due to changes in electrical properties (forexample, electrical resistance) of portions of the temperature limitedheater. Thus, more power is supplied by the temperature limited heaterduring a greater portion of a heating process.

In certain embodiments, the system including temperature limited heatersinitially provides a first heat output and then provides a reduced(second heat output) heat output, near, at, or above the Curietemperature of an electrically resistive portion of the heater when thetemperature limited heater is energized by a time-varying current. Thefirst heat output is the heat output at temperatures below which thetemperature limited heater begins to self-limit. In some embodiments,the first heat output is the heat output at a temperature 50° C., 75°C., 100° C., or 125° C. below the Curie temperature of the ferromagneticmaterial in the temperature limited heater.

The temperature limited heater may be energized by time-varying current(alternating current or modulated direct current) supplied at thewellhead. The wellhead may include a power source and other components(for example, modulation components, transformers, and/or capacitors)used in supplying power to the temperature limited heater. Thetemperature limited heater may be one of many heaters used to heat aportion of the formation.

In certain embodiments, the temperature limited heater includes aconductor that operates as a skin effect or proximity effect heater whentime-varying current is applied to the conductor. The skin effect limitsthe depth of current penetration into the interior of the conductor. Forferromagnetic materials, the skin effect is dominated by the magneticpermeability of the conductor. The relative magnetic permeability offerromagnetic materials is typically between 10 and 1000 (for example,the relative magnetic permeability of ferromagnetic materials istypically at least 10 and may be at least 50, 100, 500, 1000 orgreater). As the temperature of the ferromagnetic material is raisedabove the Curie temperature and/or as the applied electrical current isincreased, the magnetic permeability of the ferromagnetic materialdecreases substantially and the skin depth expands rapidly (for example,the skin depth expands as the inverse square root of the magneticpermeability). The reduction in magnetic permeability results in adecrease in the AC or modulated DC resistance of the conductor near, at,or above the Curie temperature and/or as the applied electrical currentis increased. When the temperature limited heater is powered by asubstantially constant current source, portions of the heater thatapproach, reach, or are above the Curie temperature may have reducedheat dissipation. Sections of the temperature limited heater that arenot at or near the Curie temperature may be dominated by skin effectheating that allows the heater to have high heat dissipation due to ahigher resistive load.

Curie temperature heaters have been used in soldering equipment, heatersfor medical applications, and heating elements for ovens (for example,pizza ovens). Some of these uses are disclosed in U.S. Pat. Nos.5,579,575 to Lamome et al.; 5,065,501 to Henschen et al.; and 5,512,732to Yagnik et al., all of which are incorporated by reference as if fullyset forth herein. U.S. Pat. No. 4,849,611 to Whitney et al., which isincorporated by reference as if fully set forth herein, describes aplurality of discrete, spaced-apart heating units including a reactivecomponent, a resistive heating component, and a temperature responsivecomponent.

An advantage of using the temperature limited heater to heathydrocarbons in the formation is that the conductor is chosen to have aCurie temperature in a desired range of temperature operation. Operationwithin the desired operating temperature range allows substantial heatinjection into the formation while maintaining the temperature of thetemperature limited heater, and other equipment, below design limittemperatures. Design limit temperatures are temperatures at whichproperties such as corrosion, creep, and/or deformation are adverselyaffected. The temperature limiting properties of the temperature limitedheater inhibits overheating or burnout of the heater adjacent to lowthermal conductivity “hot spots” in the formation. In some embodiments,the temperature limited heater is able to lower or control heat outputand/or withstand heat at temperatures above 25° C., 37° C., 100° C.,250° C., 500° C., 700° C., 800° C., 900° C., or higher up to 1131° C.,depending on the materials used in the heater.

The temperature limited heater allows for more heat injection into theformation than constant wattage heaters because the energy input intothe temperature limited heater does not have to be limited toaccommodate low thermal conductivity regions adjacent to the heater. Forexample, in Green River oil shale there is a difference of at least afactor of 3 in the thermal conductivity of the lowest richness oil shalelayers and the highest richness oil shale layers. When heating such aformation, substantially more heat is transferred to the formation withthe temperature limited heater than with the conventional heater that islimited by the temperature at low thermal conductivity layers. The heatoutput along the entire length of the conventional heater needs toaccommodate the low thermal conductivity layers so that the heater doesnot overheat at the low thermal conductivity layers and burn out. Theheat output adjacent to the low thermal conductivity layers that are athigh temperature will reduce for the temperature limited heater, but theremaining portions of the temperature limited heater that are not athigh temperature will still provide high heat output. Because heatersfor heating hydrocarbon formations typically have long lengths (forexample, at least 10 m, 100 m, 300 m, at least 500 m, 1 km or more up toabout 10 km), the majority of the length of the temperature limitedheater may be operating below the Curie temperature while only a fewportions are at or near the Curie temperature of the temperature limitedheater.

The use of temperature limited heaters allows for efficient transfer ofheat to the formation. Efficient transfer of heat allows for reductionin time needed to heat the formation to a desired temperature. Forexample, in Green River oil shale, pyrolysis typically requires 9.5years to 10 years of heating when using a 12 m heater well spacing withconventional constant wattage heaters. For the same heater spacing,temperature limited heaters may allow a larger average heat output whilemaintaining heater equipment temperatures below equipment design limittemperatures. Pyrolysis in the formation may occur at an earlier timewith the larger average heat output provided by temperature limitedheaters than the lower average heat output provided by constant wattageheaters. For example, in Green River oil shale, pyrolysis may occur in 5years using temperature limited heaters with a 12 m heater well spacing.Temperature limited heaters counteract hot spots due to inaccurate wellspacing or drilling where heater wells come too close together. Incertain embodiments, temperature limited heaters allow for increasedpower output over time for heater wells that have been spaced too farapart, or limit power output for heater wells that are spaced too closetogether. Temperature limited heaters also supply more power in regionsadjacent the overburden and underburden to compensate for temperaturelosses in these regions.

Temperature limited heaters may be advantageously used in many types offormations. For example, in tar sands formations or relatively permeableformations containing heavy hydrocarbons, temperature limited heatersmay be used to provide a controllable low temperature output forreducing the viscosity of fluids, mobilizing fluids, and/or enhancingthe radial flow of fluids at or near the wellbore or in the formation.Temperature limited heaters may be used to inhibit excess coke formationdue to overheating of the near wellbore region of the formation.

The use of temperature limited heaters, in some embodiments, eliminatesor reduces the need for expensive temperature control circuitry. Forexample, the use of temperature limited heaters eliminates or reducesthe need to perform temperature logging and/or the need to use fixedthermocouples on the heaters to monitor potential overheating at hotspots.

In certain embodiments, the temperature limited heater is deformationtolerant. Localized movement of material in a wellbore may result inlateral stresses on the heater that could deform its shape. Locationsalong a length of a heater at which the wellbore approaches or closes onthe heater may be hot spots where a standard heater overheats and hasthe potential to burn out. These hot spots may lower the yield strengthand creep strength of the metal, allowing crushing or deformation of theheater. The temperature limited heater may be formed with S curves (orother non-linear shapes) that accommodate deformation of the temperaturelimited heater without causing failure of the heater.

In some embodiments, temperature limited heaters are more economical tomanufacture or make than standard heaters. Typical ferromagneticmaterials include iron, carbon steel, or ferritic stainless steel. Suchmaterials are inexpensive as compared to nickel-based heating alloys(such as nichrome, Kanthal™ (Bulten-Kanthal AB, Sweden), and/or LOHM™(Driver-Harris Company, Harrison, N.J.)) typically used in insulatedconductor (mineral insulated cable) heaters. In one embodiment of thetemperature limited heater, the temperature limited heater ismanufactured in continuous lengths as an insulated conductor heater tolower costs and improve reliability.

In some embodiments, a temperature limited heater is placed in a heaterwell using a coiled tubing rig. A heater that can be coiled on a spoolmay be manufactured by using metal such as ferritic stainless steel (forexample, 409 stainless steel) that is welded using electrical resistancewelding (ERW). To form a heater section, a metal strip from a roll ispassed through a first former where it is shaped into a tubular and thenlongitudinally welded using ERW. The tubular is passed through a secondformer where a conductive strip (for example, a copper strip) isapplied, drawn down tightly on the tubular through a die, andlongitudinally welded using ERW. A sheath may be formed bylongitudinally welding a support material (for example, steel such as347H or 347HH) over the conductive strip material. The support materialmay be a strip rolled over the conductive strip material. An overburdensection of the heater may be formed in a similar manner. In certainembodiments, the overburden section uses a non-ferromagnetic materialsuch as 304 stainless steel or 316 stainless steel instead of aferromagnetic material. The heater section and overburden section may becoupled together using standard techniques such as butt welding using anorbital welder. In some embodiments, the overburden section material(the non-ferromagnetic material) may be pre-welded to the ferromagneticmaterial before rolling. The pre-welding may eliminate the need for aseparate coupling step (for example, butt welding). In an embodiment, aflexible cable (for example, a furnace cable such as a MGT 1000 furnacecable) may be pulled through the center after forming the tubularheater. An end bushing on the flexible cable may be welded to thetubular heater to provide an electrical current return path. The tubularheater, including the flexible cable, may be coiled onto a spool beforeinstallation into a heater well. In an embodiment, a temperature limitedheater is installed using a coiled tubing rig. The coiled tubing rig mayplace the temperature limited heater in a deformation resistantcontainer in a formation. The deformation resistant container may beplaced in the heater well using conventional methods.

In an embodiment, a Curie heater includes a furnace cable inside aferromagnetic conduit (for example, a ¾″ Schedule 80 446 stainless steelpipe). The ferromagnetic conduit may be clad with copper or anothersuitable conductive material. The ferromagnetic conduit may be placed ina deformation-tolerant conduit or deformation resistant container. Thedeformation-tolerant conduit may tolerate longitudinal deformation,radial deformation, and creep. The deformation-tolerant conduit may alsosupport the ferromagnetic conduit and furnace cable. Thedeformation-tolerant conduit may be selected based on creep and/orcorrosion resistance near or at the Curie temperature. In oneembodiment, the deformation-tolerant conduit is 1½″ Schedule 80 347Hstainless steel pipe (outside diameter of about 4.826 cm) or 1½″Schedule 160 347H stainless steel pipe (outside diameter of about 4.826cm).

The diameter and/or materials of the deformation-tolerant conduit mayvary depending on, for example, characteristics of the formation to beheated or desired heat output characteristics of the heater. In certainembodiments, air is removed from the annulus between thedeformation-tolerant conduit and the clad ferromagnetic conduit. Thespace between the deformation-tolerant conduit and the cladferromagnetic conduit may be flushed with a pressurized inert gas (forexample, helium, nitrogen, argon, or mixtures thereof). In someembodiments, the inert gas may include a small amount of hydrogen to actas a “getter” for residual oxygen. The inert gas may pass down theannulus from the surface, enter the inner diameter of the ferromagneticconduit through a small hole near the bottom of the heater, and flow upinside the ferromagnetic conduit. Removal of the air in the annulus mayreduce oxidation of materials in the heater (for example, thenickel-coated copper wires of the furnace cable) to provide a longerlife heater, especially at elevated temperatures. Thermal conductionbetween a furnace cable and the ferromagnetic conduit, and between theferromagnetic conduit and the deformation-tolerant conduit, may beimproved when the inert gas is helium. The pressurized inert gas in theannular space may also provide additional support for thedeformation-tolerant conduit against high formation pressures.Pressurized inert gas also inhibits arcing between metal conductors inthe annular space compared to inert gas at atmospheric pressure.

In certain embodiments, a thermally conductive fluid such as helium maybe placed inside void volumes of the temperature limited heater whereheat is transferred. Placing thermally conductive fluid inside voidvolumes of the temperature limited heater may improve thermal conductioninside the void volumes. Thermally conductive fluids include, but arenot limited to, gases that are thermally conductive, electricallyinsulating, and radiantly transparent. In certain embodiments, thermallyconductive fluid in the void volumes has a higher thermal conductivitythan air at standard temperature and pressure (STP) (0° C. and 101.325kPa). Radiantly transparent gases include gases with diatomic or singleatoms that do not absorb a significant amount of infrared energy. Incertain embodiments, thermally conductive fluids include helium and/orhydrogen. Thermally conductive fluids may also be thermally stable atoperating temperatures in the temperature limited heater so that thethermally conductive fluids do not thermally crack at operatingtemperature in the temperature limited heater.

Thermally conductive fluid may be placed inside a conductor, inside aconduit, and/or inside a jacket of a temperature limited heater. Thethermally conductive fluid may be placed in the space (the annulus)between one or more components (for example, conductor, conduit, orjacket) of the temperature limited heater. In some embodiments,thermally conductive fluid is placed in the space (the annulus) betweenthe temperature limited heater and a conduit.

In certain embodiments, air and/or other fluid in the space (theannulus) is displaced by a flow of thermally conductive fluid duringintroduction of the thermally conductive fluid into the space. In someembodiments, air and/or other fluid is removed (for example, vacuumed,flushed, or pumped out) from the space before introducing thermallyconductive fluid in the space. Reducing the partial pressure of oxygenin the space reduces the rate of oxidation of heater components in thespace. The thermally conductive fluid is introduced in a specific volumeand/or to a selected pressure in the space. Thermally conductive fluidmay be introduced such that the space has at least a minimum volumepercentage of thermally conductive fluid above a selected value. Incertain embodiments, the space has at least 50%, 75%, or 90% by volumeof thermally conductive fluid.

Placing thermally conductive fluid inside the space of the temperaturelimited heater increases thermal heat transfer in the space. Theincreased thermal heat transfer is caused by reducing resistance to heattransfer in the space with the thermally conductive fluid. Reducingresistance to heat transfer in the space allows for increased poweroutput from the temperature limited heater to the subsurface formation.Reducing the resistance to heat transfer inside the space with thethermally conductive fluid allows for smaller diameter electricalconductors (for example, a smaller diameter inner conductor, a smallerdiameter outer conductor, and/or a smaller diameter conduit), a largerouter radius (for example, a larger radius of a conduit or a jacket),and/or an increased space width. Reducing the diameter of electricalconductors reduces material costs. Increasing the outer radius of theconduit or the jacket and/or increasing the annulus space width providesadditional annular space. Additional annular space may accommodatedeformation of the conduit and/or the jacket without causing heaterfailure. Increasing the outer radius of the conduit or the jacket and/orincreasing the annulus width may provide additional annular space toprotect components (for example, spacers, connectors, and/or conduits)in the annulus.

As the annular width of the temperature limited heater is increased,however, greater heat transfer is needed across the annular space tomaintain good heat output properties for the heater. In someembodiments, especially for low temperature heaters, radiative heattransfer is minimally effective in transferring heat across the annularspace of the heater. Conductive heat transfer in the annular space isimportant in such embodiments to maintain good heat output propertiesfor the heater. A thermally conductive fluid provides increased heattransfer across the annular space.

In certain embodiments, the thermally conductive fluid located in thespace is also electrically insulating to inhibit arcing betweenconductors in the temperature limited heater. Arcing across the space orgap is a problem with longer heaters that require higher operatingvoltages. Arcing may be a problem with shorter heaters and/or at lowervoltages depending on the operating conditions of the heater. Increasingthe pressure of the fluid in the space increases the spark gap breakdownvoltage in the space and inhibits arcing across the space. Certaingases, such as SF₆ or N₂, have greater resistance to electricalbreakdown but have lower thermal conductivities than helium or hydrogenbecause of their higher molecular weights. Thus, gases such as SF₆ or N₂may be less desirable in some embodiments.

Pressure of thermally conductive fluid in the space may be increased toa pressure between 200 kPa and 60,000 kPa, between 500 kPa and 50,000kPa, between 700 kPa and 45,000 kPa, or between 1000 kPa and 40,000 kPa.In an embodiment, the pressure of the thermally conductive fluid isincreased to at least 700 kPa or at least 1000 kPa. In certainembodiments, the pressure of the thermally conductive fluid needed toinhibit arcing across the space depends on the temperature in the space.Electrons may track along surfaces (for example, insulators, connectors,or shields) in the space and cause arcing or electrical degradation ofthe surfaces. High pressure fluid in the space may inhibit electrontracking along surfaces in the space. Helium has about one-seventh thebreakdown voltage of air at atmospheric pressure. Thus, higher pressuresof helium (for example, 7 atm (707 kPa) or greater of helium) may beused to compensate for the lower breakdown voltage of helium as comparedto air.

Temperature limited heaters may be used for heating hydrocarbonformations including, but not limited to, oil shale formations, coalformations, tar sands formations, and heavy viscous oils. Temperaturelimited heaters may be used for remediation of contaminated soil.Temperature limited heaters may also be used in the field ofenvironmental remediation to vaporize or destroy soil contaminantsEmbodiments of temperature limited heaters are used to heat fluids in awellbore or sub-sea pipeline to inhibit deposition of paraffin orvarious hydrates. In some embodiments, a temperature limited heater isused for solution mining of a subsurface formation (for example, an oilshale or a coal formation). In certain embodiments, a fluid (forexample, molten salt) is placed in a wellbore and heated with atemperature limited heater to inhibit deformation and/or collapse of thewellbore. In some embodiments, the temperature limited heater isattached to a sucker rod in the wellbore or is part of the sucker roditself. In some embodiments, temperature limited heaters are used toheat a near wellbore region to reduce near wellbore oil viscosity duringproduction of high viscosity crude oils and during transport of highviscosity oils to the surface. In some embodiments, a temperaturelimited heater enables gas lifting of a viscous oil by lowering theviscosity of the oil without coking the oil. Temperature limited heatersmay be used in sulfur transfer lines to maintain temperatures betweenabout 110° C. and about 130° C.

Certain embodiments of temperature limited heaters may be used inchemical or refinery processes at elevated temperatures that requirecontrol in a narrow temperature range to inhibit unwanted chemicalreactions or damage from locally elevated temperatures. Someapplications may include, but are not limited to, reactor tubes, cokers,and distillation towers. Temperature limited heaters may also be used inpollution control devices (for example, catalytic converters, andoxidizers) to allow rapid heating to a control temperature withoutcomplex temperature control circuitry. Additionally, temperature limitedheaters may be used in food processing to avoid damaging food withexcessive temperatures. Temperature limited heaters may also be used inthe heat treatment of metals (for example, annealing of weld joints).Temperature limited heaters may also be used in floor heaters,cauterizers, and/or various other appliances. Temperature limitedheaters may be used with biopsy needles to destroy tumors by raisingtemperatures in vivo.

Some embodiments of temperature limited heaters may be useful in certaintypes of medical and/or veterinary devices. For example, a temperaturelimited heater may be used to therapeutically treat tissue in a human oran animal. A temperature limited heater for a medical or veterinarydevice may have ferromagnetic material including a palladium-copperalloy with a Curie temperature of about 50° C. A high frequency (forexample, a frequency greater than about 1 MHz) may be used to power arelatively small temperature limited heater for medical and/orveterinary use.

The ferromagnetic alloy or ferromagnetic alloys used in the temperaturelimited heater determine the Curie temperature of the heater. Curietemperature data for various metals is listed in “American Institute ofPhysics Handbook,” Second Edition, McGraw-Hill, pages 5-170 through5-176. Ferromagnetic conductors may include one or more of theferromagnetic elements (iron, cobalt, and nickel) and/or alloys of theseelements. In some embodiments, ferromagnetic conductors includeiron-chromium (Fe—Cr) alloys that contain tungsten (W) (for example,HCM12A and SAVE12 (Sumitomo Metals Co., Japan) and/or iron alloys thatcontain chromium (for example, Fe—Cr alloys, Fe—Cr—W alloys, Fe—Cr—V(vanadium) alloys, Fe—Cr—Nb (Niobium) alloys). Of the three mainferromagnetic elements, iron has a Curie temperature of approximately770° C.; cobalt (Co) has a Curie temperature of approximately 1131° C.;and nickel has a Curie temperature of approximately 358° C. Aniron-cobalt alloy has a Curie temperature higher than the Curietemperature of iron. For example, iron-cobalt alloy with 2% by weightcobalt has a Curie temperature of approximately 800° C.; iron-cobaltalloy with 12% by weight cobalt has a Curie temperature of approximately900° C.; and iron-cobalt alloy with 20% by weight cobalt has a Curietemperature of approximately 950° C. Iron-nickel alloy has a Curietemperature lower than the Curie temperature of iron. For example,iron-nickel alloy with 20% by weight nickel has a Curie temperature ofapproximately 720° C., and iron-nickel alloy with 60% by weight nickelhas a Curie temperature of approximately 560° C.

Some non-ferromagnetic elements used as alloys raise the Curietemperature of iron. For example, an iron-vanadium alloy with 5.9% byweight vanadium has a Curie temperature of approximately 815° C. Othernon-ferromagnetic elements (for example, carbon, aluminum, copper,silicon, and/or chromium) may be alloyed with iron or otherferromagnetic materials to lower the Curie temperature.Non-ferromagnetic materials that raise the Curie temperature may becombined with non-ferromagnetic materials that lower the Curietemperature and alloyed with iron or other ferromagnetic materials toproduce a material with a desired Curie temperature and other desiredphysical and/or chemical properties. In some embodiments, the Curietemperature material is a ferrite such as NiFe₂O₄. In other embodiments,the Curie temperature material is a binary compound such as FeNi₃ orFe₃Al.

Certain embodiments of temperature limited heaters may include more thanone ferromagnetic material. Such embodiments are within the scope ofembodiments described herein if any conditions described herein apply toat least one of the ferromagnetic materials in the temperature limitedheater.

Ferromagnetic properties generally decay as the Curie temperature isapproached. The “Handbook of Electrical Heating for Industry” by C.James Erickson (IEEE Press, 1995) shows a typical curve for 1% carbonsteel (steel with 1% carbon by weight). The loss of magneticpermeability starts at temperatures above 650° C. and tends to becomplete when temperatures exceed 730° C. Thus, the self-limitingtemperature may be somewhat below the actual Curie temperature of theferromagnetic conductor. The skin depth for current flow in 1% carbonsteel is 0.132 cm at room temperature and increases to 0.445 cm at 720°C. From 720° C. to 730° C., the skin depth sharply increases to over 2.5cm. Thus, a temperature limited heater embodiment using 1% carbon steelbegins to self-limit between 650° C. and 730° C.

Skin depth generally defines an effective penetration depth oftime-varying current into the conductive material. In general, currentdensity decreases exponentially with distance from an outer surface tothe center along the radius of the conductor. The depth at which thecurrent density is approximately 1/e of the surface current density iscalled the skin depth. For a solid cylindrical rod with a diameter muchgreater than the penetration depth, or for hollow cylinders with a wallthickness exceeding the penetration depth, the skin depth, δ, is:

δ=1981.5*(ρ/(μ*f)^(1/2);  (2)

in which: δ=skin depth in inches;

-   -   ρ=resistivity at operating temperature (ohm-cm);    -   μ=relative magnetic permeability; and    -   f=frequency (Hz).

EQN. 2 is obtained from “Handbook of Electrical Heating for Industry” byC. James Erickson (IEEE Press, 1995). For most metals, resistivity (p)increases with temperature. The relative magnetic permeability generallyvaries with temperature and with current. Additional equations may beused to assess the variance of magnetic permeability and/or skin depthon both temperature and/or current. The dependence of μ on currentarises from the dependence of μ on the magnetic field.

Materials used in the temperature limited heater may be selected toprovide a desired turndown ratio. Turndown ratios of at least 1.1:1,2:1, 3:1, 4:1, 5:1, 10:1, 30:1, or 50:1 may be selected for temperaturelimited heaters. Larger turndown ratios may also be used. A selectedturndown ratio may depend on a number of factors including, but notlimited to, the type of formation in which the temperature limitedheater is located (for example, a higher turndown ratio may be used foran oil shale formation with large variations in thermal conductivitybetween rich and lean oil shale layers) and/or a temperature limit ofmaterials used in the wellbore (for example, temperature limits ofheater materials). In some embodiments, the turndown ratio is increasedby coupling additional copper or another good electrical conductor tothe ferromagnetic material (for example, adding copper to lower theresistance above the Curie temperature).

The temperature limited heater may provide a minimum heat output (poweroutput) below the Curie temperature of the heater. In certainembodiments, the minimum heat output is at least 400 W/m (Watts permeter), 600 W/m, 700 W/m, 800 W/m, or higher up to 2000 W/m. Thetemperature limited heater reduces the amount of heat output by asection of the heater when the temperature of the section of the heaterapproaches or is above the Curie temperature. The reduced amount of heatmay be substantially less than the heat output below the Curietemperature. In some embodiments, the reduced amount of heat is at most400 W/m, 200 W/m, 100 W/m or may approach 0 W/m. In certain embodiments,the temperature limited heater operates substantially independently ofthe thermal load on the heater in a certain operating temperature range.“Thermal load” is the rate that heat is transferred from a heatingsystem to its surroundings. It is to be understood that the thermal loadmay vary with temperature of the surroundings and/or the thermalconductivity of the surroundings. In an embodiment, the temperaturelimited heater operates at or above the Curie temperature of thetemperature limited heater such that the operating temperature of theheater increases at most by 3° C., 2° C., 1.5° C., 1° C., or 0.5° C. fora decrease in thermal load of 1 W/m proximate to a portion of theheater. In certain embodiments, the temperature limited heater operatesin such a manner at a relatively constant current.

The AC or modulated DC resistance and/or the heat output of thetemperature limited heater may decrease as the temperature approachesthe Curie temperature and decrease sharply near or above the Curietemperature due to the Curie effect. In certain embodiments, the valueof the electrical resistance or heat output above or near the Curietemperature is at most one-half of the value of electrical resistance orheat output at a certain point below the Curie temperature. In someembodiments, the heat output above or near the Curie temperature is atmost 90%, 70%, 50%, 30%, 20%, 10%, or less (down to 1%) of the heatoutput at a certain point below the Curie temperature (for example, 30°C. below the Curie temperature, 40° C. below the Curie temperature, 50°C. below the Curie temperature, or 100° C. below the Curie temperature).In certain embodiments, the electrical resistance above or near theCurie temperature decreases to 80%, 70%, 60%, 50%, or less (down to 1%)of the electrical resistance at a certain point below the Curietemperature (for example, 30° C. below the Curie temperature, 40° C.below the Curie temperature, 50° C. below the Curie temperature, or 100°C. below the Curie temperature).

In some embodiments, AC frequency is adjusted to change the skin depthof the ferromagnetic material. For example, the skin depth of 1% carbonsteel at room temperature is 0.132 cm at 60 Hz, 0.0762 cm at 180 Hz, and0.046 cm at 440 Hz. Since heater diameter is typically larger than twicethe skin depth, using a higher frequency (and thus a heater with asmaller diameter) reduces heater costs. For a fixed geometry, the higherfrequency results in a higher turndown ratio. The turndown ratio at ahigher frequency is calculated by multiplying the turndown ratio at alower frequency by the square root of the higher frequency divided bythe lower frequency. In some embodiments, a frequency between 100 Hz and1000 Hz, between 140 Hz and 200 Hz, or between 400 Hz and 600 Hz is used(for example, 180 Hz, 540 Hz, or 720 Hz). In some embodiments, highfrequencies may be used. The frequencies may be greater than 1000 Hz.

To maintain a substantially constant skin depth until the Curietemperature of the temperature limited heater is reached, the heater maybe operated at a lower frequency when the heater is cold and operated ata higher frequency when the heater is hot. Line frequency heating isgenerally favorable, however, because there is less need for expensivecomponents such as power supplies, transformers, or current modulatorsthat alter frequency. Line frequency is the frequency of a generalsupply of current. Line frequency is typically 60 Hz, but may be 50 Hzor another frequency depending on the source for the supply of thecurrent. Higher frequencies may be produced using commercially availableequipment such as solid state variable frequency power supplies.Transformers that convert three-phase power to single-phase power withthree times the frequency are commercially available. For example, highvoltage three-phase power at 60 Hz may be transformed to single-phasepower at 180 Hz and at a lower voltage. Such transformers are lessexpensive and more energy efficient than solid state variable frequencypower supplies. In certain embodiments, transformers that convertthree-phase power to single-phase power are used to increase thefrequency of power supplied to the temperature limited heater.

In certain embodiments, modulated DC (for example, chopped DC, waveformmodulated DC, or cycled DC) may be used for providing electrical powerto the temperature limited heater. A DC modulator or DC chopper may becoupled to a DC power supply to provide an output of modulated directcurrent. In some embodiments, the DC power supply may include means formodulating DC. One example of a DC modulator is a DC-to-DC convertersystem. DC-to-DC converter systems are generally known in the art. DC istypically modulated or chopped into a desired waveform. Waveforms for DCmodulation include, but are not limited to, square-wave, sinusoidal,deformed sinusoidal, deformed square-wave, triangular, and other regularor irregular waveforms.

The modulated DC waveform generally defines the frequency of themodulated DC. Thus, the modulated DC waveform may be selected to providea desired modulated DC frequency. The shape and/or the rate ofmodulation (such as the rate of chopping) of the modulated DC waveformmay be varied to vary the modulated DC frequency. DC may be modulated atfrequencies that are higher than generally available AC frequencies. Forexample, modulated DC may be provided at frequencies of at least 1000Hz. Increasing the frequency of supplied current to higher valuesadvantageously increases the turndown ratio of the temperature limitedheater.

In certain embodiments, the modulated DC waveform is adjusted or alteredto vary the modulated DC frequency. The DC modulator may be able toadjust or alter the modulated DC waveform at any time during use of thetemperature limited heater and at high currents or voltages. Thus,modulated DC provided to the temperature limited heater is not limitedto a single frequency or even a small set of frequency values. Waveformselection using the DC modulator typically allows for a wide range ofmodulated DC frequencies and for discrete control of the modulated DCfrequency. Thus, the modulated DC frequency is more easily set at adistinct value whereas AC frequency is generally limited to multiples ofthe line frequency. Discrete control of the modulated DC frequencyallows for more selective control over the turndown ratio of thetemperature limited heater. Being able to selectively control theturndown ratio of the temperature limited heater allows for a broaderrange of materials to be used in designing and constructing thetemperature limited heater.

In certain embodiments, electrical power for the temperature limitedheater is initially supplied using non-modulated DC or very lowfrequency modulated DC. Using DC, or low frequency DC, at earlier timesof heating reduces inefficiencies associated with higher frequencies. DCand/or low frequency modulated DC may also be cheaper to use duringinitial heating times. After a selected temperature is reached in atemperature limited heater; modulated DC, higher frequency modulated DC,or AC is used for providing electrical power to the temperature limitedheater so that the heat output will decrease near, at, or above theCurie temperature.

In some embodiments, the modulated DC frequency or the AC frequency isadjusted to compensate for changes in properties (for example,subsurface conditions such as temperature or pressure) of thetemperature limited heater during use. The modulated DC frequency or theAC frequency provided to the temperature limited heater is varied basedon assessed downhole conditions. For example, as the temperature of thetemperature limited heater in the wellbore increases, it may beadvantageous to increase the frequency of the current provided to theheater, thus increasing the turndown ratio of the heater. In anembodiment, the downhole temperature of the temperature limited heaterin the wellbore is assessed.

In certain embodiments, the modulated DC frequency, or the AC frequency,is varied to adjust the turndown ratio of the temperature limitedheater. The turndown ratio may be adjusted to compensate for hot spotsoccurring along a length of the temperature limited heater. For example,the turndown ratio is increased because the temperature limited heateris getting too hot in certain locations. In some embodiments, themodulated DC frequency, or the AC frequency, are varied to adjust aturndown ratio without assessing a subsurface condition.

At or near the Curie temperature of the ferromagnetic material, arelatively small change in voltage may cause a relatively large changein current to the load. The relatively small change in voltage mayproduce problems in the power supplied to the temperature limitedheater, especially at or near the Curie temperature. The problemsinclude, but are not limited to, reducing the power factor, tripping acircuit breaker, and/or blowing a fuse. In some cases, voltage changesmay be caused by a change in the load of the temperature limited heater.In certain embodiments, an electrical current supply (for example, asupply of modulated DC or AC) provides a relatively constant amount ofcurrent that does not substantially vary with changes in load of thetemperature limited heater. In an embodiment, the electrical currentsupply provides an amount of electrical current that remains within 15%,within 10%, within 5%, or within 2% of a selected constant current valuewhen a load of the temperature limited heater changes.

Temperature limited heaters may generate an inductive load. Theinductive load is due to some applied electrical current being used bythe ferromagnetic material to generate a magnetic field in addition togenerating a resistive heat output. As downhole temperature changes inthe temperature limited heater, the inductive load of the heater changesdue to changes in the ferromagnetic properties of ferromagneticmaterials in the heater with temperature. The inductive load of thetemperature limited heater may cause a phase shift between the currentand the voltage applied to the heater.

A reduction in actual power applied to the temperature limited heatermay be caused by a time lag in the current waveform (for example, thecurrent has a phase shift relative to the voltage due to an inductiveload) and/or by distortions in the current waveform (for example,distortions in the current waveform caused by introduced harmonics dueto a non-linear load). Thus, it may take more current to apply aselected amount of power due to phase shifting or waveform distortion.The ratio of actual power applied and the apparent power that would havebeen transmitted if the same current were in phase and undistorted isthe power factor. The power factor is always less than or equal to 1.The power factor is 1 when there is no phase shift or distortion in thewaveform.

Actual power applied to a heater due to a phase shift may be describedby EQN. 3:

P=I×V×cos (θ);  (3)

in which P is the actual power applied to a heater; I is the appliedcurrent; V is the applied voltage; and θ is the phase angle differencebetween voltage and current. Other phenomena such as waveform distortionmay contribute to further lowering of the power factor. If there is nodistortion in the waveform, then cos(0) is equal to the power factor.

At higher frequencies (for example, modulated DC frequencies of at least1000 Hz, 1500 Hz, or 2000 Hz), the problem with phase shifting and/ordistortion is more pronounced. In certain embodiments, a capacitor isused to compensate for phase shifting caused by the inductive load.Capacitive load may be used to balance the inductive load becausecurrent for capacitance is 180 degrees out of phase from current forinductance. In some embodiments, a variable capacitor (for example, asolid state switching capacitor) is used to compensate for phaseshifting caused by a varying inductive load. In an embodiment, thevariable capacitor is placed at the wellhead for the temperature limitedheater. Placing the variable capacitor at the wellhead allows thecapacitance to be varied more easily in response to changes in theinductive load of the temperature limited heater. In certainembodiments, the variable capacitor is placed subsurface with thetemperature limited heater, subsurface within the heater, or as close tothe heating conductor as possible to minimize line losses due to thecapacitor. In some embodiments, the variable capacitor is placed at acentral location for a field of heater wells (in some embodiments, onevariable capacitor may be used for several temperature limited heaters).In one embodiment, the variable capacitor is placed at the electricaljunction between the field of heaters and the utility supply ofelectricity.

In certain embodiments, the variable capacitor is used to maintain thepower factor of the temperature limited heater or the power factor ofthe electrical conductors in the temperature limited heater above aselected value. In some embodiments, the variable capacitor is used tomaintain the power factor of the temperature limited heater above theselected value of 0.85, 0.9, or 0.95. In certain embodiments, thecapacitance in the variable capacitor is varied to maintain the powerfactor of the temperature limited heater above the selected value.

In some embodiments, the modulated DC waveform is pre-shaped tocompensate for phase shifting and/or harmonic distortion. The waveformmay be pre-shaped by modulating the waveform into a specific shape. Forexample, the DC modulator is programmed or designed to output a waveformof a particular shape. In certain embodiments, the pre-shaped waveformis varied to compensate for changes in the inductive load of thetemperature limited heater caused by changes in the phase shift and/orthe harmonic distortion. Electrical measurements may be used to assessthe phase shift and/or the harmonic distortion. In certain embodiments,heater conditions (for example, downhole temperature or pressure) areassessed and used to determine the pre-shaped waveform. In someembodiments, the pre-shaped waveform is determined through the use of asimulation or calculations based on the heater design. Simulationsand/or heater conditions may also be used to determine the capacitanceneeded for the variable capacitor.

In some embodiments, the modulated DC waveform modulates DC between 100%(full current load) and 0% (no current load). For example, a square-wavemay modulate 100 A DC between 100% (100 A) and 0% (0 A) (full wavemodulation), between 100% (100 A) and 50% (50 A), or between 75% (75 A)and 25% (25 A). The lower current load (for example, the 0%, 25%, or 50%current load) may be defined as the base current load.

Generally, a temperature limited heater designed for higher voltage andlower current will have a smaller skin depth. Decreasing the current maydecrease the skin depth of the ferromagnetic material. The smaller skindepth allows the temperature limited heater to have a smaller diameter,thereby reducing equipment costs. In certain embodiments, the appliedcurrent is at least 1 amp, 10 amps, 70 amps, 100 amps, 200 amps, 500amps, or greater up to 2000 amps. In some embodiments, current issupplied at voltages above 200 volts, above 480 volts, above 650 volts,above 1000 volts, above 1500 volts, or higher up to 10000 volts.

In certain embodiments, the temperature limited heater includes an innerconductor inside an outer conductor. The inner conductor and the outerconductor are radially disposed about a central axis. The inner andouter conductors may be separated by an insulation layer. In certainembodiments, the inner and outer conductors are coupled at the bottom ofthe temperature limited heater. Electrical current may flow into thetemperature limited heater through the inner conductor and returnthrough the outer conductor. One or both conductors may includeferromagnetic material.

The insulation layer may comprise an electrically insulating ceramicwith high thermal conductivity, such as magnesium oxide, aluminum oxide,silicon dioxide, beryllium oxide, boron nitride, silicon nitride, orcombinations thereof. The insulating layer may be a compacted powder(for example, compacted ceramic powder). Compaction may improve thermalconductivity and provide better insulation resistance. For lowertemperature applications, polymer insulation made from, for example,fluoropolymers, polyimides, polyamides, and/or polyethylenes, may beused. In some embodiments, the polymer insulation is made ofperfluoroalkoxy (PFA) or polyetheretherketone (PEEK™ (Victrex Ltd.,England)). The insulating layer may be chosen to be substantiallyinfrared transparent to aid heat transfer from the inner conductor tothe outer conductor. In an embodiment, the insulating layer istransparent quartz sand. The insulation layer may be air or anon-reactive gas such as helium, nitrogen, or sulfur hexafluoride. Ifthe insulation layer is air or a non-reactive gas, there may beinsulating spacers designed to inhibit electrical contact between theinner conductor and the outer conductor. The insulating spacers may bemade of, for example, high purity aluminum oxide or another thermallyconducting, electrically insulating material such as silicon nitride.The insulating spacers may be a fibrous ceramic material such as Nextel™312 (3M Corporation, St. Paul, Minn.), mica tape, or glass fiber.Ceramic material may be made of alumina, alumina-silicate,alumina-borosilicate, silicon nitride, boron nitride, or othermaterials.

The insulation layer may be flexible and/or substantially deformationtolerant. For example, if the insulation layer is a solid or compactedmaterial that substantially fills the space between the inner and outerconductors, the temperature limited heater may be flexible and/orsubstantially deformation tolerant. Forces on the outer conductor can betransmitted through the insulation layer to the solid inner conductor,which may resist crushing. Such a temperature limited heater may bebent, dog-legged, and spiraled without causing the outer conductor andthe inner conductor to electrically short to each other. Deformationtolerance may be important if the wellbore is likely to undergosubstantial deformation during heating of the formation.

In certain embodiments, an outermost layer of the temperature limitedheater (for example, the outer conductor) is chosen for corrosion, yieldstrength, and/or creep resistance. In one embodiment, austenitic(non-ferromagnetic) stainless steels such as 201, 304H, 347H, 347HH,316H, 310H, 347HP, NF709 (Nippon Steel Corp., Japan) stainless steels,or combinations thereof may be used in the outer conductor. Theoutermost layer may also include a clad conductor. For example, acorrosion resistant alloy such as 800H or 347H stainless steel may beclad for corrosion protection over a ferromagnetic carbon steel tubular.If high temperature strength is not required, the outermost layer may beconstructed from the ferromagnetic metal with good corrosion resistancesuch as one of the ferritic stainless steels. In one embodiment, aferritic alloy of 82.3% by weight iron with 17.7% by weight chromium(Curie temperature of 678° C.) provides desired corrosion resistance.

The Metals Handbook, vol. 8, page 291 (American Society of Materials(ASM)) includes a graph of Curie temperature of iron-chromium alloysversus the amount of chromium in the alloys. In some temperature limitedheater embodiments, a separate support rod or tubular (made from 347Hstainless steel) is coupled to the temperature limited heater made froman iron-chromium alloy to provide yield strength and/or creepresistance. In certain embodiments, the support material and/or theferromagnetic material is selected to provide a 100,000 hourcreep-rupture strength of at least 20.7 MPa at 650° C. In someembodiments, the 100,000 hour creep-rupture strength is at least 13.8MPa at 650° C. or at least 6.9 MPa at 650° C. For example, 347H steelhas a favorable creep-rupture strength at or above 650° C. In someembodiments, the 100,000 hour creep-rupture strength ranges from 6.9 MPato 41.3 MPa or more for longer heaters and/or higher earth or fluidstresses.

In temperature limited heater embodiments with both an innerferromagnetic conductor and an outer ferromagnetic conductor, the skineffect current path occurs on the outside of the inner conductor and onthe inside of the outer conductor. Thus, the outside of the outerconductor may be clad with the corrosion resistant alloy, such asstainless steel, without affecting the skin effect current path on theinside of the outer conductor.

A ferromagnetic conductor with a thickness of at least the skin depth atthe Curie temperature allows a substantial decrease in resistance of theferromagnetic material as the skin depth increases sharply near theCurie temperature. In certain embodiments when the ferromagneticconductor is not clad with a highly conducting material such as copper,the thickness of the conductor may be 1.5 times the skin depth near theCurie temperature, 3 times the skin depth near the Curie temperature, oreven 10 or more times the skin depth near the Curie temperature. If theferromagnetic conductor is clad with copper, thickness of theferromagnetic conductor may be substantially the same as the skin depthnear the Curie temperature. In some embodiments, the ferromagneticconductor clad with copper has a thickness of at least three-fourths ofthe skin depth near the Curie temperature.

In certain embodiments, the temperature limited heater includes acomposite conductor with a ferromagnetic tubular and anon-ferromagnetic, high electrical conductivity core. Thenon-ferromagnetic, high electrical conductivity core reduces a requireddiameter of the conductor. For example, the conductor may be composite1.19 cm diameter conductor with a core of 0.575 cm diameter copper cladwith a 0.298 cm thickness of ferritic stainless steel or carbon steelsurrounding the core. The core or non-ferromagnetic conductor may becopper or copper alloy. The core or non-ferromagnetic conductor may alsobe made of other metals that exhibit low electrical resistivity andrelative magnetic permeabilities near 1 (for example, substantiallynon-ferromagnetic materials such as aluminum and aluminum alloys,phosphor bronze, beryllium copper, and/or brass). A composite conductorallows the electrical resistance of the temperature limited heater todecrease more steeply near the Curie temperature. As the skin depthincreases near the Curie temperature to include the copper core, theelectrical resistance decreases very sharply.

The composite conductor may increase the conductivity of the temperaturelimited heater and/or allow the heater to operate at lower voltages. Inan embodiment, the composite conductor exhibits a relatively flatresistance versus temperature profile at temperatures below a regionnear the Curie temperature of the ferromagnetic conductor of thecomposite conductor. In some embodiments, the temperature limited heaterexhibits a relatively flat resistance versus temperature profile between100° C. and 750° C. or between 300° C. and 600° C. The relatively flatresistance versus temperature profile may also be exhibited in othertemperature ranges by adjusting, for example, materials and/or theconfiguration of materials in the temperature limited heater. In certainembodiments, the relative thickness of each material in the compositeconductor is selected to produce a desired resistivity versustemperature profile for the temperature limited heater.

In certain embodiments, the relative thickness of each material in acomposite conductor is selected to produce a desired resistivity versustemperature profile for a temperature limited heater. In an embodiment,the composite conductor is an inner conductor surrounded by 0.127 cmthick magnesium oxide powder as an insulator. The outer conductor may be304H stainless steel with a wall thickness of 0.127 cm. The outsidediameter of the heater may be about 1.65 cm.

A composite conductor (for example, a composite inner conductor or acomposite outer conductor) may be manufactured by methods including, butnot limited to, co-extrusion, roll forming, tight fit tubing (forexample, cooling the inner member and heating the outer member, theninserting the inner member in the outer member, followed by a drawingoperation and/or allowing the system to cool), explosive orelectromagnetic cladding, arc overlay welding, longitudinal stripwelding, plasma powder welding, billet co-extrusion, electroplating,drawing, sputtering, plasma deposition, co-extrusion casting, magneticforming, molten cylinder casting (of inner core material inside theouter or vice versa), insertion followed by welding or high temperaturebraising, shielded active gas welding (SAG), and/or insertion of aninner pipe in an outer pipe followed by mechanical expansion of theinner pipe by hydroforming or use of a pig to expand and swage the innerpipe against the outer pipe. In some embodiments, a ferromagneticconductor is braided over a non-ferromagnetic conductor. In certainembodiments, composite conductors are formed using methods similar tothose used for cladding (for example, cladding copper to steel). Ametallurgical bond between copper cladding and base ferromagneticmaterial may be advantageous. Composite conductors produced by aco-extrusion process that forms a good metallurgical bond (for example,a good bond between copper and 446 stainless steel) may be provided byAnomet Products, Inc. (Shrewsbury, Mass.).

Several methods may also be used to form a composite conductor of morethan two conductors (for example, a three part composite conductor or afour part composite conductor). One method is to form two parts of thecomposite conductor by co-extrusion and then swaging down the thirdand/or fourth parts of the composite conductor onto the coextrudedparts. A second method involves forming two or more parts of thecomposite conductor by co-extrusion or another method, bending a stripof the outer conductor around the formed parts, and then welding theouter conductor together. The welding of the outer conductor maypenetrate deep enough to create good electrical contact to the innerparts of the composite conductor. Another method is to swage all partsof the composite conductor onto one another either simultaneously or intwo or more steps. In another method, all parts of the compositeconductor are coextruded simultaneously. In another method, explosivecladding may be used to form a composite conductor. Explosive claddingmay involve placing a first material in a second material and submergingthe composite material in a substantially non-compressible fluid. Anexplosive charge may be set off in the fluid to bind the first materialto the second material.

In an embodiment, two or more conductors are joined to form a compositeconductor by various methods (for example, longitudinal strip welding)to provide tight contact between the conducting layers. In certainembodiments, two or more conducting layers and/or insulating layers arecombined to form a composite heater with layers selected such that thecoefficient of thermal expansion decreases with each successive layerfrom the inner layer toward the outer layer. As the temperature of theheater increases, the innermost layer expands to the greatest degree.Each successive outwardly lying layer expands to a slightly lesserdegree, with the outermost layer expanding the least. This sequentialexpansion may provide relatively intimate contact between layers forgood electrical contact between layers.

In an embodiment, two or more conductors are drawn together to form acomposite conductor. In certain embodiments, a relatively malleableferromagnetic conductor (for example, iron such as 1018 steel) may beused to form a composite conductor. A relatively soft ferromagneticconductor typically has a low carbon content. A relatively malleableferromagnetic conductor may be useful in drawing processes for formingcomposite conductors and/or other processes that require stretching orbending of the ferromagnetic conductor. In a drawing process, theferromagnetic conductor may be annealed after one or more steps of thedrawing process. The ferromagnetic conductor may be annealed in an inertgas atmosphere to inhibit oxidation of the conductor. In someembodiments, oil is placed on the ferromagnetic conductor to inhibitoxidation of the conductor during processing.

The diameter of a temperature limited heater may be small enough toinhibit deformation of the heater by a collapsing formation. In certainembodiments, the outside diameter of a temperature limited heater isless than about 5 cm. In some embodiments, the outside diameter of atemperature limited heater is less than about 4 cm, less than about 3cm, or between about 2 cm and about 5 cm.

In heater embodiments described herein (including, but not limited to,temperature limited heaters, insulated conductor heaters,conductor-in-conduit heaters, and elongated member heaters), a largesttransverse cross-sectional dimension of a heater may be selected toprovide a desired ratio of the largest transverse cross-sectionaldimension to wellbore diameter (for example, initial wellbore diameter).The largest transverse cross-sectional dimension is the largestdimension of the heater on the same axis as the wellbore diameter (forexample, the diameter of a cylindrical heater or the width of a verticalheater). In certain embodiments, the ratio of the largest transversecross-sectional dimension to wellbore diameter is selected to be lessthan about 1:2, less than about 1:3, or less than about 1:4. The ratioof heater diameter to wellbore diameter may be chosen to inhibit contactand/or deformation of the heater by the formation during heating. Forexample, the ratio of heater diameter to wellbore diameter may be chosento inhibit closing in of the wellbore on the heater during heating. Incertain embodiments, the wellbore diameter is determined by a diameterof a drill bit used to form the wellbore.

A wellbore diameter may shrink from an initial value of about 16.5 cm toabout 6.4 cm during heating of a formation (for example, for a wellborein oil shale with a richness greater than about 0.12 L/kg). At somepoint, expansion of formation material into the wellbore during heatingresults in a balancing between the hoop stress of the wellbore and thecompressive strength due to thermal expansion of hydrocarbon, orkerogen, rich layers. The hoop stress of the wellbore itself may reducethe stress applied to a conduit (for example, a liner) located in thewellbore. At this point, the formation may no longer have the strengthto deform or collapse a heater or a liner. For example, the radialstress provided by formation material may be about 12,000 psi (82.7 MPa)at a diameter of about 16.5 cm, while the stress at a diameter of about6.4 cm after expansion may be about 3000 psi (20.7 MPa). A heaterdiameter may be selected to be less than about 3.8 cm to inhibit contactof the formation and the heater. A temperature limited heater mayadvantageously provide a higher heat output over a significant portionof the wellbore (for example, the heat output needed to providesufficient heat to pyrolyze hydrocarbons in a hydrocarbon containingformation) than a constant wattage heater for smaller heater diameters(for example, less than about 5.1 cm).

FIG. 24 depicts an embodiment of an apparatus used to form a compositeconductor. Ingot 412 may be a ferromagnetic conductor (for example, ironor carbon steel). Ingot 412 may be placed in chamber 414. Chamber 414may be made of materials that are electrically insulating and able towithstand temperatures of about 800° C. or higher. In one embodiment,chamber 414 is a quartz chamber. In some embodiments, an inert, ornon-reactive, gas (for example, argon or nitrogen with a smallpercentage of hydrogen) may be placed in chamber 414. In certainembodiments, a flow of inert gas is provided to chamber 414 to maintaina pressure in the chamber. Induction coil 416 may be placed aroundchamber 414. An alternating current may be supplied to induction coil416 to inductively heat ingot 412. Inert gas inside chamber 414 mayinhibit oxidation or corrosion of ingot 412.

Inner conductor 418 may be placed inside ingot 412. Inner conductor 418may be a non-ferromagnetic conductor (for example, copper or aluminum)that melts at a lower temperature than ingot 412. In an embodiment,ingot 412 may be heated to a temperature above the melting point ofinner conductor 418 and below the melting point of the ingot. Innerconductor 418 may melt and substantially fill the space inside ingot 412(for example, the inner annulus of the ingot). A cap may be placed atthe bottom of ingot 412 to inhibit inner conductor 418 from flowingand/or leaking out of the inner annulus of the ingot. After innerconductor 418 has sufficiently melted to substantially fill the innerannulus of ingot 412, the inner conductor and the ingot may be allowedto cool to room temperature. Ingot 412 and inner conductor 418 may becooled at a relatively slow rate to allow inner conductor 418 to form agood soldering bond with ingot 412. The rate of cooling may depend on,for example, the types of materials used for the ingot and the innerconductor.

In some embodiments, a composite conductor may be formed by tube-in-tubemilling of dual metal strips, such as the process performed by PrecisionTube Technology (Houston, Tex.). A tube-in-tube milling process may alsobe used to form cladding on a conductor (for example, copper claddinginside carbon steel) or to form two materials into a tight fittube-within-a-tube configuration.

FIG. 25 depicts a cross section representation of an embodiment of aninner conductor and an outer conductor formed by a tube-in-tube millingprocess. Outer conductor 420 may be coupled to inner conductor 422.Outer conductor 420 may be weldable material such as steel. Innerconductor 422 may have a higher electrical conductivity than outerconductor 420. In an embodiment, inner conductor 422 is copper oraluminum. Weld bead 424 may be formed on outer conductor 420.

In a tube-in-tube milling process, flat strips of material for the outerconductor may have a thickness substantially equal to the desired wallthickness of the outer conductor. The width of the strips may allowformation of a tube of a desired inner diameter. The flat strips may bewelded end-to-end to form an outer conductor of a desired length. Flatstrips of material for the inner conductor may be cut such that theinner conductor formed from the strips fit inside the outer conductor.The flat strips of inner conductor material may be welded togetherend-to-end to achieve a length substantially the same as the desiredlength of the outer conductor. The flat strips for the outer conductorand the flat strips for the inner conductor may be fed into separateaccumulators. Both accumulators may be coupled to a tube mill. The twoflat strips may be sandwiched together at the beginning of the tubemill.

The tube mill may form the flat strips into a tube-in-tube shape. Afterthe tube-in-tube shape has been formed, a non-contact high frequencyinduction welder may heat the ends of the strips of the outer conductorto a forging temperature of the outer conductor. The ends of the stripsthen may be brought together to forge weld the ends of the outerconductor into a weld bead. Excess weld bead material may be cut off. Insome embodiments, the tube-in-tube produced by the tube mill is furtherprocessed (for example, annealed and/or pressed) to achieve a desiredsize and/or shape. The result of the tube-in-tube process may be aninner conductor in an outer conductor, as shown in FIG. 25.

FIGS. 26-71 depict various embodiments of temperature limited heaters.One or more features of an embodiment of the temperature limited heaterdepicted in any of these figures may be combined with one or morefeatures of other embodiments of temperature limited heaters depicted inthese figures. In certain embodiments described herein, temperaturelimited heaters are dimensioned to operate at a frequency of 60 Hz AC.It is to be understood that dimensions of the temperature limited heatermay be adjusted from those described herein in order for the temperaturelimited heater to operate in a similar manner at other AC frequencies orwith modulated DC.

FIG. 26 depicts a cross-sectional representation of an embodiment of thetemperature limited heater with an outer conductor having aferromagnetic section and a non-ferromagnetic section. FIGS. 27 and 28depict transverse cross-sectional views of the embodiment shown in FIG.26. In one embodiment, ferromagnetic section 426 is used to provide heatto hydrocarbon layers in the formation. Non-ferromagnetic section 428 isused in the overburden of the formation. Non-ferromagnetic section 428provides little or no heat to the overburden, thus inhibiting heatlosses in the overburden and improving heater efficiency. Ferromagneticsection 426 includes a ferromagnetic material such as 409 stainlesssteel or 410 stainless steel. Ferromagnetic section 426 has a thicknessof 0.3 cm. Non-ferromagnetic section 428 is copper with a thickness of0.3 cm. Inner conductor 430 is copper. Inner conductor 430 has adiameter of 0.9 cm. Electrical insulator 432 is silicon nitride, boronnitride, magnesium oxide powder, or another suitable insulator material.Electrical insulator 432 has a thickness of 0.1 cm to 0.3 cm.

FIG. 29 depicts a cross-sectional representation of an embodiment of atemperature limited heater with an outer conductor having aferromagnetic section and a non-ferromagnetic section placed inside asheath. FIGS. 30, 31, and 32 depict transverse cross-sectional views ofthe embodiment shown in FIG. 29. Ferromagnetic section 426 is 410stainless steel with a thickness of 0.6 cm. Non-ferromagnetic section428 is copper with a thickness of 0.6 cm. Inner conductor 430 is copperwith a diameter of 0.9 cm. Outer conductor 434 includes ferromagneticmaterial. Outer conductor 434 provides some heat in the overburdensection of the heater. Providing some heat in the overburden inhibitscondensation or refluxing of fluids in the overburden. Outer conductor434 is 409, 410, or 446 stainless steel with an outer diameter of 3.0 cmand a thickness of 0.6 cm. Electrical insulator 432 includes compactedmagnesium oxide powder with a thickness of 0.3 cm. In some embodiments,electrical insulator 432 includes silicon nitride, boron nitride, orhexagonal type boron nitride. Conductive section 436 may couple innerconductor 430 with ferromagnetic section 426 and/or outer conductor 434.

FIG. 33 depicts a cross-sectional representation of an embodiment of atemperature limited heater with a ferromagnetic outer conductor. Theheater is placed in a corrosion resistant jacket. A conductive layer isplaced between the outer conductor and the jacket. FIGS. 34 and 35depict transverse cross-sectional views of the embodiment shown in FIG.33. Outer conductor 434 is a ¾″ Schedule 80 446 stainless steel pipe. Inan embodiment, conductive layer 438 is placed between outer conductor434 and jacket 440. Conductive layer 438 is a copper layer. Outerconductor 434 is clad with conductive layer 438. In certain embodiments,conductive layer 438 includes one or more segments (for example,conductive layer 438 includes one or more copper tube segments). Jacket440 is a 1¼″ Schedule 80 347H stainless steel pipe or a 1½″ Schedule 160347H stainless steel pipe. In an embodiment, inner conductor 430 is 4/0MGT-1000 furnace cable with stranded nickel-coated copper wire withlayers of mica tape and glass fiber insulation. 4/0 MGT-1000 furnacecable is UL type 5107 (available from Allied Wire and Cable(Phoenixville, Pa.)). Conductive section 436 couples inner conductor 430and jacket 440. In an embodiment, conductive section 436 is copper.

FIG. 36 depicts a cross-sectional representation of an embodiment of atemperature limited heater with an outer conductor. The outer conductorincludes a ferromagnetic section and a non-ferromagnetic section. Theheater is placed in a corrosion resistant jacket. A conductive layer isplaced between the outer conductor and the jacket. FIGS. 37 and 38depict transverse cross-sectional views of the embodiment shown in FIG.36. Ferromagnetic section 426 is 409, 410, or 446 stainless steel with athickness of 0.9 cm. Non-ferromagnetic section 428 is copper with athickness of 0.9 cm. Ferromagnetic section 426 and non-ferromagneticsection 428 are placed in jacket 440. Jacket 440 is 304 or 347Hstainless steel with a thickness of 0.1 cm. Conductive layer 438 is acopper layer. Electrical insulator 432 includes compacted siliconnitride, boron nitride, or magnesium oxide powder with a thickness of0.1 to 0.3 cm. Inner conductor 430 is copper with a diameter of 1.0 cm.

In an embodiment, ferromagnetic section 426 is 446 stainless steel witha thickness of 0.9 cm. Jacket 440 is 410 stainless steel with athickness of 0.6 cm. 410 stainless steel has a higher Curie temperaturethan 446 stainless steel. Such a temperature limited heater may“contain” current such that the current does not easily flow from theheater to the surrounding formation and/or to any surrounding water (forexample, brine, groundwater, or formation water). In this embodiment, amajority of the current flows through ferromagnetic section 426 untilthe Curie temperature of the ferromagnetic section is reached. After theCurie temperature of ferromagnetic section 426 is reached, a majority ofthe current flows through conductive layer 438. The ferromagneticproperties of jacket 440 (410 stainless steel) inhibit the current fromflowing outside the jacket and “contain” the current. Jacket 440 mayalso have a thickness that provides strength to the temperature limitedheater.

FIG. 39 depicts a cross-sectional representation of an embodiment of atemperature limited heater. The heating section of the temperaturelimited heater includes non-ferromagnetic inner conductors and aferromagnetic outer conductor. The overburden section of the temperaturelimited heater includes a non-ferromagnetic outer conductor. FIGS. 40,41, and 42 depict transverse cross-sectional views of the embodimentshown in FIG. 39. Inner conductor 430 is copper with a diameter of 1.0cm. Electrical insulator 432 is placed between inner conductor 430 andconductive layer 438. Electrical insulator 432 includes compactedsilicon nitride, boron nitride, or magnesium oxide powder with athickness of 0.1 cm to 0.3 cm. Conductive layer 438 is copper with athickness of 0.1 cm. Insulation layer 442 is in the annulus outside ofconductive layer 438. The thickness of the annulus may be 0.3 cm.Insulation layer 442 is quartz sand.

Heating section 444 may provide heat to one or more hydrocarbon layersin the formation. Heating section 444 includes ferromagnetic materialsuch as 409 stainless steel or 410 stainless steel. Heating section 444has a thickness of 0.9 cm. Endcap 446 is coupled to an end of heatingsection 444. Endcap 446 electrically couples heating section 444 toinner conductor 430 and/or conductive layer 438. Endcap 446 is 304stainless steel. Heating section 444 is coupled to overburden section448. Overburden section 448 includes carbon steel and/or other suitablesupport materials. Overburden section 448 has a thickness of 0.6 cm.Overburden section 448 is lined with conductive layer 450. Conductivelayer 450 is copper with a thickness of 0.3 cm.

FIG. 43 depicts a cross-sectional representation of an embodiment of atemperature limited heater with an overburden section and a heatingsection. FIGS. 44 and 45 depict transverse cross-sectional views of theembodiment shown in FIG. 43. The overburden section includes portion430A of inner conductor 430. Portion 430A is copper with a diameter of1.3 cm. The heating section includes portion 430B of inner conductor430. Portion 430B is copper with a diameter of 0.5 cm. Portion 430B isplaced in ferromagnetic conductor 452. Ferromagnetic conductor 452 is446 stainless steel with a thickness of 0.4 cm. Electrical insulator 432includes compacted silicon nitride, boron nitride, or magnesium oxidepowder with a thickness of 0.2 cm. Outer conductor 434 is copper with athickness of 0.1 cm. Outer conductor 434 is placed in jacket 440. Jacket440 is 316H or 347H stainless steel with a thickness of 0.2 cm.

FIG. 46A and FIG. 46B depict cross-sectional representations of anembodiment of a temperature limited heater with a ferromagnetic innerconductor. Inner conductor 430 is a 1″ Schedule XXS 446 stainless steelpipe. In some embodiments, inner conductor 430 includes 409 stainlesssteel, 410 stainless steel, Invar 36, alloy 42-6, alloy 52, or otherferromagnetic materials. Inner conductor 430 has a diameter of 2.5 cm.Electrical insulator 432 includes compacted silicon nitride, boronnitride, or magnesium oxide powders; or polymers, Nextel ceramic fiber,mica, or glass fibers. Outer conductor 434 is copper or any othernon-ferromagnetic material such as aluminum. Outer conductor 434 iscoupled to jacket 440. Jacket 440 is 304H, 316H, or 347H stainlesssteel. In this embodiment, a majority of the heat is produced in innerconductor 430.

FIG. 47A and FIG. 47B depict cross-sectional representations of anembodiment of a temperature limited heater with a ferromagnetic innerconductor and a non-ferromagnetic core. Inner conductor 430 may be madeof 446 stainless steel, 409 stainless steel, 410 stainless steel, carbonsteel, Armco ingot iron, iron-cobalt alloys, or other ferromagneticmaterials. Core 454 may be tightly bonded inside inner conductor 430.Core 454 is copper or other non-ferromagnetic material. In certainembodiments, core 454 is inserted as a tight fit inside inner conductor430 before a drawing operation. In some embodiments, core 454 and innerconductor 430 are co-extrusion bonded. Outer conductor 434 is 347Hstainless steel. A drawing or rolling operation to compact electricalinsulator 432 (for example, compacted silicon nitride, boron nitride, ormagnesium oxide powder) may ensure good electrical contact between innerconductor 430 and core 454. In this embodiment, heat is producedprimarily in inner conductor 430 until the Curie temperature isapproached. Resistance then decreases sharply as current penetrates core454.

FIG. 48A and FIG. 48B depict cross-sectional representations of anembodiment of a temperature limited heater with a ferromagnetic outerconductor. Inner conductor 430 is nickel-clad copper. Electricalinsulator 432 is silicon nitride, boron nitride, or magnesium oxide.Outer conductor 434 is a 1″ Schedule XXS carbon steel pipe. In thisembodiment, heat is produced primarily in outer conductor 434, resultingin a small temperature differential across electrical insulator 432.

FIG. 49A and FIG. 49B depict cross-sectional representations of anembodiment of a temperature limited heater with a ferromagnetic outerconductor that is clad with a corrosion resistant alloy. Inner conductor430 is copper. Outer conductor 434 is a 1″ Schedule XXS carbon steelpipe. Outer conductor 434 is coupled to jacket 440. Jacket 440 is madeof corrosion resistant material (for example, 347H stainless steel).Jacket 440 provides protection from corrosive fluids in the wellbore(for example, sulfidizing and carburizing gases). Heat is producedprimarily in outer conductor 434, resulting in a small temperaturedifferential across electrical insulator 432.

FIG. 50A and FIG. 50B depict cross-sectional representations of anembodiment of a temperature limited heater with a ferromagnetic outerconductor. The outer conductor is clad with a conductive layer and acorrosion resistant alloy. Inner conductor 430 is copper. Electricalinsulator 432 is silicon nitride, boron nitride, or magnesium oxide.Outer conductor 434 is a 1″ Schedule 80 446 stainless steel pipe. Outerconductor 434 is coupled to jacket 440. Jacket 440 is made fromcorrosion resistant material such as 347H stainless steel. In anembodiment, conductive layer 438 is placed between outer conductor 434and jacket 440. Conductive layer 438 is a copper layer. Heat is producedprimarily in outer conductor 434, resulting in a small temperaturedifferential across electrical insulator 432. Conductive layer 438allows a sharp decrease in the resistance of outer conductor 434 as theouter conductor approaches the Curie temperature. Jacket 440 providesprotection from corrosive fluids in the wellbore.

In an embodiment, a temperature limited heater includes triaxialconductors. FIG. 51A and FIG. 51B depict cross-sectional representationsof an embodiment of a temperature limited heater with triaxialconductors. Inner conductor 430 may be copper or another highlyconductive material. Electrical insulator 432 may be silicon nitride,boron nitride, or magnesium oxide (in certain embodiments, as compactedpowders). Middle conductor 456 may include ferromagnetic material (forexample, 446 stainless steel). In the embodiment of FIGS. 51A and 51B,outer conductor 434 is separated from middle conductor 456 by electricalinsulator 432. Outer conductor 434 may include corrosion resistant,electrically conductive material (for example, stainless steel). In someembodiments, electrical insulator 432 is a space between conductors (forexample, an air gap or other gas gap) that electrically insulates theconductors (for example, conductors 430, 434, and 456 may be in aconductor-in-conduit-in-conduit arrangement).

In a temperature limited heater with triaxial conductors, such asdepicted in FIGS. 51A and 51B, electrical current may propagate throughtwo conductors in one direction and through the third conductor in anopposite direction. In FIGS. 51A and 51B, electrical current maypropagate in through middle conductor 456 in one direction and returnthrough inner conductor 430 and outer conductor 434 in an oppositedirection, as shown by the arrows in FIG. 51A and the +/− signs in FIG.51B. In an embodiment, electrical current is split approximately in halfbetween inner conductor 430 and outer conductor 434. Splitting theelectrical current between inner conductor 430 and outer conductor 434causes current propagating through middle conductor 456 to flow throughboth inside and outside skin depths of the middle conductor.

Current flows through both the inside and outside skin depths due toreduced magnetic field intensity from the current being split betweenthe outer conductor and the inner conductor. Reducing the magnetic fieldintensity allows the skin depth of middle conductor 456 to remainrelatively small with the same magnetic permeability. Thus, the thinnerinside and outside skin depths may produce an increased Curie effectcompared to the same thickness of ferromagnetic material with only oneskin depth. The thinner inside and outside skin depths may produce asharper turndown than one single skin depth in the same ferromagneticmaterial. Splitting the current between outer conductor 434 and innerconductor 430 may allow a thinner middle conductor 456 to produce thesame Curie effect as a thicker middle conductor. In certain embodiments,the materials and thicknesses used for outer conductor 434, innerconductor 430 and middle conductor 456 have to be balanced to producedesired results in the Curie effect and turndown ratio of a triaxialtemperature limited heater.

In some embodiments, the conductor (for example, an inner conductor, anouter conductor, or a ferromagnetic conductor) is the compositeconductor that includes two or more different materials. In certainembodiments, the composite conductor includes two or more ferromagneticmaterials. In some embodiments, the composite ferromagnetic conductorincludes two or more radially disposed materials. In certainembodiments, the composite conductor includes a ferromagnetic conductorand a non-ferromagnetic conductor. In some embodiments, the compositeconductor includes the ferromagnetic conductor placed over anon-ferromagnetic core. Two or more materials may be used to obtain arelatively flat electrical resistivity versus temperature profile in atemperature region below the Curie temperature and/or a sharp decrease(a high turndown ratio) in the electrical resistivity at or near theCurie temperature. In some cases, two or more materials are used toprovide more than one Curie temperature for the temperature limitedheater.

In certain embodiments, a composite electrical conductor is formed usinga billet co-extrusion process. A billet co-extrusion process may includecoupling together two or more electrical conductors at relatively hightemperatures (for example, at temperatures that are near or above 75% ofthe melting temperature of a conductor). The electrical conductors maybe drawn together at the relatively high temperatures (for example,under vacuum). Co-extrusion at high temperatures under vacuum exposesfresh metal surfaces during drawing while inhibiting oxidation of themetal surfaces. This type of co-extrusion improves the metallurgicalbond between coextruded metals. The drawn together conductors may thenbe cooled to form a composite electrical conductor made from the two ormore electrical conductors. In some embodiments, the compositeelectrical conductor is a solid composite electrical conductor. Incertain embodiments, the composite electrical conductor may be a tubularcomposite electrical conductor.

In one embodiment, a copper core is billet coextruded with a stainlesssteel conductor (for example, 446 stainless steel). The copper core andthe stainless steel conductor may be heated to a softening temperaturein vacuum. At the softening temperature, the stainless steel conductormay be drawn over the copper core to form a tight fit. The stainlesssteel conductor and copper core may then be cooled to form a compositeelectrical conductor with the stainless steel surrounding the coppercore.

In some embodiments, a long, composite electrical conductor is formedfrom several sections of composite electrical conductor. The sections ofcomposite electrical conductor may be formed by a billet co-extrusionprocess. The sections of composite electrical conductor may be coupledtogether using a welding process. FIGS. 52, 53, and 54 depictembodiments of coupled sections of composite electrical conductors. InFIG. 52, core 454 extends beyond the ends of inner conductor 430 in eachsection of a composite electrical conductor. In an embodiment, core 454is copper and inner conductor 430 is 446 stainless steel. Cores 454 fromeach section of the composite electrical conductor may be coupledtogether by, for example, brazing the core ends together. Core couplingmaterial 458 may couple the core ends together, as shown in FIG. 52.Core coupling material 458 may be, for example Everdur, a copper-siliconalloy material (for example, an alloy with about 3% by weight silicon incopper). Alternatively, the copper core may be autogenously welded orfilled with copper.

Inner conductor coupling material 460 may couple inner conductors 430from each section of the composite electrical conductor. Inner conductorcoupling material 460 may be material used for welding sections of innerconductor 430 together. In certain embodiments, inner conductor couplingmaterial 460 may be used for welding stainless steel inner conductorsections together. In some embodiments, inner conductor couplingmaterial 460 is 304 stainless steel or 310 stainless steel. A thirdmaterial (for example, 309 stainless steel) may be used to couple innerconductor coupling material 460 to ends of inner conductor 430. Thethird material may be needed or desired to produce a better bond (forexample, a better weld) between inner conductor 430 and inner conductorcoupling material 460. The third material may be non-magnetic to reducethe potential for a hot spot to occur at the coupling.

In certain embodiments, inner conductor coupling material 460 surroundsthe ends of cores 454 that protrude beyond the ends of inner conductors430, as shown in FIG. 52. Inner conductor coupling material 460 mayinclude one or more portions coupled together. Inner conductor couplingmaterial 460 may be placed in a clam shell configuration around the endsof cores 454 that protrude beyond the ends of inner conductors 430, asshown in the end view depicted in FIG. 53. Coupling material 462 may beused to couple together portions (for example, halves) of innerconductor coupling material 460. Coupling material 462 may be the samematerial as inner conductor coupling material 460 or another materialsuitable for coupling together portions of the inner conductor couplingmaterial.

In some embodiments, a composite electrical conductor includes innerconductor coupling material 460 with 304 stainless steel or 310stainless steel and inner conductor 430 with 446 stainless steel oranother ferromagnetic material. In such an embodiment, inner conductorcoupling material 460 produces significantly less heat than innerconductor 430. The portions of the composite electrical conductor thatinclude the inner conductor coupling material (for example, the weldedportions or “joints” of the composite electrical conductor) may remainat lower temperatures than adjacent material during application ofapplied electrical current to the composite electrical conductor. Thereliability and durability of the composite electrical conductor may beincreased by keeping the joints of the composite electrical conductor atlower temperatures.

FIG. 54 depicts an embodiment for coupling together sections of acomposite electrical conductor. Ends of cores 454 and ends of innerconductors 430 are beveled to facilitate coupling together the sectionsof the composite electrical conductor. Core coupling material 458 maycouple (for example, braze) together the ends of each core 454. The endsof each inner conductor 430 may be coupled (for example, welded)together with inner conductor coupling material 460. Inner conductorcoupling material 460 may be 309 stainless steel or another suitablewelding material. In some embodiments, inner conductor coupling material460 is 309 stainless steel. 309 stainless steel may reliably weld toboth an inner conductor having 446 stainless steel and a core havingcopper. Using beveled ends when coupling together sections of acomposite electrical conductor may produce a reliable and durablecoupling between the sections of composite electrical conductor. FIG. 54depicts a weld formed between ends of sections that have beveledsurfaces.

The composite electrical conductor may be used as the conductor in anyelectrical heater embodiment described herein. For example, thecomposite conductor may be used as the conductor in aconductor-in-conduit heater or an insulated conductor heater. In certainembodiments, the composite conductor may be coupled to a support membersuch as a support conductor. The support member may be used to providesupport to the composite conductor so that the composite conductor isnot relied upon for strength at or near the Curie temperature. Thesupport member may be useful for heaters of lengths of at least 100 m.The support member may be a non-ferromagnetic member that has good hightemperature creep strength. Examples of materials that are used for asupport member include, but are not limited to, Haynes® 625 alloy andHaynes® HR120® alloy (Haynes International, Kokomo, Ind.), NF709,Incoloy® 800H alloy and 347HP alloy (Allegheny Ludlum Corp., Pittsburgh,Pa.). In some embodiments, materials in a composite conductor aredirectly coupled (for example, brazed, metallurgically bonded, orswaged) to each other and/or the support member. Using a support membermay reduce the need for the ferromagnetic member to provide support forthe temperature limited heater, especially at or near the Curietemperature. Thus, the temperature limited heater may be designed withmore flexibility in the selection of ferromagnetic materials.

FIG. 55 depicts a cross-sectional representation of an embodiment of thecomposite conductor with the support member. Core 454 is surrounded byferromagnetic conductor 452 and support member 464. In some embodiments,core 454, ferromagnetic conductor 452, and support member 464 aredirectly coupled (for example, brazed together or metallurgically bondedtogether). In one embodiment, core 454 is copper, ferromagneticconductor 452 is 446 stainless steel, and support member 464 is 347Halloy. In certain embodiments, support member 464 is a Schedule 80 pipe.Support member 464 surrounds the composite conductor havingferromagnetic conductor 452 and core 454. Ferromagnetic conductor 452and core 454 may be joined to form the composite conductor by, forexample, a co-extrusion process. For example, the composite conductor isa 1.9 cm outside diameter 446 stainless steel ferromagnetic conductorsurrounding a 0.95 cm diameter copper core.

In certain embodiments, the diameter of core 454 is adjusted relative toa constant outside diameter of ferromagnetic conductor 452 to adjust theturndown ratio of the temperature limited heater. For example, thediameter of core 454 may be increased to 1.14 cm while maintaining theoutside diameter of ferromagnetic conductor 452 at 1.9 cm to increasethe turndown ratio of the heater.

In some embodiments, conductors (for example, core 454 and ferromagneticconductor 452) in the composite conductor are separated by supportmember 464. FIG. 56 depicts a cross-sectional representation of anembodiment of the composite conductor with support member 464 separatingthe conductors. In one embodiment, core 454 is copper with a diameter of0.95 cm, support member 464 is 347H alloy with an outside diameter of1.9 cm, and ferromagnetic conductor 452 is 446 stainless steel with anoutside diameter of 2.7 cm. The support member depicted in FIG. 56 has alower creep strength relative to the support members depicted in FIG.55.

In certain embodiments, support member 464 is located inside thecomposite conductor. FIG. 57 depicts a cross-sectional representation ofan embodiment of the composite conductor surrounding support member 464.Support member 464 is made of 347H alloy. Inner conductor 430 is copper.Ferromagnetic conductor 452 is 446 stainless steel. In one embodiment,support member 464 is 1.25 cm diameter 347H alloy, inner conductor 430is 1.9 cm outside diameter copper, and ferromagnetic conductor 452 is2.7 cm outside diameter 446 stainless steel. The turndown ratio ishigher than the turndown ratio for the embodiments depicted in FIGS. 55,56, and 58 for the same outside diameter, but it has a lower creepstrength.

In some embodiments, the thickness of inner conductor 430, which iscopper, is reduced and the thickness of support member 464 is increasedto increase the creep strength at the expense of reduced turndown ratio.For example, the diameter of support member 464 is increased to 1.6 cmwhile maintaining the outside diameter of inner conductor 430 at 1.9 cmto reduce the thickness of the conduit. This reduction in thickness ofinner conductor 430 results in a decreased turndown ratio relative tothe thicker inner conductor embodiment but an increased creep strength.

In one embodiment, support member 464 is a conduit (or pipe) insideinner conductor 430 and ferromagnetic conductor 452. FIG. 58 depicts across-sectional representation of an embodiment of the compositeconductor surrounding support member 464. In one embodiment, supportmember 464 is 347H alloy with a 0.63 cm diameter center hole. In someembodiments, support member 464 is a preformed conduit. In certainembodiments, support member 464 is formed by having a dissolvablematerial (for example, copper dissolvable by nitric acid) located insidethe support member during formation of the composite conductor. Thedissolvable material is dissolved to form the hole after the conductoris assembled. In an embodiment, support member 464 is 347H alloy with aninside diameter of 0.63 cm and an outside diameter of 1.6 cm, innerconductor 430 is copper with an outside diameter of 1.8 cm, andferromagnetic conductor 452 is 446 stainless steel with an outsidediameter of 2.7 cm.

In certain embodiments, the composite electrical conductor is used asthe conductor in the conductor-in-conduit heater. For example, thecomposite electrical conductor may be used as conductor 466 in FIG. 59.

FIG. 59 depicts a cross-sectional representation of an embodiment of theconductor-in-conduit heater. Conductor 466 is disposed in conduit 468.Conductor 466 is a rod or conduit of electrically conductive material.Low resistance sections 470 is present at both ends of conductor 466 togenerate less heating in these sections. Low resistance section 470 isformed by having a greater cross-sectional area of conductor 466 in thatsection, or the sections are made of material having less resistance. Incertain embodiments, low resistance section 470 includes a lowresistance conductor coupled to conductor 466.

Conduit 468 is made of an electrically conductive material. Conduit 468is disposed in opening 252 in hydrocarbon layer 254. Opening 252 has adiameter that accommodates conduit 468.

Conductor 466 may be centered in conduit 468 by centralizers 472.Centralizers 472 electrically isolate conductor 466 from conduit 468.Centralizers 472 inhibit movement and properly locate conductor 466 inconduit 468. Centralizers 472 are made of ceramic material or acombination of ceramic and metallic materials. Centralizers 472 inhibitdeformation of conductor 466 in conduit 468. Centralizers 472 aretouching or spaced at intervals between approximately 0.1 m (meters) andapproximately 3 m or more along conductor 466.

A second low resistance section 470 of conductor 466 may coupleconductor 466 to wellhead 474, as depicted in FIG. 59. Electricalcurrent may be applied to conductor 466 from power cable 476 through lowresistance section 470 of conductor 466. Electrical current passes fromconductor 466 through sliding connector 478 to conduit 468. Conduit 468may be electrically insulated from overburden casing 480 and fromwellhead 474 to return electrical current to power cable 476. Heat maybe generated in conductor 466 and conduit 468. The generated heat mayradiate in conduit 468 and opening 252 to heat at least a portion ofhydrocarbon layer 254.

Overburden casing 480 may be disposed in overburden 370. Overburdencasing 480 is, in some embodiments, surrounded by materials (forexample, reinforcing material and/or cement) that inhibit heating ofoverburden 370. Low resistance section 470 of conductor 466 may beplaced in overburden casing 480. Low resistance section 470 of conductor466 is made of, for example, carbon steel. Low resistance section 470 ofconductor 466 may be centralized in overburden casing 480 usingcentralizers 472. Centralizers 472 are spaced at intervals ofapproximately 6 m to approximately 12 m or, for example, approximately 9m along low resistance section 470 of conductor 466. In a heaterembodiment, low resistance section 470 of conductor 466 is coupled toconductor 466 by one or more welds. In other heater embodiments, lowresistance sections are threaded, threaded and welded, or otherwisecoupled to the conductor. Low resistance section 470 generates little orno heat in overburden casing 480. Packing 372 may be placed betweenoverburden casing 480 and opening 252. Packing 372 may be used as a capat the junction of overburden 370 and hydrocarbon layer 254 to allowfilling of materials in the annulus between overburden casing 480 andopening 252. In some embodiments, packing 372 inhibits fluid fromflowing from opening 252 to surface 482.

FIG. 60 depicts a cross-sectional representation of an embodiment of aremovable conductor-in-conduit heat source. Conduit 468 may be placed inopening 252 through overburden 370 such that a gap remains between theconduit and overburden casing 480. Fluids may be removed from opening252 through the gap between conduit 468 and overburden casing 480.Fluids may be removed from the gap through conduit 484. Conduit 468 andcomponents of the heat source included in the conduit that are coupledto wellhead 474 may be removed from opening 252 as a single unit. Theheat source may be removed as a single unit to be repaired, replaced,and/or used in another portion of the formation.

Water or other fluids inside conduit 468 can adversely affect heatingusing the conductor-in-conduit heater. In certain embodiments, fluidinside conduit 468 is removed to reduce the pressure inside the conduit.The fluid may be removed by vacuum pumping or other means for reducingthe pressure inside conduit 468. In some embodiments, the pressure isreduced outside conduit 468 and inside opening 252. In certainembodiments, the space inside conduit 468 or the space outside theconduit is vacuum pumped to a pressure below the vapor pressure of waterat the downhole temperature of the conduit. For example, at a downholetemperature of 25° C., the space inside or outside conduit 468 would bevacuum pumped to a pressure below about 101 kPa.

In certain embodiments, the space inside or outside conduit 468 isvacuum pumped to a pressure below the vapor pressure of water at icetemperatures. The vapor pressure of ice at 0° C. is 610 Pa. As conduit468 is vacuum pumped, water in the conduit gets colder until the waterfreezes. Thus, vacuum pumping to a pressure below the vapor pressure ofwater at ice temperatures indicates that most or all of the water hasbeen removed from the space inside or outside conduit 468. In certainembodiments, high pumping capacity vacuum pumps (for example, a Kinney®CB245 vacuum pump available from Tuthill Co. (Burr Ridge, Ill.)) areused to vacuum pump below pressures of about 1 Pa. In some embodiments,a vacuum gauge is coupled between the vacuum pump and the wellhead forthe heater. In some embodiments, a cold trap (for example, a dry icetrap or liquid nitrogen trap) is placed between conduit 468 and thevacuum pump to condense water from the conduit and inhibit water fromcontaminating pump oil.

As pressure in conduit 468 is decreased, ice in the conduit gets colderand the vapor pressure of the ice further decreases. For example, thevapor pressure of ice at (−10)° C. is 260 Pa. Thus, in certainembodiments, the space inside or outside conduit 468 is vacuum pumped toa pressure below 1 kPa, below 750 Pa, below 600 Pa, below 500 Pa, below100 Pa, 15 Pa, below 10 Pa, below 5 Pa, or less. Vacuum pumping to suchpressures improves the removal of water from conduit 468.

In some embodiments, conduit 468 is vacuum pumped to a selected pressureand then the conduit is closed off (pressure sealed), for example, byclosing a valve on the wellhead. The pressure in conduit 468 ismonitored for any pressure rise. If the pressure rises to a value nearthe vapor pressure of water or ice and at least temporarily stabilizes,there is most likely more water in the conduit and the conduit is thenvacuum pumped again. If the pressure does not rise up to the vaporpressure of ice or water, then conduit 468 is considered dry. If thepressure continuously rises to pressures above the vapor pressure of iceor water, then there may be a leak in conduit 468 causing the pressurerise.

In certain embodiments, heat is provided by conductor 466 and/or conduit468 during vacuum pumping of the conduit. The provided heat may increasethe vapor pressure of water or ice in conduit 468. The provided heat mayinhibit ice from forming in conduit 468. Providing heat in conduit 468may decrease the time needed to remove (vacuum pump) water from theconduit. Providing heat in conduit 468 may increase the likelihood ofremoving substantially all the water from the conduit.

In some embodiments, a non-condensable gas (for example, dry nitrogen,argon, or helium) is backfilled inside or outside conduit 468 aftervacuum pumping. In some embodiments, the space inside or outside conduit468 is backfilled with the non-condensable gas to a pressure between 101kPa and 10 MPa, between 202 kPa and 5 MPa, or between 500 kPa and 1 MPa.In some embodiments, the inside or outside of conduit 468 is vacuumpumped for a time, then backfilled with non-condensable gas, and thenvacuum pumped again. This process may be repeated for several cycles tomore completely remove water and other fluids from inside or outsideconduit 468. In some embodiments, conduit 468 is operated with thebackfilled non-condensable gas remaining inside or outside the conduit.

In some embodiments, a small amount of an oxidizing fluid, such asoxygen, is added to the non-condensable gas backfilled in conduit 468.The oxidizing fluid may oxidize metals of conduit 468 and/or conductor466. The oxidation may increase the emissivity of the conduit and/orconductor metals. The small amount of oxidizing fluid may be betweenabout 100 ppm and 25 ppm, between about 75 ppm and 40 ppm, or betweenabout 60 ppm and 50 ppm in the non-condensable gas. In one embodiment,at most 50 ppm of oxidizing fluid is in the non-condensable gas inconduit 468.

FIG. 61 depicts an embodiment of a sliding connector. Sliding connector478 may be coupled near an end of conductor 466. Sliding connector 478may be positioned near a bottom end of conduit 468. Sliding connector478 may electrically couple conductor 466 to conduit 468. Slidingconnector 478 may move during use to accommodate thermal expansionand/or contraction of conductor 466 and conduit 468 relative to eachother. In some embodiments, sliding connector 478 may be attached to lowresistance section 470 of conductor 466. The lower resistance of lowresistance section 470 may allow the sliding connector to be at atemperature that does not exceed about 90° C. Maintaining slidingconnector 478 at a relatively low temperature may inhibit corrosion ofthe sliding connector and promote good contact between the slidingconnector and conduit 468.

Sliding connector 478 may include scraper 486. Scraper 486 may abut aninner surface of conduit 468 at point 488. Scraper 486 may include anymetal or electrically conducting material (for example, steel orstainless steel). Centralizer 490 may couple to conductor 466. In someembodiments, sliding connector 478 is positioned on low resistancesection 470 of conductor 466. Centralizer 490 may include anyelectrically conducting material (for example, a metal or metal alloy).Spring bow 492 may couple scraper 486 to centralizer 490. Spring bow 492may include any metal or electrically conducting material (for example,copper-beryllium alloy). In some embodiments, centralizer 490, springbow 492, and/or scraper 486 are welded together.

More than one sliding connector 478 may be used for redundancy and toreduce the current through each scraper 486. In addition, a thickness ofconduit 468 may be increased for a length adjacent to sliding connector478 to reduce heat generated in that portion of conduit. The length ofconduit 468 with increased thickness may be, for example, approximately6 m. In certain embodiments, electrical contact may be made betweencentralizer 490 and scraper 486 (shown in FIG. 61) on sliding connector478 using an electrical conductor (for example, a copper wire) that hasa lower electrical resistance than spring bow 492. Electrical currentmay flow through the electrical conductor rather than spring bow 492 sothat the spring bow has a longer lifetime.

FIG. 62A depicts an embodiment of contacting sections for aconductor-in-conduit heater. Conductor 466 and conduit 468 form theconductor-in-conduit heater. In the upper contact section, lead-in cable494 provides power to conductor 466 and conduit 468. Connector 496couples lead-in cable 494 to conductor 466. Conductor 466 is supportedby rod 498. In certain embodiments, rod 498 is a sucker rod such as afiberglass, stainless steel, or carbon steel sucker rod. A fiberglasssucker rod may have lower proximity effect losses than stainless steelor carbon steel. Rod 498 and conductor 466 are electrically isolated byisolation sub 500.

Return electrical current enters the upper contacting section throughconduit 468. Conduit 468 is electrically coupled to return cable 502through contactor 504. In certain embodiments, liner 506 is located onthe inside of conduit 468 to promote electrical contact between theconduit and contactor 504. In certain embodiments, liner 506 is copper.In some embodiments, conduit 468 includes one or more isolation subs500. Isolation subs 500 in conduit 468 inhibit any current flow tosections above the contacting section of the conduit. Isolation subs 500may be, for example fiberglass sections of conduit 468 or electricallyinsulating epoxy threaded sections in the conduit.

Lead-in cable 494 and return cable 502 may be 4-0 copper cable withTEFLON® insulation. Using copper cables to make electrical contact inthe upper contacting section may be less expensive than other contactingmethods such as cladding. In certain embodiments, more than one cable isused for lead-in cable 494 and/or return cable 502. FIG. 62B depicts anaerial view of the upper contact section of the conductor-in-conduitheater in FIG. 62A with three lead-in cables 494 and three return cables502. The cables are coupled to rod 498 with strap 508. Centralizers 472maintain a position of rod 498 in conduit 468. The lead-in cables andreturn cables may be paired off in three pairs. Each pair may have onelead-in cable 494 and one return cable 502. Thus, in each cable pair,one cable carries current downwards (lead-in cables) and one cablecarries current upwards (return cables). This opposite current flow ineach pair reduces skin effect losses in the upper contacting section. Inaddition, splitting the lead-in and return current between severalcables reduces electrical loss and heat loss in the upper contactingsection.

In the lower contacting section shown in FIG. 62A, conductor 466 iselectrically coupled to conduit 468 through contactor 504. In certainembodiments, liner 506 is located on the inside of conduit 468 topromote electrical contact between the conduit and contactor 504.

In some embodiments, a fiber optic system including an optical sensor isused to continuously monitor parameters (for example, temperature,pressure, and/or strain) along a portion and/or the entire length of aheater assembly. In certain embodiments, an optical sensor is used tomonitor composition of gas at one or more locations along the opticalsensor. The optical sensor may include, but is not limited to, a hightemperature rated optical fiber (for example, a single mode fiber or amultimode fiber) or fiber optic cable. A Sensornet DTS system(Sensornet; London, U.K.) includes an optical fiber that is used tomonitor temperature along a length of a heater assembly. A Sensornet DTSsystem includes an optical fiber that is used to monitor temperature andstrain (and/or pressure) at the same time along a length of a heaterassembly.

In some embodiments, an optical sensor used to monitor temperature,strain, and/or pressure is protected by positioning, at least partially,the optical sensor in a protective sleeve (such as an enclosed tube)resistant to conditions in a downhole environment. In certainembodiments, the protective sleeve is a small stainless steel tube. Insome embodiments, an open-ended sleeve is used to allow determination ofgas composition at the surface and/or at the terminal end of an oxidizerassembly. The optical sensor may be pre-installed in a protective sleeveand coiled on a reel. The sleeve may be uncoiled from the reel andcoupled to a heater assembly. In some embodiments, an optical sensor ina protective sleeve is lowered into a section of the formation with aheater assembly.

In certain embodiments, the sleeve is placed down a hollow conductor ofa conductor-in-conduit heater. In some embodiments, the fiber opticcable is a high temperature rated fiber optic cable. FIG. 63 depicts anembodiment of sleeve 510 in a conductor-in-conduit heater. Conductor 466may be a hollow conductor. Sleeve 510 may be placed inside conductor466. Sleeve 510 may be moved to a position inside conductor 466 byproviding a pressurized fluid (for example, a pressurized inert gas)into the conductor to move the sleeve along a length of the conductor.Sleeve 510 may have a plug 512 located at an end of the sleeve so thatthe sleeve may be moved by the pressurized fluid. Plug 512 may be of adiameter slightly smaller than an inside diameter of conductor 466 sothat the plug is allowed to move along the inside of the conductor. Insome embodiments, plug 512 may have small openings to allow some fluidto flow past the plug. Conductor 466 may have an open end or a closedend with openings at the end to allow pressure release from the end ofthe conductor so that sleeve 510 and plug 512 can move along the insideof the conductor. In certain embodiments, sleeve 510 may be placedinside any hollow conduit or conductor in any type of heater.

Using a pressurized fluid to position sleeve 510 inside conductor 466allows for selected positioning of the sleeve. The pressure of the fluidused to move sleeve 510 inside conductor 466 may be set to move thesleeve a selected distance in the conductor so that the sleeve ispositioned as desired. In certain embodiments, sleeve 510 may beremovable from conductor 466 so that the sleeve can be repaired and/orreplaced.

Temperatures monitored by the fiber optic cable may depend uponpositioning of sleeve 510. In certain embodiments, sleeve 510 ispositioned in an annulus between the conduit and the conductor orbetween the conduit and an opening in the formation. In certainembodiments, sleeve 510 with enclosed fiber optic cable is wrappedspirally to enhance resolution.

In certain embodiments, centralizers (such as centralizers 472 depictedin FIGS. 59 and 60) are made of silicon nitride. In some embodiments,silicon nitride is gas pressure sintered reaction bonded siliconnitride. Gas pressure sintered reaction bonded silicon nitride can bemade by sintering the silicon nitride at 1800° C. in a 10.3 MPa nitrogenatmosphere to inhibit degradation of the silicon nitride duringsintering. One example of a gas pressure sintered reaction bondedsilicon nitride is obtained from Ceradyne, Inc. (Costa Mesa, Calif.,U.S.A.) as Ceralloy® 147-31N.

Gas pressure sintered reaction bonded silicon nitride may be ground to afine finish. The fine finish (which gives a very low surface porosity ofthe silicon nitride) allows the silicon nitride to slide easily alongmetal surfaces without picking up metal particles from the surfaces. Gaspressure sintered reaction bonded silicon nitride is a very densematerial with high tensile strength, high flexural mechanical strength,and high thermal impact stress characteristics. Gas pressure sinteredreaction bonded silicon nitride is an excellent high temperatureelectrical insulator. Gas pressure sintered reaction bonded siliconnitride has about the same leakage current at 900° C. as alumina (Al₂O₃)at 760° C. Gas pressure sintered reaction bonded silicon nitride has athermal conductivity of 25 watts per meter·K. The relatively highthermal conductivity promotes heat transfer away from the centerconductor of a conductor-in-conduit heater.

Other types of silicon nitride such as, but not limited to,reaction-bonded silicon nitride or hot isostatically pressed siliconnitride may be used. Hot isostatic pressing includes sintering granularsilicon nitride and additives at 100-200 MPa in nitrogen gas. Somesilicon nitrides are made by sintering silicon nitride with yttriumoxide or cerium oxide to lower the sintering temperature so that thesilicon nitride does not degrade (for example, by releasing nitrogen)during sintering. However, adding other material to the silicon nitridemay increase the leakage current of the silicon nitride at elevatedtemperatures compared to purer forms of silicon nitride.

FIG. 64 depicts an embodiment of a conductor-in-conduit temperaturelimited heater. Conductor 466 is coupled to ferromagnetic conductor 452(for example, clad, coextruded, press fit, drawn inside). In someembodiments, ferromagnetic conductor 452 is coextruded over conductor466. Ferromagnetic conductor 452 is coupled to the outside of conductor466 so that current propagates only through the skin depth of theferromagnetic conductor at room temperature. Ferromagnetic conductor 452provides mechanical support for conductor 466 at elevated temperatures.Ferromagnetic conductor 452 is, for example, iron, iron alloy, or anyother ferromagnetic material. In an embodiment, conductor 466 is copperand ferromagnetic conductor 452 is 446 stainless steel.

Conductor 466 and ferromagnetic conductor 452 are electrically coupledto conduit 468 with sliding connector 478. Conduit 468 is anon-ferromagnetic material such as, but not limited to, 347H stainlesssteel. In one embodiment, conduit 468 is a 1½″ Schedule 80 347Hstainless steel pipe. In another embodiment, conduit 468 is a ScheduleXXH 347H stainless steel pipe. One or more centralizers 472 maintain thegap between conduit 468 and ferromagnetic conductor 452. In anembodiment, centralizer 472 is made of gas pressure sintered reactionbonded silicon nitride. Centralizer 472 may be held in position onferromagnetic conductor 452 by one or more weld tabs located on theferromagnetic conductor.

In certain embodiments, the composite electrical conductor may be usedas a conductor in an insulated conductor heater. FIG. 65A and FIG. 65Bdepict an embodiment of the insulated conductor heater. Insulatedconductor 514 includes core 454 and inner conductor 430. Core 454 andinner conductor 430 are a composite electrical conductor. Core 454 andinner conductor 430 are located within insulator 432. Core 454, innerconductor 430, and insulator 432 are located inside outer conductor 434.Insulator 432 is silicon nitride, boron nitride, magnesium oxide, oranother suitable electrical insulator. Outer conductor 434 is copper,steel, or any other electrical conductor.

In certain embodiments, insulator 432 is a powdered insulator. In someembodiments, insulator 432 is an insulator with a preformed shape (forexample, preformed half-shells). Insulated conductor 514 may be formedusing several techniques known in the art. Examples of techniques forforming insulated conductors include a “weld-fill-draw” method or a“fill-draw” method. Insulated conductors made using these techniques maybe made by, for example, Tyco International, Inc. (Princeton, N.J.) orWatlow Electric Manufacturing Co. (St. Louis, Mo.).

In some embodiments, jacket 440 is located outside outer conductor 434,as shown in FIG. 66A and FIG. 66B. In some embodiments, jacket 440 is304 stainless steel and outer conductor 434 is copper. Jacket 440provides corrosion resistance for the insulated conductor heater. Insome embodiments, jacket 440 and outer conductor 434 are preformedstrips that are drawn over insulator 432 to form insulated conductor514.

In certain embodiments, insulated conductor 514 is located in a conduitthat provides protection (for example, corrosion protection, degradationprotection, and mechanical deformation protection) for the insulatedconductor. In FIG. 67, insulated conductor 514 is located inside conduit468 with gap 516 separating the insulated conductor from the conduit.

For a temperature limited heater in which the ferromagnetic conductorprovides a majority of the resistive heat output below the Curietemperature, a majority of the current flows through material withhighly non-linear functions of magnetic field (H) versus magneticinduction (B). These non-linear functions may cause strong inductiveeffects and distortion that lead to decreased power factor in thetemperature limited heater at temperatures below the Curie temperature.These effects may render the electrical power supply to the temperaturelimited heater difficult to control and may result in additional currentflow through surface and/or overburden power supply conductors.Expensive and/or difficult to implement control systems such as variablecapacitors or modulated power supplies may be used to attempt tocompensate for these effects and to control temperature limited heaterswhere the majority of the resistive heat output is provided by currentflow through the ferromagnetic material.

In certain temperature limited heater embodiments, the ferromagneticconductor confines a majority of the flow of electrical current to anelectrical conductor coupled to the ferromagnetic conductor when thetemperature limited heater is below or near the Curie temperature of theferromagnetic conductor. The electrical conductor may be a sheath,jacket, support member, corrosion resistant member, or otherelectrically resistive member. In some embodiments, the ferromagneticconductor confines a majority of the flow of electrical current to theelectrical conductor positioned between an outermost layer and theferromagnetic conductor. The ferromagnetic conductor is located in thecross section of the temperature limited heater such that the magneticproperties of the ferromagnetic conductor at or below the Curietemperature of the ferromagnetic conductor confine the majority of theflow of electrical current to the electrical conductor. The majority ofthe flow of electrical current is confined to the electrical conductordue to the skin effect of the ferromagnetic conductor. Thus, themajority of the current is flowing through material with substantiallylinear resistive properties throughout most of the operating range ofthe heater.

In certain embodiments, the ferromagnetic conductor and the electricalconductor are located in the cross section of the temperature limitedheater so that the skin effect of the ferromagnetic material limits thepenetration depth of electrical current in the electrical conductor andthe ferromagnetic conductor at temperatures below the Curie temperatureof the ferromagnetic conductor. Thus, the electrical conductor providesa majority of the electrically resistive heat output of the temperaturelimited heater at temperatures up to a temperature at or near the Curietemperature of the ferromagnetic conductor. In certain embodiments, thedimensions of the electrical conductor may be chosen to provide desiredheat output characteristics.

Because the majority of the current flows through the electricalconductor below the Curie temperature, the temperature limited heaterhas a resistance versus temperature profile that at least partiallyreflects the resistance versus temperature profile of the material inthe electrical conductor. Thus, the resistance versus temperatureprofile of the temperature limited heater is substantially linear belowthe Curie temperature of the ferromagnetic conductor if the material inthe electrical conductor has a substantially linear resistance versustemperature profile. For example, the temperature limited heater inwhich the majority of the current flows in the electrical conductorbelow the Curie temperature may have a resistance versus temperatureprofile similar to the profile shown in FIG. 144. The resistance of thetemperature limited heater has little or no dependence on the currentflowing through the heater until the temperature nears the Curietemperature. The majority of the current flows in the electricalconductor rather than the ferromagnetic conductor below the Curietemperature.

Resistance versus temperature profiles for temperature limited heatersin which the majority of the current flows in the electrical conductoralso tend to exhibit sharper reductions in resistance near or at theCurie temperature of the ferromagnetic conductor. For example, thereduction in resistance shown in FIG. 144 is sharper than the reductionin resistance shown in FIG. 128. The sharper reductions in resistancenear or at the Curie temperature are easier to control than more gradualresistance reductions near the Curie temperature.

In certain embodiments, the material and/or the dimensions of thematerial in the electrical conductor are selected so that thetemperature limited heater has a desired resistance versus temperatureprofile below the Curie temperature of the ferromagnetic conductor.

Temperature limited heaters in which the majority of the current flowsin the electrical conductor rather than the ferromagnetic conductorbelow the Curie temperature are easier to predict and/or control.Behavior of temperature limited heaters in which the majority of thecurrent flows in the electrical conductor rather than the ferromagneticconductor below the Curie temperature may be predicted by, for example,its resistance versus temperature profile and/or its power factor versustemperature profile. Resistance versus temperature profiles and/or powerfactor versus temperature profiles may be assessed or predicted by, forexample, experimental measurements that assess the behavior of thetemperature limited heater, analytical equations that assess or predictthe behavior of the temperature limited heater, and/or simulations thatassess or predict the behavior of the temperature limited heater.

In certain embodiments, assessed or predicted behavior of thetemperature limited heater is used to control the temperature limitedheater. The temperature limited heater may be controlled based onmeasurements (assessments) of the resistance and/or the power factorduring operation of the heater. In some embodiments, the power, orcurrent, supplied to the temperature limited heater is controlled basedon assessment of the resistance and/or the power factor of the heaterduring operation of the heater and the comparison of this assessmentversus the predicted behavior of the heater. In certain embodiments, thetemperature limited heater is controlled without measurement of thetemperature of the heater or a temperature near the heater. Controllingthe temperature limited heater without temperature measurementeliminates operating costs associated with downhole temperaturemeasurement. Controlling the temperature limited heater based onassessment of the resistance and/or the power factor of the heater alsoreduces the time for making adjustments in the power or current suppliedto the heater compared to controlling the heater based on measuredtemperature.

As the temperature of the temperature limited heater approaches orexceeds the Curie temperature of the ferromagnetic conductor, reductionin the ferromagnetic properties of the ferromagnetic conductor allowselectrical current to flow through a greater portion of the electricallyconducting cross section of the temperature limited heater. Thus, theelectrical resistance of the temperature limited heater is reduced andthe temperature limited heater automatically provides reduced heatoutput at or near the Curie temperature of the ferromagnetic conductor.In certain embodiments, a highly electrically conductive member iscoupled to the ferromagnetic conductor and the electrical conductor toreduce the electrical resistance of the temperature limited heater at orabove the Curie temperature of the ferromagnetic conductor. The highlyelectrically conductive member may be an inner conductor, a core, oranother conductive member of copper, aluminum, nickel, or alloysthereof.

The ferromagnetic conductor that confines the majority of the flow ofelectrical current to the electrical conductor at temperatures below theCurie temperature may have a relatively small cross section compared tothe ferromagnetic conductor in temperature limited heaters that use theferromagnetic conductor to provide the majority of resistive heat outputup to or near the Curie temperature. A temperature limited heater thatuses the electrical conductor to provide a majority of the resistiveheat output below the Curie temperature has low magnetic inductance attemperatures below the Curie temperature because less current is flowingthrough the ferromagnetic conductor as compared to the temperaturelimited heater where the majority of the resistive heat output below theCurie temperature is provided by the ferromagnetic material. Magneticfield (H) at radius (r) of the ferromagnetic conductor is proportionalto the current (I) flowing through the ferromagnetic conductor and thecore divided by the radius, or:

H∝I/r.  (4)

Since only a portion of the current flows through the ferromagneticconductor for a temperature limited heater that uses the outer conductorto provide a majority of the resistive heat output below the Curietemperature, the magnetic field of the temperature limited heater may besignificantly smaller than the magnetic field of the temperature limitedheater where the majority of the current flows through the ferromagneticmaterial. The relative magnetic permeability 40 may be large for smallmagnetic fields.

The skin depth (δ) of the ferromagnetic conductor is inverselyproportional to the square root of the relative magnetic permeability40:

δ∝(1/μ)^(1/2).  (5)

Increasing the relative magnetic permeability decreases the skin depthof the ferromagnetic conductor. However, because only a portion of thecurrent flows through the ferromagnetic conductor for temperatures belowthe Curie temperature, the radius (or thickness) of the ferromagneticconductor may be decreased for ferromagnetic materials with largerelative magnetic permeabilities to compensate for the decreased skindepth while still allowing the skin effect to limit the penetrationdepth of the electrical current to the electrical conductor attemperatures below the Curie temperature of the ferromagnetic conductor.The radius (thickness) of the ferromagnetic conductor may be between 0.3mm and 8 mm, between 0.3 mm and 2 mm, or between 2 mm and 4 mm dependingon the relative magnetic permeability of the ferromagnetic conductor.Decreasing the thickness of the ferromagnetic conductor decreases costsof manufacturing the temperature limited heater, as the cost offerromagnetic material tends to be a significant portion of the cost ofthe temperature limited heater. Increasing the relative magneticpermeability of the ferromagnetic conductor provides a higher turndownratio and a sharper decrease in electrical resistance for thetemperature limited heater at or near the Curie temperature of theferromagnetic conductor.

Ferromagnetic materials (such as purified iron or iron-cobalt alloys)with high relative magnetic permeabilities (for example, at least 200,at least 1000, at least 1×10⁴, or at least 1×10⁵) and/or high Curietemperatures (for example, at least 600° C., at least 700° C., or atleast 800° C.) tend to have less corrosion resistance and/or lessmechanical strength at high temperatures. The electrical conductor mayprovide corrosion resistance and/or high mechanical strength at hightemperatures for the temperature limited heater. Thus, the ferromagneticconductor may be chosen primarily for its ferromagnetic properties.

Confining the majority of the flow of electrical current to theelectrical conductor below the Curie temperature of the ferromagneticconductor reduces variations in the power factor. Because only a portionof the electrical current flows through the ferromagnetic conductorbelow the Curie temperature, the non-linear ferromagnetic properties ofthe ferromagnetic conductor have little or no effect on the power factorof the temperature limited heater, except at or near the Curietemperature. Even at or near the Curie temperature, the effect on thepower factor is reduced compared to temperature limited heaters in whichthe ferromagnetic conductor provides a majority of the resistive heatoutput below the Curie temperature. Thus, there is less or no need forexternal compensation (for example, variable capacitors or waveformmodification) to adjust for changes in the inductive load of thetemperature limited heater to maintain a relatively high power factor.

In certain embodiments, the temperature limited heater, which confinesthe majority of the flow of electrical current to the electricalconductor below the Curie temperature of the ferromagnetic conductor,maintains the power factor above 0.85, above 0.9, or above 0.95 duringuse of the heater. Any reduction in the power factor occurs only insections of the temperature limited heater at temperatures near theCurie temperature. Most sections of the temperature limited heater aretypically not at or near the Curie temperature during use. Thesesections have a high power factor that approaches 1.0. The power factorfor the entire temperature limited heater is maintained above 0.85,above 0.9, or above 0.95 during use of the heater even if some sectionsof the heater have power factors below 0.85.

Maintaining high power factors also allows for less expensive powersupplies and/or control devices such as solid state power supplies orSCRs (silicon controlled rectifiers). These devices may fail to operateproperly if the power factor varies by too large an amount because ofinductive loads. With the power factors maintained at the higher values;however, these devices may be used to provide power to the temperaturelimited heater. Solid state power supplies also have the advantage ofallowing fine tuning and controlled adjustment of the power supplied tothe temperature limited heater.

In some embodiments, transformers are used to provide power to thetemperature limited heater. Multiple voltage taps may be made into thetransformer to provide power to the temperature limited heater. Multiplevoltage taps allows the current supplied to switch back and forthbetween the multiple voltages. This maintains the current within a rangebound by the multiple voltage taps.

The highly electrically conductive member, or inner conductor, increasesthe turndown ratio of the temperature limited heater. In certainembodiments, thickness of the highly electrically conductive member isincreased to increase the turndown ratio of the temperature limitedheater. In some embodiments, the thickness of the electrical conductoris reduced to increase the turndown ratio of the temperature limitedheater. In certain embodiments, the turndown ratio of the temperaturelimited heater is between 1.1 and 10, between 2 and 8, or between 3 and6 (for example, the turndown ratio is at least 1.1, at least 2, or atleast 3).

FIG. 68 depicts an embodiment of a temperature limited heater in whichthe support member provides a majority of the heat output below theCurie temperature of the ferromagnetic conductor. Core 454 is an innerconductor of the temperature limited heater. In certain embodiments,core 454 is a highly electrically conductive material such as copper oraluminum. In some embodiments, core 454 is a copper alloy that providesmechanical strength and good electrically conductivity such as adispersion strengthened copper. In one embodiment, core 454 is Glidcop®(SCM Metal Products, Inc., Research Triangle Park, N.C.). Ferromagneticconductor 452 is a thin layer of ferromagnetic material betweenelectrical conductor 518 and core 454. In certain embodiments,electrical conductor 518 is also support member 464. In certainembodiments, ferromagnetic conductor 452 is iron or an iron alloy. Insome embodiments, ferromagnetic conductor 452 includes ferromagneticmaterial with a high relative magnetic permeability. For example,ferromagnetic conductor 452 may be purified iron such as Armco ingotiron (AK Steel Ltd., United Kingdom). Iron with some impuritiestypically has a relative magnetic permeability on the order of 400.Purifying the iron by annealing the iron in hydrogen gas (H₂) at 1450°C. increases the relative magnetic permeability of the iron. Increasingthe relative magnetic permeability of ferromagnetic conductor 452 allowsthe thickness of the ferromagnetic conductor to be reduced. For example,the thickness of unpurified iron may be approximately 4.5 mm while thethickness of the purified iron is approximately 0.76 mm.

In certain embodiments, electrical conductor 518 provides support forferromagnetic conductor 452 and the temperature limited heater.Electrical conductor 518 may be made of a material that provides goodmechanical strength at temperatures near or above the Curie temperatureof ferromagnetic conductor 452. In certain embodiments, electricalconductor 518 is a corrosion resistant member. Electrical conductor 518(support member 464) may provide support for ferromagnetic conductor 452and corrosion resistance. Electrical conductor 518 is made from amaterial that provides desired electrically resistive heat output attemperatures up to and/or above the Curie temperature of ferromagneticconductor 452.

In an embodiment, electrical conductor 518 is 347H stainless steel. Insome embodiments, electrical conductor 518 is another electricallyconductive, good mechanical strength, corrosion resistant material. Forexample, electrical conductor 518 may be 304H, 316H, 347HH, NF709,Incoloy® 800H alloy (Inco Alloys International, Huntington, W. Va.),Haynes® HR120® alloy, or Inconel® 617 alloy.

In some embodiments, electrical conductor 518 (support member 464)includes different alloys in different portions of the temperaturelimited heater. For example, a lower portion of electrical conductor 518(support member 464) is 347H stainless steel and an upper portion of theelectrical conductor (support member) is NF709. In certain embodiments,different alloys are used in different portions of the electricalconductor (support member) to increase the mechanical strength of theelectrical conductor (support member) while maintaining desired heatingproperties for the temperature limited heater.

In some embodiments, ferromagnetic conductor 452 includes differentferromagnetic conductors in different portions of the temperaturelimited heater. Different ferromagnetic conductors may be used indifferent portions of the temperature limited heater to vary the Curietemperature and, thus, the maximum operating temperature in thedifferent portions. In some embodiments, the Curie temperature in anupper portion of the temperature limited heater is lower than the Curietemperature in a lower portion of the heater. The lower Curietemperature in the upper portion increases the creep-rupture strengthlifetime in the upper portion of the heater.

In the embodiment depicted in FIG. 68, ferromagnetic conductor 452,electrical conductor 518, and core 454 are dimensioned so that the skindepth of the ferromagnetic conductor limits the penetration depth of themajority of the flow of electrical current to the support member whenthe temperature is below the Curie temperature of the ferromagneticconductor. Thus, electrical conductor 518 provides a majority of theelectrically resistive heat output of the temperature limited heater attemperatures up to a temperature at or near the Curie temperature offerromagnetic conductor 452. In certain embodiments, the temperaturelimited heater depicted in FIG. 68 is smaller (for example, an outsidediameter of 3 cm, 2.9 cm, 2.5 cm, or less) than other temperaturelimited heaters that do not use electrical conductor 518 to provide themajority of electrically resistive heat output. The temperature limitedheater depicted in FIG. 68 may be smaller because ferromagneticconductor 452 is thin as compared to the size of the ferromagneticconductor needed for a temperature limited heater in which the majorityof the resistive heat output is provided by the ferromagnetic conductor.

In some embodiments, the support member and the corrosion resistantmember are different members in the temperature limited heater. FIGS. 69and 70 depict embodiments of temperature limited heaters in which thejacket provides a majority of the heat output below the Curietemperature of the ferromagnetic conductor. In these embodiments,electrical conductor 518 is jacket 440. Electrical conductor 518,ferromagnetic conductor 452, support member 464, and core 454 (in FIG.69) or inner conductor 430 (in FIG. 70) are dimensioned so that the skindepth of the ferromagnetic conductor limits the penetration depth of themajority of the flow of electrical current to the thickness of thejacket. In certain embodiments, electrical conductor 518 is a materialthat is corrosion resistant and provides electrically resistive heatoutput below the Curie temperature of ferromagnetic conductor 452. Forexample, electrical conductor 518 is 825 stainless steel or 347Hstainless steel. In some embodiments, electrical conductor 518 has asmall thickness (for example, on the order of 0.5 mm).

In FIG. 69, core 454 is highly electrically conductive material such ascopper or aluminum. Support member 464 is 347H stainless steel oranother material with good mechanical strength at or near the Curietemperature of ferromagnetic conductor 452.

In FIG. 70, support member 464 is the core of the temperature limitedheater and is 347H stainless steel or another material with goodmechanical strength at or near the Curie temperature of ferromagneticconductor 452. Inner conductor 430 is highly electrically conductivematerial such as copper or aluminum.

In certain embodiments, middle conductor 456 in the temperature limitedheater with triaxial conductors depicted in FIG. 51A and FIG. 51Bincludes an electrical conductor in addition to the ferromagneticmaterial. The electrical conductor may be on the outside of middleconductor 456. The electrical conductor and the ferromagnetic materialare dimensioned so that the skin depth of the ferromagnetic materiallimits the penetration depth of the majority of the flow of electricalcurrent to the electrical conductor when the temperature is below theCurie temperature of the ferromagnetic material. The electricalconductor provides a majority of the electrically resistive heat outputof middle conductor 456 (and the triaxial temperature limited heater) attemperatures up to a temperature at or near the Curie temperature offerromagnetic conductor. The electrical conductor is made from amaterial that provides desired electrically resistive heat output attemperatures up to and/or above the Curie temperature of ferromagneticmember. For example, the electrical conductor is 347H stainless steel,304H, 316H, 347HH, NF709, Incoloy® 800H alloy, Haynes® HR120® alloy, orInconel® 617 alloy.

In certain embodiments, the materials and design of the temperaturelimited heater are chosen to allow use of the heater at hightemperatures (for example, above 850° C.). FIG. 71 depicts a hightemperature embodiment of the temperature limited heater. The heaterdepicted in FIG. 71 operates as a conductor-in-conduit heater with themajority of heat being generated in conduit 468. Theconductor-in-conduit heater may provide a higher heat output because themajority of heat is generated in conduit 468 rather than conductor 466.Having the heat generated in conduit 468 reduces heat losses associatedwith transferring heat between the conduit and conductor 466.

Core 454 and conductive layer 438 are copper. In some embodiments, core454 and conductive layer 438 are nickel if the operating temperatures isto be near or above the melting point of copper. Support members 464 areelectrically conductive materials with good mechanical strength at hightemperatures. Materials for support members 464 that withstand at leasta maximum temperature of about 870° C. may be, but are not limited to,MO-RE® alloys (Duraloy Technologies, Inc. (Scottdale, Pa.)),CF8C+(Metaltek Intl. (Waukesha, Wis.)), or Inconel® 617 alloy. Materialsfor support members 464 that withstand at least a maximum temperature ofabout 980° C. include, but are not limited to, Incoloy® Alloy MA 956.Support member 464 in conduit 468 provides mechanical support for theconduit. Support member 464 in conductor 466 provides mechanical supportfor core 454.

Electrical conductor 518 is a thin corrosion resistant material. Incertain embodiments, electrical conductor 518 is 347H, 617, 625, or 800Hstainless steel. Ferromagnetic conductor 452 is a high Curie temperatureferromagnetic material such as iron-cobalt alloy (for example, a 15% byweight cobalt, iron-cobalt alloy).

In certain embodiments, electrical conductor 518 provides the majorityof heat output of the temperature limited heater at temperatures up to atemperature at or near the Curie temperature of ferromagnetic conductor452. Conductive layer 438 increases the turndown ratio of thetemperature limited heater.

For long vertical temperature limited heaters (for example, heaters atleast 300 m, at least 500 m, or at least 1 km in length), the hangingstress becomes important in the selection of materials for thetemperature limited heater. Without the proper selection of material,the support member may not have sufficient mechanical strength (forexample, creep-rupture strength) to support the weight of thetemperature limited heater at the operating temperatures of the heater.FIG. 72 depicts hanging stress (ksi (kilopounds per square inch)) versusoutside diameter (in.) for the temperature limited heater shown in FIG.68 with 347H as the support member. The hanging stress was assessed withthe support member outside a 0.5″ copper core and a 0.75″ outsidediameter carbon steel ferromagnetic conductor. This assessment assumesthe support member bears the entire load of the heater and that theheater length is 1000 ft. (about 305 m). As shown in FIG. 72, increasingthe thickness of the support member decreases the hanging stress on thesupport member. Decreasing the hanging stress on the support memberallows the temperature limited heater to operate at higher temperatures.

In certain embodiments, materials for the support member are varied toincrease the maximum allowable hanging stress at operating temperaturesof the temperature limited heater and, thus, increase the maximumoperating temperature of the temperature limited heater. Altering thematerials of the support member affects the heat output of thetemperature limited heater below the Curie temperature because changingthe materials changes the resistance versus temperature profile of thesupport member. In certain embodiments, the support member is made ofmore than one material along the length of the heater so that thetemperature limited heater maintains desired operating properties (forexample, resistance versus temperature profile below the Curietemperature) as much as possible while providing sufficient mechanicalproperties to support the heater.

FIG. 73 depicts hanging stress (ksi) versus temperature (° F.) forseveral materials and varying outside diameters for the temperaturelimited heaters. Curve 520 is for 347H stainless steel. Curve 522 is forIncoloy® alloy 800H. Curve 524 is for Haynes® HR120® alloy. Curve 526 isfor NF709. Each of the curves includes four points that representvarious outside diameters of the support member. The point with thehighest stress for each curve corresponds to outside diameter of 1.05″.The point with the second highest stress for each curve corresponds tooutside diameter of 1.15″. The point with the second lowest stress foreach curve corresponds to outside diameter of 1.25″. The point with thelowest stress for each curve corresponds to outside diameter of 1.315″.As shown in FIG. 73, increasing the strength and/or outside diameter ofthe material and the support member increases the maximum operatingtemperature of the temperature limited heater.

FIGS. 74, 75, and 76 depict examples of embodiments for temperaturelimited heaters able to provide desired heat output and mechanicalstrength for operating temperatures up to about 770° C. for 30,000 hrs.creep-rupture lifetime. The depicted temperature limited heaters havelengths of 1000 ft., copper cores of 0.5″ diameter, and ironferromagnetic conductors with outside diameters of 0.765″. In FIG. 74,the support member in heater portion 528 is 347H stainless steel. Thesupport member in heater portion 530 is Incoloy® alloy 800H. Portion 528has a length of 750 ft. and portion 530 has a length of 250 ft. Theoutside diameter of the support member is 1.315″. In FIG. 75, thesupport member in heater portion 528 is 347H stainless steel. Thesupport member in heater portion 530 is Incoloy® alloy 800H. The supportmember in heater portion 532 is Haynes® HR120® alloy. Portion 528 has alength of 650 ft., portion 530 has a length of 300 ft., and portion 532has a length of 50 ft. The outside diameter of the support member is1.15″. In FIG. 76, the support member in heater portion 528 is 347Hstainless steel. The support member in heater portion 530 is Incoloy®alloy 800H. The support member in heater portion 532 is Haynes® HR120®alloy. Portion 528 has a length of 550 ft., portion 530 has a length of250 ft., and portion 532 has a length of 200 ft. The outside diameter ofthe support member is 1.05″.

The materials of the support member along the length of the temperaturelimited heater may be varied to achieve a variety of desired operatingproperties. The choice of the materials of the temperature limitedheater is adjusted depending on a desired use of the temperature limitedheater. TABLE 1 lists examples of materials that may be used for thesupport member. The table provides the hanging stresses (σ) of thesupport members and the maximum operating temperatures of thetemperature limited heaters for several different outside diameters (OD)of the support member. The core diameter and the outside diameter of theiron ferromagnetic conductor in each case are 0.5″ and 0.765″,respectively.

TABLE 1 OD = 1.05″ OD = 1.15″ OD = 1.25″ OD = 1.315″ σ T σ T σ T σ TMaterial (ksi) (° F.) (ksi) (° F.) (ksi) (° F.) (ksi) (° F.) 347Hstainless 7.55 1310 6.33 1340 5.63 1360 5.31 1370 steel Incoloy ® 7.551337 6.33 1378 5.63 1400 5.31 1420 alloy 800H Haynes ® 7.57 1450 6.361492 5.65 1520 5.34 1540 HR120 ® alloy HA230 7.91 1475 6.69 1510 5.991530 5.67 1540 Haynes ® 7.65 1458 6.43 1492 5.72 1512 5.41 1520 alloy556 NF709 7.57 1440 6.36 1480 5.65 1502 5.34 1512

In certain embodiments, one or more portions of the temperature limitedheater have varying outside diameters and/or materials to providedesired properties for the heater. FIGS. 77 and 78 depict examples ofembodiments for temperature limited heaters that vary the diameterand/or materials of the support member along the length of the heatersto provide desired operating properties and sufficient mechanicalproperties (for example, creep-rupture strength properties) foroperating temperatures up to about 834° C. for 30,000 hrs., heaterlengths of 850 ft., a copper core diameter of 0.5″, and an iron-cobalt(6% by weight cobalt) ferromagnetic conductor outside diameter of 0.75″.In FIG. 77, portion 528 is 347H stainless steel with a length of 300 ft.and an outside diameter of 1.15″. Portion 530 is NF709 with a length of400 ft. and an outside diameter of 1.15″. Portion 532 is NF709 with alength of 150 ft. and an outside diameter of 1.25″. In FIG. 78, portion528 is 347H stainless steel with a length of 300 ft. and an outsidediameter of 1.15″. Portion 530 is 347H stainless steel with a length of100 ft. and an outside diameter of 1.20″. Portion 532 is NF709 with alength of 350 ft. and an outside diameter of 1.20″. Portion 534 is NF709with a length of 100 ft. and an outside diameter of 1.25″.

In some embodiments, a relatively thin conductive layer is used toprovide the majority of the electrically resistive heat output of thetemperature limited heater at temperatures up to a temperature at ornear the Curie temperature of the ferromagnetic conductor. Such atemperature limited heater may be used as the heating member in aninsulated conductor heater. The heating member of the insulatedconductor heater may be located inside a sheath with an insulation layerbetween the sheath and the heating member.

FIGS. 79A and 79B depict cross-sectional representations of anembodiment of the insulated conductor heater with the temperaturelimited heater as the heating member. Insulated conductor 514 includescore 454, ferromagnetic conductor 452, inner conductor 430, electricalinsulator 432, and jacket 440. Core 454 is a copper core. Ferromagneticconductor 452 is, for example, iron or an iron alloy.

Inner conductor 430 is a relatively thin conductive layer ofnon-ferromagnetic material with a higher electrical conductivity thanferromagnetic conductor 452. In certain embodiments, inner conductor 430is copper. Inner conductor 430 may also be a copper alloy. Copper alloystypically have a flatter resistance versus temperature profile than purecopper. A flatter resistance versus temperature profile may provide lessvariation in the heat output as a function of temperature up to theCurie temperature. In some embodiments, inner conductor 430 is copperwith 6% by weight nickel (for example, CuNi6 or LOHM™). In someembodiments, inner conductor 430 is CuNi10Fe1Mn alloy. Below the Curietemperature of ferromagnetic conductor 452, the magnetic properties ofthe ferromagnetic conductor confine the majority of the flow ofelectrical current to inner conductor 430. Thus, inner conductor 430provides the majority of the resistive heat output of insulatedconductor 514 below the Curie temperature.

In certain embodiments, inner conductor 430 is dimensioned, along withcore 454 and ferromagnetic conductor 452, so that the inner conductorprovides a desired amount of heat output and a desired turndown ratio.For example, inner conductor 430 may have a cross-sectional area that isaround 2 or 3 times less than the cross-sectional area of core 454.Typically, inner conductor 430 has to have a relatively smallcross-sectional area to provide a desired heat output if the innerconductor is copper or copper alloy. In an embodiment with copper innerconductor 430, core 454 has a diameter of 0.66 cm, ferromagneticconductor 452 has an outside diameter of 0.91 cm, inner conductor 430has an outside diameter of 1.03 cm, electrical insulator 442 has anoutside diameter of 1.53 cm, and jacket 440 has an outside diameter of1.79 cm. In an embodiment with a CuNi6 inner conductor 430, core 454 hasa diameter of 0.66 cm, ferromagnetic conductor 452 has an outsidediameter of 0.91 cm, inner conductor 430 has an outside diameter of 1.12cm, electrical insulator 432 has an outside diameter of 1.63 cm, andjacket 440 has an outside diameter of 1.88 cm. Such insulated conductorsare typically smaller and cheaper to manufacture than insulatedconductors that do not use the thin inner conductor to provide themajority of heat output below the Curie temperature.

Electrical insulator 432 may be magnesium oxide, aluminum oxide, silicondioxide, beryllium oxide, boron nitride, silicon nitride, orcombinations thereof. In certain embodiments, electrical insulator 432is a compacted powder of magnesium oxide. In some embodiments,electrical insulator 432 includes beads of silicon nitride.

In certain embodiments, a small layer of material is placed betweenelectrical insulator 432 and inner conductor 430 to inhibit copper frommigrating into the electrical insulator at higher temperatures. Forexample, the small layer of nickel (for example, about 0.5 mm of nickel)may be placed between electrical insulator 432 and inner conductor 430.

Jacket 440 is made of a corrosion resistant material such as, but notlimited to, 347 stainless steel, 347H stainless steel, 446 stainlesssteel, or 825 stainless steel. In some embodiments, jacket 440 providessome mechanical strength for insulated conductor 514 at or above theCurie temperature of ferromagnetic conductor 452. In certainembodiments, jacket 440 is not used to conduct electrical current.

In certain embodiments of temperature limited heaters, three temperaturelimited heaters are coupled together in a three-phase wye configuration.Coupling three temperature limited heaters together in the three-phasewye configuration lowers the current in each of the individualtemperature limited heaters because the current is split between thethree individual heaters. Lowering the current in each individualtemperature limited heater allows each heater to have a small diameter.The lower currents allow for higher relative magnetic permeabilities ineach of the individual temperature limited heaters and, thus, higherturndown ratios. In addition, there may be no return current needed foreach of the individual temperature limited heaters. Thus, the turndownratio remains higher for each of the individual temperature limitedheaters than if each temperature limited heater had its own returncurrent path.

In the three-phase wye configuration, individual temperature limitedheaters may be coupled together by shorting the sheaths, jackets, orcanisters of each of the individual temperature limited heaters to theelectrically conductive sections (the conductors providing heat) attheir terminating ends (for example, the ends of the heaters at thebottom of a heater wellbore). In some embodiments, the sheaths, jackets,canisters, and/or electrically conductive sections are coupled to asupport member that supports the temperature limited heaters in thewellbore.

FIG. 80A depicts an embodiment for installing and coupling heaters in awellbore. The embodiment in FIG. 80A depicts insulated conductor heatersbeing installed into the wellbore. Other types of heaters, such asconductor-in-conduit heaters, may also be installed in the wellboreusing the embodiment depicted. Also, in FIG. 80A, two insulatedconductors 514 are shown while a third insulated conductor is not seenfrom the view depicted. Typically, three insulated conductors 514 wouldbe coupled to support member 536, as shown in FIG. 80B. In anembodiment, support member 536 is a thick walled 347H pipe. In someembodiments, thermocouples or other temperature sensors are placedinside support member 536. The three insulated conductors may be coupledin a three-phase wye configuration.

In FIG. 80A, insulated conductors 514 are coiled on coiled tubing rigs538. As insulated conductors 514 are uncoiled from rigs 538, theinsulated conductors are coupled to support member 536. In certainembodiments, insulated conductors 514 are simultaneously uncoiled and/orsimultaneously coupled to support member 536. Insulated conductors 514may be coupled to support member 536 using metal (for example, 304stainless steel or Inconel® alloys) straps 540. In some embodiments,insulated conductors 514 are coupled to support member 536 using othertypes of fasteners such as buckles, wire holders, or snaps. Supportmember 536 along with insulated conductors 514 are installed intoopening 252.

Insulated conductors 514 may be electrically coupled to each other (forexample, for a three-phase wye configuration) in contactor section 542.In section 542, sheaths, jackets, canisters, and/or electricallyconductive sections are coupled to each other and/or to support member536 so that insulated conductors 514 are electrically coupled together.In certain embodiments, the sheaths of insulated conductors 514 areshorted to the conductors of the insulated conductors. The sheaths ofindividual insulated conductors 514 may then be shorted together toelectrically couple the insulated conductors.

In certain embodiments, three conductors are located inside a singleconduit to form a three conductor-in-conduit heater. FIGS. 81A and 81Bdepict an embodiment of a three conductor-in-conduit heater. FIG. 81Adepicts a top down view of the three conductor-in-conduit heater. FIG.81B depicts a side view representation with a cutout to show theinternals of the three conductor-in-conduit heater. Three conductors 466are located inside conduit 468. The three conductors 466 aresubstantially evenly spaced within conduit 468. In some embodiments, thethree conductors 466 are coupled in a spiral configuration.

One or more centralizers 472 are placed around each conductor 466.Centralizers 472 are made from electrically insulating material such assilicon nitride or boron nitride. Centralizers 472 maintain a positionof conductors 466 in conduit 468. Centralizers 472 also inhibitelectrical contact between conductors 466 and conduit 468. In certainembodiments, centralizers 472 are spaced along the length of conductors466 so that the centralizers surrounding one conductor overlap (as seenfrom the top down view) centralizers from another conductor. Thisreduces the number of centralizers needed for each conductor and allowsfor tight spacing of the conductors.

In certain embodiments, the three conductors 466 are coupled in athree-phase wye configuration. The three conductors 466 may be coupledat or near the bottom of the heaters in the three-phase wyeconfiguration. In the three-phase wye configuration, conduit 468 is notelectrically coupled to the three conductors 466. Thus, conduit 468 mayonly be used to provide strength for and/or inhibit corrosion of thethree conductors 466.

In some embodiments, the temperature limited heater is used to achievelower temperature heating (for example, for heating fluids in aproduction well, heating a surface pipeline, or reducing the viscosityof fluids in a wellbore or near wellbore region). Varying theferromagnetic materials of the temperature limited heater allows forlower temperature heating. In some embodiments, the ferromagneticconductor is made of material with a lower Curie temperature than thatof 446 stainless steel. For example, the ferromagnetic conductor may bean alloy of iron and nickel. The alloy may have between 30% by weightand 42% by weight nickel with the rest being iron. In one embodiment,the alloy is Invar 36. Invar 36 is 36% by weight nickel in iron and hasa Curie temperature of 277° C. In some embodiments, an alloy is a threecomponent alloy with, for example, chromium, nickel, and iron. Forexample, an alloy may have 6% by weight chromium, 42% by weight nickel,and 52% by weight iron. A 2.5 cm diameter rod of Invar 36 has a turndownratio of approximately 2 to 1 at the Curie temperature. Placing theInvar 36 alloy over a copper core may allow for a smaller rod diameter.A copper core may result in a high turndown ratio. The insulator inlower temperature heater embodiments may be made of a high performancepolymer insulator (such as PFA or PEEK™) when used with alloys with aCurie temperature that is below the melting point or softening point ofthe polymer insulator.

In certain embodiments, a conductor-in-conduit temperature limitedheater is used in lower temperature applications by using lower Curietemperature ferromagnetic materials. For example, a lower Curietemperature ferromagnetic material may be used for heating inside suckerpump rods. Heating sucker pump rods may be useful to lower the viscosityof fluids in the sucker pump or rod and/or to maintain a lower viscosityof fluids in the sucker pump rod. Lowering the viscosity of the oil mayinhibit sticking of a pump used to pump the fluids. Fluids in the suckerpump rod may be heated up to temperatures less than about 250° C. orless than about 300° C. Temperatures need to be maintained below thesevalues to inhibit coking of hydrocarbon fluids in the sucker pumpsystem.

For lower temperature applications, ferromagnetic conductor 452 in FIG.64 may be Alloy 42-6 coupled to conductor 466. Conductor 466 may becopper. In one embodiment, ferromagnetic conductor 452 is 1.9 cm outsidediameter Alloy 42-6 over copper conductor 466 with a 2:1 outsidediameter to copper diameter ratio. In some embodiments, ferromagneticconductor 452 includes other lower temperature ferromagnetic materialssuch as Alloy 32, Alloy 52, Invar 36, iron-nickel-chromium alloys,iron-nickel alloys, nickel-chromium alloys, or other nickel alloys.Conduit 468 may be a hollow sucker rod made from carbon steel. Thecarbon steel or other material used in conduit 468 confines current tothe inside of the conduit to inhibit stray voltages at the surface ofthe formation. Centralizer 544 may be made from gas pressure sinteredreaction bonded silicon nitride. In some embodiments, centralizer 544 ismade from polymers such as PFA or PEEK™. In certain embodiments, polymerinsulation is clad along an entire length of the heater. Conductor 466and ferromagnetic conductor 452 are electrically coupled to conduit 468with sliding connector 478.

FIG. 82 depicts an embodiment of a temperature limited heater with a lowtemperature ferromagnetic outer conductor. Outer conductor 434 is glasssealing Alloy 42-6. Alloy 42-6 may be obtained from Carpenter Metals(Reading, Pa.) or Anomet Products, Inc. (Shrewsbury, Mass.). In someembodiments, outer conductor 434 includes other compositions and/ormaterials to get various Curie temperatures (for example, CarpenterTemperature Compensator “32” (Curie temperature of 199° C.; availablefrom Carpenter Metals) or Invar 36). In an embodiment, conductive layer438 is coupled (for example, clad, welded, or brazed) to outer conductor434. Conductive layer 438 is a copper layer. Conductive layer 438improves a turndown ratio of outer conductor 434. Jacket 440 is aferromagnetic metal such as carbon steel. Jacket 440 protects outerconductor 434 from a corrosive environment. Inner conductor 430 may haveelectrical insulator 432. Electrical insulator 432 may be a mica tapewinding with overlaid fiberglass braid. In an embodiment, innerconductor 430 and electrical insulator 432 are a 4/0 MGT-1000 furnacecable or 3/0 MGT-1000 furnace cable. 4/0 MGT-1000 furnace cable or 3/0MGT-1000 furnace cable is available from Allied Wire and Cable(Phoenixville, Pa.). In some embodiments, a protective braid such as astainless steel braid may be placed over electrical insulator 432.

Conductive section 436 electrically couples inner conductor 430 to outerconductor 434 and/or jacket 440. In some embodiments, jacket 440 touchesor electrically contacts conductive layer 438 (for example, if theheater is placed in a horizontal configuration). If jacket 440 is aferromagnetic metal such as carbon steel (with a Curie temperature abovethe Curie temperature of outer conductor 434), current will propagateonly on the inside of the jacket. Thus, the outside of the jacketremains electrically safe during operation. In some embodiments, jacket440 is drawn down (for example, swaged down in a die) onto conductivelayer 438 so that a tight fit is made between the jacket and theconductive layer. The heater may be spooled as coiled tubing forinsertion into a wellbore. In other embodiments, an annular space ispresent between conductive layer 438 and jacket 440, as depicted in FIG.82.

FIG. 83 depicts an embodiment of a temperature limitedconductor-in-conduit heater. Conduit 468 is a hollow sucker rod made ofa ferromagnetic metal such as Alloy 42-6, Alloy 32, Alloy 52, Invar 36,iron-nickel-chromium alloys, iron-nickel alloys, nickel alloys, ornickel-chromium alloys. Inner conductor 430 has electrical insulator432. Electrical insulator 432 is a mica tape winding with overlaidfiberglass braid. In an embodiment, inner conductor 430 and electricalinsulator 432 are a 4/0 MGT-1000 furnace cable or 3/0 MGT-1000 furnacecable. In some embodiments, polymer insulations are used for lowertemperature Curie heaters. In certain embodiments, a protective braid isplaced over electrical insulator 432. Conduit 468 has a wall thicknessthat is greater than the skin depth at the Curie temperature (forexample, 2 to 3 times the skin depth at the Curie temperature). In someembodiments, a more conductive conductor is coupled to conduit 468 toincrease the turndown ratio of the heater.

FIG. 84 depicts a cross-sectional representation of an embodiment of aconductor-in-conduit temperature limited heater. Conductor 466 iscoupled (for example, clad, coextruded, press fit, drawn inside) toferromagnetic conductor 452. A metallurgical bond between conductor 466and ferromagnetic conductor 452 is favorable. Ferromagnetic conductor452 is coupled to the outside of conductor 466 so that currentpropagates through the skin depth of the ferromagnetic conductor at roomtemperature. Conductor 466 provides mechanical support for ferromagneticconductor 452 at elevated temperatures. Ferromagnetic conductor 452 isiron, an iron alloy (for example, iron with 10% to 27% by weightchromium for corrosion resistance), or any other ferromagnetic material.In one embodiment, conductor 466 is 304 stainless steel andferromagnetic conductor 452 is 446 stainless steel. Conductor 466 andferromagnetic conductor 452 are electrically coupled to conduit 468 withsliding connector 478. Conduit 468 may be a non-ferromagnetic materialsuch as austenitic stainless steel.

FIG. 85 depicts a cross-sectional representation of an embodiment of aconductor-in-conduit temperature limited heater. Conduit 468 is coupledto ferromagnetic conductor 452 (for example, clad, press fit, or drawninside of the ferromagnetic conductor). Ferromagnetic conductor 452 iscoupled to the inside of conduit 468 to allow current to propagatethrough the skin depth of the ferromagnetic conductor at roomtemperature. Conduit 468 provides mechanical support for ferromagneticconductor 452 at elevated temperatures. Conduit 468 and ferromagneticconductor 452 are electrically coupled to conductor 466 with slidingconnector 478.

FIG. 86 depicts a cross-sectional view of an embodiment of aconductor-in-conduit temperature limited heater. Conductor 466 maysurround core 454. In an embodiment, conductor 466 is 347H stainlesssteel and core 454 is copper. Conductor 466 and core 454 may be formedtogether as a composite conductor. Conduit 468 may include ferromagneticconductor 452. In an embodiment, ferromagnetic conductor 452 is SumitomoHCM12A or 446 stainless steel. Ferromagnetic conductor 452 may have aSchedule XXH thickness so that the conductor is inhibited fromdeforming. In certain embodiments, conduit 468 also includes jacket 440.Jacket 440 may include corrosion resistant material that inhibitselectrons from flowing away from the heater and into a subsurfaceformation at higher temperatures (for example, temperatures near theCurie temperature of ferromagnetic conductor 452). For example, jacket440 may be about a 0.4 cm thick sheath of 410 stainless steel Inhibitingelectrons from flowing to the formation may increase the safety of usinga heater in a subsurface formation.

FIG. 87 depicts a cross-sectional representation of an embodiment of aconductor-in-conduit temperature limited heater with an insulatedconductor. Insulated conductor 514 may include core 454, electricalinsulator 432, and jacket 440. Jacket 440 may be made of a corrosionresistant material (for example, stainless steel). Endcap 446 may beplaced at an end of insulated conductor 514 to couple core 454 tosliding connector 478. Endcap 446 may be made of non-corrosive,electrically conducting materials such as nickel or stainless steel.Endcap 446 may be coupled to the end of insulated conductor 514 by anysuitable method (for example, welding, soldering, braising). Slidingconnector 478 may electrically couple core 454 and endcap 446 toferromagnetic conductor 452. Conduit 468 may provide support forferromagnetic conductor 452 at elevated temperatures.

FIG. 88 depicts a cross-sectional representation of an embodiment of aninsulated conductor-in-conduit temperature limited heater. Insulatedconductor 514 may include core 454, electrical insulator 432, and jacket440. Insulated conductor 514 may be coupled to ferromagnetic conductor452 with connector 546. Connector 546 may be made of non-corrosive,electrically conducting materials such as nickel or stainless steel.Connector 546 may be coupled to insulated conductor 514 and coupled toferromagnetic conductor 452 using suitable methods for electricallycoupling (for example, welding, soldering, braising). Insulatedconductor 514 may be placed along a wall of ferromagnetic conductor 452.Insulated conductor 514 may provide mechanical support for ferromagneticconductor 452 at elevated temperatures. In some embodiments, otherstructures (for example, a conduit) are used to provide mechanicalsupport for ferromagnetic conductor 452.

FIG. 89 depicts a cross-sectional representation of an embodiment of aninsulated conductor-in-conduit temperature limited heater. Insulatedconductor 514 may be coupled to endcap 446. Endcap 446 may be coupled tocoupling 548. Coupling 548 may electrically couple insulated conductor514 to ferromagnetic conductor 452. Coupling 548 may be a flexiblecoupling. For example, coupling 548 may include flexible materials (forexample, braided wire). Coupling 548 may be made of non-corrosivematerials such as nickel, stainless steel, and/or copper.

FIG. 90 depicts a cross-sectional representation of an embodiment of aconductor-in-conduit temperature limited heater with an insulatedconductor. Insulated conductor 514 includes core 454, electricalinsulator 432, and jacket 440. Jacket 440 is made of a highlyelectrically conductive material such as copper. Core 454 is made of alower temperature ferromagnetic material such as such as Alloy 42-6,Alloy 32, Invar 36, iron-nickel-chromium alloys, iron-nickel alloys,nickel alloys, or nickel-chromium alloys. In certain embodiments, thematerials of jacket 440 and core 454 are reversed so that the jacket isthe ferromagnetic conductor and the core is the highly conductiveportion of the heater. Ferromagnetic material used in jacket 440 or core454 may have a thickness greater than the skin depth at the Curietemperature (for example, 2 to 3 times the skin depth at the Curietemperature). Endcap 446 is placed at an end of insulated conductor 514to couple core 454 to sliding connector 478. Endcap 446 is made ofnon-corrosive, electrically conducting materials such as nickel orstainless steel. In certain embodiments, conduit 468 is a hollow suckerrod made from, for example, carbon steel.

FIGS. 91 and 92 depict cross-sectional views of an embodiment of atemperature limited heater that includes an insulated conductor. FIG. 91depicts a cross-sectional view of an embodiment of an overburden sectionof the temperature limited heater. The overburden section may includeinsulated conductor 514 placed in conduit 468. Conduit 468 may be 1¼″Schedule 80 carbon steel pipe internally clad with copper in theoverburden section. Insulated conductor 514 may be a mineral insulatedcable or polymer insulated cable. Conductive layer 438 may be placed inthe annulus between insulated conductor 514 and conduit 468. Conductivelayer 438 may be approximately 2.5 cm diameter copper tubing. Theoverburden section may be coupled to the heating section of the heater.FIG. 92 depicts a cross-sectional view of an embodiment of a heatingsection of the temperature limited heater. Insulated conductor 514 inthe heating section may be a continuous portion of insulated conductor514 in the overburden section. Ferromagnetic conductor 452 may becoupled to conductive layer 438. In certain embodiments, conductivelayer 438 in the heating section is copper drawn over ferromagneticconductor 452 and coupled to conductive layer 438 in the overburdensection. Conduit 468 may include a heating section and an overburdensection. These two sections may be coupled together to form conduit 468.The heating section may be 1¼″Schedule 80 347H stainless steel pipe. Anend cap, or other suitable electrical connector, may coupleferromagnetic conductor 452 to insulated conductor 514 at a lower end ofthe heater. The lower end of the heater is understood to be the endfarthest from the point the heater enters the hydrocarbon layer from theoverburden section.

FIGS. 93 and 94 depict cross-sectional views of an embodiment of atemperature limited heater that includes an insulated conductor. FIG. 93depicts a cross-sectional view of an embodiment of an overburden sectionof the temperature limited heater. Insulated conductor 514 may includecore 454, electrical insulator 432, and jacket 440. Insulated conductor514 may have a diameter of about 1.5 cm. Core 454 may be copper.Electrical insulator 432 may be silicon nitride, boron nitride, ormagnesium oxide. Jacket 440 may be copper in the overburden section toreduce heat losses. Conduit 468 may be 1″ Schedule 40 carbon steel inthe overburden section. Conductive layer 438 may be coupled to conduit468. Conductive layer 438 may be copper with a thickness of about 0.2 cmto reduce heat losses in the overburden section. Gap 516 may be anannular space between insulated conductor 514 and conduit 468. FIG. 94depicts a cross-sectional view of an embodiment of a heating section ofthe temperature limited heater. Insulated conductor 514 in the heatingsection may be coupled to insulated conductor 514 in the overburdensection. Jacket 440 in the heating section may be made of a corrosionresistant material (for example, 825 stainless steel). Ferromagneticconductor 452 may be coupled to conduit 468 in the overburden section.Ferromagnetic conductor 452 may be Schedule 160 409, 410, or 446stainless steel pipe. Gap 516 may be between ferromagnetic conductor 452and insulated conductor 514. An end cap, or other suitable electricalconnector, may couple ferromagnetic conductor 452 to insulated conductor514 at a distal end of the heater. The distal end of the heater isunderstood to be the end farthest from the overburden section.

In certain embodiments, a temperature limited heater includes a flexiblecable (for example, a furnace cable) as the inner conductor. Forexample, the inner conductor may be a 27% nickel-clad or stainlesssteel-clad stranded copper wire with four layers of mica tape surroundedby a layer of ceramic and/or mineral fiber (for example, alumina fiber,aluminosilicate fiber, borosilicate fiber, or aluminoborosilicatefiber). A stainless steel-clad stranded copper wire furnace cable may beavailable from Anomet Products, Inc. (Shrewsbury, Mass.). The innerconductor may be rated for applications at temperatures of 1000° C. orhigher. The inner conductor may be pulled inside a conduit. The conduitmay be a ferromagnetic conduit (for example, a ¾″ Schedule 80 446stainless steel pipe). The conduit may be covered with a layer ofcopper, or other electrical conductor, with a thickness of about 0.3 cmor any other suitable thickness. The assembly may be placed inside asupport conduit (for example, a 1¼″ Schedule 80 347H or 347HH stainlesssteel tubular). The support conduit may provide additional creep-rupturestrength and protection for the copper and the inner conductor. For usesat temperatures greater than about 1000° C., the inner copper conductormay be plated with a more corrosion resistant alloy (for example,Incoloy® 825) to inhibit oxidation. In some embodiments, the top of thetemperature limited heater is sealed to inhibit air from contacting theinner conductor.

In some embodiments, a ferromagnetic conductor of a temperature limitedheater includes a copper core (for example, a 1.27 cm diameter coppercore) placed inside a first steel conduit (for example, a ½″ Schedule 80347H or 347HH stainless steel pipe). A second steel conduit (forexample, a 1″ Schedule 80 446 stainless steel pipe) may be drawn downover the first steel conduit assembly. The first steel conduit mayprovide strength and creep resistance while the copper core may providea high turndown ratio.

In some embodiments, a ferromagnetic conductor of a temperature limitedheater (for example, a center or inner conductor of aconductor-in-conduit temperature limited heater) includes a heavy walledconduit (for example, an extra heavy wall 410 stainless steel pipe). Theheavy walled conduit may have a diameter of about 2.5 cm. The heavywalled conduit may be drawn down over a copper rod. The copper rod mayhave a diameter of about 1.3 cm. The resulting heater may include athick ferromagnetic sheath containing the copper rod. The thickferromagnetic sheath may be the heavy walled conduit with, for example,about a 2.6 cm outside diameter after drawing. The heater may have aturndown ratio of about 8:1. The thickness of the heavy walled conduitmay be selected to inhibit deformation of the heater. A thickferromagnetic conduit may provide deformation resistance while addingminimal expense to the cost of the heater.

In another embodiment, a temperature limited heater includes asubstantially U-shaped heater with a ferromagnetic cladding over anon-ferromagnetic core (in this context, the “U” may have a curved or,alternatively, orthogonal shape). A U-shaped, or hairpin, heater mayhave insulating support mechanisms (for example, polymer or ceramicspacers) that inhibit the two legs of the hairpin from electricallyshorting to each other. In some embodiments, a hairpin heater isinstalled in a casing (for example, an environmental protection casing).The insulators may inhibit electrical shorting to the casing and mayfacilitate installation of the heater in the casing. The cross sectionof the hairpin heater may be, but is not limited to, circular,elliptical, square, or rectangular.

FIG. 95 depicts an embodiment of a temperature limited heater with ahairpin inner conductor. Inner conductor 430 may be placed in a hairpinconfiguration with two legs coupled by a substantially U-shaped sectionat or near the bottom of the heater. Current may enter inner conductor430 through one leg and exit through the other leg. Inner conductor 430may be, but is not limited to, ferritic stainless steel, carbon steel,or iron. Core 454 may be placed inside inner conductor 430. In certainembodiments, inner conductor 430 may be clad to core 454. Core 454 maybe a copper rod. The legs of the heater may be insulated from each otherand from casing 550 by spacers 552. Spacers 552 may be alumina spacers(for example, about 90% to about 99.8% alumina) or silicon nitridespacers. Weld beads or other protrusions may be placed on innerconductor 430 to maintain a location of spacers 552 on the innerconductor. In some embodiments, spacers 552 include two sections thatare fastened together around inner conductor 430. Casing 550 may be anenvironmentally protective casing made of, for example, stainless steel.

In certain embodiments, a temperature limited heater incorporatescurves, helixes, bends, or waves in a relatively straight heater toallow thermal expansion and contraction of the heater withoutoverstressing materials in the heater. When a cool heater is heated or ahot heater is cooled, the heater expands or contracts in proportion tothe change in temperature and the coefficient of thermal expansion ofmaterials in the heater. For long straight heaters that undergo widevariations in temperature during use and are fixed at more than onepoint in the wellbore (for example, due to mechanical deformation of thewellbore), the expansion or contraction may cause the heater to bend,kink, and/or pull apart. Use of an “S” bend or other curves, helixes,bends, or waves in the heater at intervals in the heated length mayprovide a spring effect and allow the heater to expand or contract moregently so that the heater does not bend, kink, or pull apart.

A 310 stainless steel heater subjected to about 500° C. temperaturechange may shrink/grow approximately 0.85% of the length of the heaterwith this temperature change. Thus, a length of about 3 m of a heaterwould contract about 2.6 cm when it cools through 500° C. If a longheater were affixed at about 3 m intervals, such a change in lengthcould stretch and, possibly, break the heater. FIG. 96 depicts anembodiment of an “S” bend in a heater. The additional material in the“S” bend may allow for thermal contraction or expansion of heater 382without damage to the heater.

In some embodiments, a temperature limited heater includes a sandwichconstruction with both current supply and current return paths separatedby an insulator. The sandwich heater may include two outer layers ofconductor, two inner layers of ferromagnetic material, and a layer ofinsulator between the ferromagnetic layers. The cross-sectionaldimensions of the heater may be optimized for mechanical flexibility andspoolability. The sandwich heater may be formed as a bimetallic stripthat is bent back upon itself. The sandwich heater may be inserted in acasing, such as an environmental protection casing. The sandwich heatermay be separated from the casing with an electrical insulator.

A heater may include a section that passes through an overburden. Insome embodiments, the portion of the heater in the overburden does notneed to supply as much heat as a portion of the heater adjacent tohydrocarbon layers that are to be subjected to in situ conversion. Incertain embodiments, a substantially non-heating section of a heater haslimited or no heat output. A substantially non-heating section of aheater may be located adjacent to layers of the formation (for example,rock layers, non-hydrocarbon layers, or lean layers) that remainadvantageously unheated. A substantially non-heating section of a heatermay include a copper or aluminum conductor instead of a ferromagneticconductor. In some embodiments, a substantially non-heating section of aheater includes a copper or copper alloy inner conductor. Asubstantially non-heating section may also include a copper outerconductor clad with a corrosion resistant alloy. In some embodiments, anoverburden section includes a relatively thick ferromagnetic portion toinhibit crushing.

In certain embodiments, a temperature limited heater provides some heatto the overburden portion of a heater well and/or production well. Heatsupplied to the overburden portion may inhibit formation fluids (forexample, water and hydrocarbons) from refluxing or condensing in thewellbore. Refluxing fluids may use a large portion of heat energysupplied to a target section of the wellbore, thus limiting heattransfer from the wellbore to the target section.

A temperature limited heater may be constructed in sections that arecoupled (welded) together. The sections may be 10 m long or longer.Construction materials for each section are chosen to provide a selectedheat output for different parts of the formation. For example, an oilshale formation may contain layers with highly variable richnesses.Providing selected amounts of heat to individual layers, or multiplelayers with similar richnesses, improves heating efficiency of theformation and/or inhibits collapse of the wellbore. A splice section maybe formed between the sections, for example, by welding the innerconductors, filling the splice section with an insulator, and thenwelding the outer conductor. Alternatively, the heater is formed fromlarger diameter tubulars and drawn down to a desired length anddiameter. A boron nitride, silicon nitride, magnesium oxide, or othertype of insulation layer may be added by a weld-fill-draw method(starting from metal strip) or a fill-draw method (starting fromtubulars) well known in the industry in the manufacture of mineralinsulated heater cables. The assembly and filling can be done in avertical or a horizontal orientation. The final heater assembly may bespooled onto a large diameter spool (for example, 1 m, 2 m, 3 m, or morein diameter) and transported to a site of a formation for subsurfacedeployment. Alternatively, the heater may be assembled on site insections as the heater is lowered vertically into a wellbore.

The temperature limited heater may be a single-phase heater or athree-phase heater. In a three-phase heater embodiment, the temperaturelimited heater has a delta or a wye configuration. Each of the threeferromagnetic conductors in the three-phase heater may be inside aseparate sheath. A connection between conductors may be made at thebottom of the heater inside a splice section. The three conductors mayremain insulated from the sheath inside the splice section.

FIG. 97 depicts an embodiment of a three-phase temperature limitedheater with ferromagnetic inner conductors. Each leg 554 has innerconductor 430, core 454, and jacket 440. Inner conductors 430 areferritic stainless steel or 1% carbon steel. Inner conductors 430 havecore 454. Core 454 may be copper. Each inner conductor 430 is coupled toits own jacket 440. Jacket 440 is a sheath made of a corrosion resistantmaterial (such as 304H stainless steel). Electrical insulator 432 isplaced between inner conductor 430 and jacket 440. Inner conductor 430is ferritic stainless steel or carbon steel with an outside diameter of1.14 cm and a thickness of 0.445 cm. Core 454 is a copper core with a0.25 cm diameter. Each leg 554 of the heater is coupled to terminalblock 556. Terminal block 556 is filled with insulation material 558 andhas an outer surface of stainless steel. Insulation material 558 is, insome embodiments, silicon nitride, boron nitride, magnesium oxide orother suitable electrically insulating material. Inner conductors 430 oflegs 554 are coupled (welded) in terminal block 556. Jackets 440 of legs554 are coupled (welded) to an outer surface of terminal block 556.Terminal block 556 may include two halves coupled together around thecoupled portions of legs 554.

In an embodiment, the heated section of a three-phase heater is about245 m long. The three-phase heater may be wye connected and operated ata current of about 150 A. The resistance of one leg of the heater mayincrease from about 1.1 ohms at room temperature to about 3.1 ohms atabout 650° C. The resistance of one leg may decrease rapidly above about720° C. to about 1.5 ohms. The voltage may increase from about 165 V atroom temperature to about 465 V at 650° C. The voltage may decreaserapidly above about 720° C. to about 225 V. The heat output per leg mayincrease from about 102 watts/meter at room temperature to about 285watts/meter at 650° C. The heat output per leg may decrease rapidlyabove about 720° C. to about 1.4 watts/meter. Other embodiments of innerconductor 430, core 454, jacket 440, and/or electrical insulator 432 maybe used in the three-phase temperature limited heater shown in FIG. 97.Any embodiment of a single-phase temperature limited heater may be usedas a leg of a three-phase temperature limited heater.

In some three-phase heater embodiments, three ferromagnetic conductorsare separated by insulation inside a common outer metal sheath. Thethree conductors may be insulated from the sheath or the threeconductors may be connected to the sheath at the bottom of the heaterassembly. In another embodiment, a single outer sheath or three outersheaths are ferromagnetic conductors and the inner conductors may benon-ferromagnetic (for example, aluminum, copper, or a highly conductivealloy). Alternatively, each of the three non-ferromagnetic conductorsare inside a separate ferromagnetic sheath, and a connection between theconductors is made at the bottom of the heater inside a splice section.The three conductors may remain insulated from the sheath inside thesplice section.

FIG. 98 depicts an embodiment of a three-phase temperature limitedheater with ferromagnetic inner conductors in a common jacket. Innerconductors 430 surround cores 454. Inner conductors 430 are placed inelectrical insulator 432. Inner conductors 430 and electrical insulator432 are placed in a single jacket 440. Jacket 440 is a sheath made ofcorrosion resistant material such as stainless steel. Jacket 440 has anoutside diameter of between 2.5 cm and 5 cm (for example, 3.1 cm, 3.5cm, or 3.8 cm). Inner conductors 430 are coupled at or near the bottomof the heater at termination 560. Termination 560 is a weldedtermination of inner conductors 430. Inner conductors 430 may be coupledin a wye configuration.

In some embodiments, the three-phase heater includes three legs that arelocated in separate wellbores. The legs may be coupled in a commoncontacting section (for example, a central wellbore, a connectingwellbore, or a solution filled contacting section). FIG. 99 depicts anembodiment of temperature limited heaters coupled together in athree-phase configuration. Each leg 562, 564, 566 may be located inseparate openings 252 in hydrocarbon layer 254. Each leg 562, 564, 566may include heating element 568. Each leg 562, 564, 566 may be coupledto single contacting element 570 in one opening 252. Contacting element570 may electrically couple legs 562, 564, 566 together in a three-phaseconfiguration. Contacting element 570 may be located in, for example, acentral opening in the formation. Contacting element 570 may be locatedin a portion of opening 252 below hydrocarbon layer 254 (for example, anunderburden). In certain embodiments, magnetic tracking of a magneticelement located in a central opening (for example, opening 252 with leg564) is used to guide the formation of the outer openings (for example,openings 252 with legs 562 and 566) so that the outer openings intersectthe central opening. The central opening may be formed first usingstandard wellbore drilling methods. Contacting element 570 may includefunnels, guides, or catchers for allowing each leg to be inserted intothe contacting element.

In certain embodiments, two legs in separate wellbores intercept in asingle contacting section. FIG. 100 depicts an embodiment of twotemperature limited heaters coupled together in a single contactingsection. Legs 562 and 564 include one or more heating elements 568.Heating elements 568 may include one or more electrical conductors. Incertain embodiments, legs 562 and 564 are electrically coupled in asingle-phase configuration with one leg positively biased versus theother leg so that current flows downhole through one leg and returnsthrough the other leg.

Heating elements 568 in legs 562 and 564 may be temperature limitedheaters. In certain embodiments, heating elements 568 are solid rodheaters. For example, heating elements 568 may be rods made of a singleferromagnetic conductor element or composite conductors that includeferromagnetic material. During initial heating when water is present inthe formation being heated, heating elements 568 may leak current intohydrocarbon layer 254. The current leaked into hydrocarbon layer 254 mayresistively heat the hydrocarbon layer.

In some embodiments (for example, in oil shale formations), heatingelements 568 do not need support members. Heating elements 568 may bepartially or slightly bent, curved, made into an S-shape, or made into ahelical shape to allow for expansion and/or contraction of the heatingelements. In certain embodiments, solid rod heating elements 568 areplaced in small diameter wellbores (for example, about 3¾″ (about 9.5cm) diameter wellbores). Small diameter wellbores may be less expensiveto drill or form than larger diameter wellbores.

In certain embodiments, portions of legs 562 and 564 in overburden 370have insulation (for example, polymer insulation) to inhibit heating theoverburden. Heating elements 568 may be substantially vertical andsubstantially parallel to each other in hydrocarbon layer 254. At ornear the bottom of hydrocarbon layer 254, leg 562 may be directionallydrilled towards leg 564 to intercept leg 564 in contacting section 572.Directional drilling may be done by, for example, Vector Magnetics LLC(Ithaca, N.Y.). The depth of contacting section 572 depends on thelength of bend in leg 562 needed to intercept leg 564. For example, fora 40 ft. (about 12 m) spacing between vertical portions of legs 562 and564, about 200 ft. (about 61 m) is needed to allow the bend of leg 562to intercept leg 564.

FIG. 101 depicts an embodiment for coupling legs 562 and 564 incontacting section 572. Heating elements 568 are coupled to contactingelements 570 at or near junction of contacting section 572 andhydrocarbon layer 254. Contacting elements 570 may be copper or anothersuitable electrical conductor. In certain embodiments, contactingelement 570 in leg 564 is a liner with opening 574. Contacting element570 from leg 562 passes through opening 574. Contactor 576 is coupled tothe end of contacting element 570 from leg 562. Contactor 576 provideselectrical coupling between contacting elements in legs 562 and 564.

FIG. 102 depicts an embodiment for coupling legs 562 and 564 incontacting section 572 with contact solution 578 in the contactingsection. Contact solution 578 is placed in portions of leg 562 and/orportions of leg 564 with contacting elements 570. Contact solution 578promotes electrical contact between contacting elements 570. Contactsolution 578 may be graphite based cement or another high electricalconductivity cement or solution (for example, brine or other ionicsolutions).

In some embodiments, electrical contact is made between contactingelements 570 using only contact solution 578. FIG. 103 depicts anembodiment for coupling legs 562 and 564 in contacting section 572without a contactor. Contacting elements 570 may or may not touch incontacting section 572. Electrical contact between contacting elements570 in contacting section 572 is made using contact solution 578.

In certain embodiments, contacting elements 570 include one or more finsor projections. The fins or projections may increase an electricalcontact area of contacting elements 570. In some embodiments, legs 562and 564 (for example, electrical conductors in heating elements 568) areelectrically coupled together but do not physically contact each other.This type of electrical coupling may be accomplished with, for example,contact solution 578.

In some embodiments, the temperature limited heater includes a singleferromagnetic conductor with current returning through the formation.The heating element may be a ferromagnetic tubular (in an embodiment,446 stainless steel (with 25% by weight chromium and a Curie temperatureabove 620° C.) clad over 304H, 316H, or 347H stainless steel) thatextends through the heated target section and makes electrical contactto the formation in an electrical contacting section. The electricalcontacting section may be located below a heated target section. Forexample, the electrical contacting section is in the underburden of theformation. In an embodiment, the electrical contacting section is asection 60 m deep with a larger diameter than the heater wellbore. Thetubular in the electrical contacting section is a high electricalconductivity metal. The annulus in the electrical contacting section maybe filled with a contact material/solution such as brine or othermaterials that enhance electrical contact with the formation (forexample, metal beads, hematite, and/or graphite based cement). Theelectrical contacting section may be located in a low resistivity brinesaturated zone (with higher porosity) to maintain electrical contactthrough the brine. In the electrical contacting section, the tubulardiameter may also be increased to allow maximum current flow into theformation with lower heat dissipation in the fluid. Current may flowthrough the ferromagnetic tubular in the heated section and heat thetubular.

FIG. 104 depicts an embodiment of a temperature limited heater withcurrent return through the formation. Heating element 568 may be placedin opening 252 in hydrocarbon layer 254. Heating element 568 may be 446stainless steel clad over a 304H stainless steel tubular that extendsthrough hydrocarbon layer 254. Heating element 568 may be coupled tocontacting element 570. Contacting element 570 may have a higherelectrical conductivity than heating element 568. Contacting element 570may be placed in electrical contacting section 572, located belowhydrocarbon layer 254. Contacting element 570 may make electricalcontact with the earth in contacting section 572. Contacting element 570may be placed in contacting wellbore 580. Contacting element 570 mayhave a diameter between about 10 cm and about 20 cm (for example, about15 cm). The diameter of contacting element 570 may be sized to increasecontact area between contacting element 570 and contact solution 578.The contact area may be increased by increasing the diameter ofcontacting element 570. Increasing the diameter of contacting element570 may increase the contact area without adding excessive cost toinstallation and use of the contacting element, contacting wellbore 580,and/or contact solution 578. Increasing the diameter of contactingelement 570 may allow sufficient electrical contact to be maintainedbetween the contacting element and contacting section 572. Increasingthe contact area may also inhibit evaporation or boiling off of contactsolution 578.

Contacting wellbore 580 may be, for example, a section about 60 m deepwith a larger diameter wellbore than opening 252. The annulus ofcontacting wellbore 580 may be filled with contact solution 578. Contactsolution 578 may be brine or other material (such as graphite basedcement, electrically conducting particles such as hematite, ormetal-coated sand or beads) that enhances electrical contact incontacting section 572. In some embodiments, contacting section 572 is alow resistivity brine saturated zone that maintains electrical contactthrough the brine. Contacting wellbore 580 may be under-reamed to alarger diameter (for example, a diameter between about 25 cm and about50 cm) to allow maximum current flow into contacting section 572 withlow heat output. Current may flow through heating element 568, boilingmoisture from the wellbore, and heating until the heat output reducesnear or at the Curie temperature.

In an embodiment, three-phase temperature limited heaters are made withcurrent connection through the formation. Each heater includes a singleCurie temperature heating element with an electrical contacting sectionin a brine saturated zone below a heated target section. In anembodiment, three such heaters are connected electrically at the surfacein a three-phase wye configuration. The heaters may be deployed in atriangular pattern from the surface. In certain embodiments, the currentreturns through the earth to a neutral point between the three heaters.The three-phase Curie heaters may be replicated in a pattern that coversthe entire formation.

FIG. 105 depicts an embodiment of a three-phase temperature limitedheater with current connection through the formation. Legs 562, 564, 566may be placed in the formation. Each leg 562, 564, 566 may have heatingelement 568 that is placed in opening 252 in hydrocarbon layer 254. Eachleg may have contacting element 570 placed in contact solution 578 incontacting wellbore 580. Each contacting element 570 may be electricallycoupled to electrical contacting section 572 through contact solution578. Legs 562, 564, 566 may be connected in a wye configuration thatresults in a neutral point in electrical contacting section 572 betweenthe three legs. FIG. 106 depicts an aerial view of the embodiment ofFIG. 105 with neutral point 582 shown positioned centrally among legs562, 564, 566.

FIG. 107 depicts an embodiment of three temperature limited heaterselectrically coupled to a horizontal wellbore in the formation. Wellbore584 may have a substantially horizontal portion in contacting section572. Openings 252 may be directionally drilled to intersect wellbore 584in contacting wellbores 580. In some embodiments, wellbore 584 isdirectionally drilled to intersect openings 252 in contacting wellbores580. Contacting wellbores 580 may be underreamed. Underreaming mayincrease the likelihood of intersection between openings 252 andwellbore 584 during drilling and/or increase the contact volume incontacting wellbores 580.

In certain embodiments, legs 562, 564, 566 are coupled in a three-phasewye configuration. In some embodiments, legs 562, 564, 566, along withone or more other legs, are coupled through wellbore 584 in a singlephase configuration in which the legs are alternately biased positivelyand negatively so that current alternately runs up and down the legs. Insome embodiments, legs 562, 564, 566 are single phase heaters withcurrent returning to the surface through wellbore 584.

In certain embodiments, legs 562, 564, 566 are electrically coupled incontacting wellbores 580 using contact solution 578. Contact solution578 may be located in individual contacting wellbores 580 or may belocated along the length of the horizontal portion of wellbore 584. Insome embodiments, electrical contact is made between legs 562, 564, 566and/or materials in wellbore 584 through other methods (for example,contactors or contacting elements such as funnels, guides, or catchers).

FIG. 108 depicts an embodiment of a three-phase temperature limitedheater with a common current connection through the formation. In FIG.108, each leg 562, 564, 566 couples to a single contacting element 570in a single contacting wellbore 580. Legs 562 and 566 are directionallydrilled to intercept leg 564 in wellbore 580. Contacting element 570 mayinclude funnels, guides, or catchers for allowing each leg to beinserted into the contacting element. In some embodiments, graphitebased cement is used for contact solution 578.

A section of heater through a high thermal conductivity zone may betailored to deliver more heat dissipation in the high thermalconductivity zone. Tailoring of the heater may be achieved by changingcross-sectional areas of the heating elements (for example, by changingratios of copper to iron), and/or using different metals in the heatingelements. Thermal conductance of the insulation layer may also bemodified in certain sections to control the thermal output to raise orlower the apparent Curie temperature.

In an embodiment, the temperature limited heater includes a hollow coreor hollow inner conductor. Layers forming the heater may be perforatedto allow fluids from the wellbore (for example, formation fluids orwater) to enter the hollow core. Fluids in the hollow core may betransported (for example, pumped or gas lifted) to the surface throughthe hollow core. In some embodiments, the temperature limited heaterwith the hollow core or the hollow inner conductor is used as aheater/production well or a production well. Fluids such as steam may beinjected into the formation through the hollow inner conductor.

In certain embodiments, a temperature limited heater is utilized forheavy oil applications (for example, treatment of relatively permeableformations or tar sands formations). A temperature limited heater mayprovide a relatively low Curie temperature so that a maximum averageoperating temperature of the heater is less than 350° C., 300° C., 250°C., 225° C., 200° C., or 150° C. In an embodiment (for example, for atar sands formation), a maximum temperature of the heater is less thanabout 250° C. to inhibit olefin generation and production of othercracked products. In some embodiments, a maximum temperature of theheater above about 250° C. is used to produce lighter hydrocarbonproducts. For example, the maximum temperature of the heater may be ator less than about 500° C.

A heater may heat a volume of formation adjacent to a productionwellbore (a near production wellbore region) so that the temperature offluid in the production wellbore and in the volume adjacent to theproduction wellbore is less than the temperature that causes degradationof the fluid. The heat source may be located in the production wellboreor near the production wellbore. In some embodiments, the heat source isa temperature limited heater. In some embodiments, two or more heatsources may supply heat to the volume. Heat from the heat source mayreduce the viscosity of crude oil in or near the production wellbore. Insome embodiments, heat from the heat source mobilizes fluids in or nearthe production wellbore and/or enhances the radial flow of fluids to theproduction wellbore. In some embodiments, reducing the viscosity ofcrude oil allows or enhances gas lifting of heavy oil (approximately atmost 10° API gravity oil) or intermediate gravity oil (approximately 12°to 20° API gravity oil) from the production wellbore. In certainembodiments, the initial API gravity of oil in the formation is at most10°, at most 20°, at most 25°, or at most 30°. In certain embodiments,the viscosity of oil in the formation is at least 0.05 Pa·s (50 cp). Insome embodiments, the viscosity of oil in the formation is at least 0.10Pa·s (100 cp), at least 0.15 Pa·s (150 cp), or at least at least 0.20Pa·s (200 cp). Large amounts of natural gas may have to be utilized toprovide gas lift of oil with viscosities above 0.05 Pa·s. Reducing theviscosity of oil at or near the production wellbore in the formation toa viscosity of 0.05 Pa·s (50 cp), 0.03 Pa·s (30 cp), 0.02 Pa·s (20 cp),0.01 Pa·s (10 cp), or less (down to 0.001 Pa·s (1 cp) or lower) lowersthe amount of natural gas needed to lift oil from the formation. In someembodiments, reduced viscosity oil is produced by other methods such aspumping.

The rate of production of oil from the formation may be increased byraising the temperature at or near a production wellbore to reduce theviscosity of the oil in the formation in and adjacent to the productionwellbore. In certain embodiments, the rate of production of oil from theformation is increased by 2 times, 3 times, 4 times, or greater up to 20times over standard cold production, which has no external heating offormation during production. Certain formations may be more economicallyviable for enhanced oil production using the heating of the nearproduction wellbore region. Formations that have a cold production rateapproximately between 0.05 m³/(day per meter of wellbore length) and0.20 m³/(day per meter of wellbore length) may have significantimprovements in production rate using heating to reduce the viscosity inthe near production wellbore region. In some formations, productionwells up to 775 m, up to 1000 m, or up to 1500 m in length are used. Forexample, production wells between 450 m and 775 m in length are used,between 550 m and 800 m are used, or between 650 m and 900 m are used.Thus, a significant increase in production is achievable in someformations. Heating the near production wellbore region may be used informations where the cold production rate is not between 0.05 m³/(dayper meter of wellbore length) and 0.20 m³/(day per meter of wellborelength), but heating such formations may not be as economicallyfavorable. Higher cold production rates may not be significantlyincreased by heating the near wellbore region, while lower productionrates may not be increased to an economically useful value.

Using the temperature limited heater to reduce the viscosity of oil ator near the production well inhibits problems associated withnon-temperature limited heaters and heating the oil in the formation dueto hot spots. One possible problem is that non-temperature limitedheaters can causing coking of oil at or near the production well if theheater overheats the oil because the heaters are at too high atemperature. Higher temperatures in the production well may also causebrine to boil in the well, which may lead to scale formation in thewell. Non-temperature limited heaters that reach higher temperatures mayalso cause damage to other wellbore components (for example, screensused for sand control, pumps, or valves). Hot spots may be caused byportions of the formation expanding against or collapsing on the heater.In some embodiments, the heater (either the temperature limited heateror another type of non-temperature limited heater) has sections that arelower because of sagging over long heater distances. These lowersections may sit in heavy oil or bitumen that collects in lower portionsof the wellbore. At these lower sections, the heater may develop hotspots due to coking of the heavy oil or bitumen. A standardnon-temperature limited heater may overheat at these hot spots, thusproducing a non-uniform amount of heat along the length of the heater.Using the temperature limited heater may inhibit overheating of theheater at hot spots or lower sections and provide more uniform heatingalong the length of the wellbore.

In some embodiments, oil or bitumen cokes in a perforated liner orscreen in a heater/production wellbore (for example, coke may formbetween the heater and the liner or between the liner and theformation). Oil or bitumen may also coke in a toe section of a heel andtoe heater/production wellbore, as shown in and described below for FIG.127. A temperature limited heater may limit a temperature of aheater/production wellbore below a coking temperature to inhibit cokingin the well so that production in the wellbore does not plug up.

FIG. 109 depicts an embodiment for heating and producing from theformation with the temperature limited heater in a production wellbore.Production conduit 366 is located in wellbore 586. In certainembodiments, a portion of wellbore 586 is located substantiallyhorizontally in formation 314. In some embodiments, the wellbore islocated substantially vertically in the formation. In an embodiment,wellbore 586 is an open wellbore (an uncased wellbore). In someembodiments, the wellbore has a casing or liner with perforations oropenings to allow fluid to flow into the wellbore.

Conduit 366 may be made from carbon steel or more corrosion resistantmaterials such as stainless steel. Conduit 366 may include apparatus andmechanisms for gas lifting or pumping produced oil to the surface. Forexample, conduit 366 includes gas lift valves used in a gas liftprocess. Examples of gas lift control systems and valves are disclosedin U.S. Pat. No. 6,715,550 to Vinegar et al. and U.S. Patent ApplicationPublication Nos. 2002-0036085 to Bass et al. and 2003-0038734 to Hirschet al., each of which is incorporated by reference as if fully set forthherein. Conduit 366 may include one or more openings (perforations) toallow fluid to flow into the production conduit. In certain embodiments,the openings in conduit 366 are in a portion of the conduit that remainsbelow the liquid level in wellbore 586. For example, the openings are ina horizontal portion of conduit 366.

Heater 382 is located in conduit 366, as shown in FIG. 109. In someembodiments, heater 382 is located outside conduit 366, as shown in FIG.110. The heater located outside the production conduit may be coupled(strapped) to the production conduit. In some embodiments, more than oneheater (for example, two, three, or four heaters) are placed aboutconduit 366. The use of more than one heater may reduce bowing orflexing of the production conduit caused by heating on only one side ofthe production conduit. In an embodiment, heater 382 is a temperaturelimited heater. Heater 382 provides heat to reduce the viscosity offluid (such as oil or hydrocarbons) in and near wellbore 586. In certainembodiments, heater 382 raises the temperature of the fluid in wellbore586 up to a temperature of 250° C. or less (for example, 225° C., 200°C., or 150° C.). Heater 382 may be at higher temperatures (for example,275° C., 300° C., or 325° C.) because the heater provides heat toconduit 366 and there is some temperature differential between theheater and the conduit. Thus, heat produced from the heater does notraise the temperature of fluids in the wellbore above 250° C.

In certain embodiments, heater 382 includes ferromagnetic materials suchas Carpenter Temperature Compensator “32”, Alloy 42-6, Alloy 52, Invar36, or other iron-nickel or iron-nickel-chromium alloys. In certainembodiments, nickel or nickel-chromium alloys are used in heater 382. Insome embodiments, heater 382 includes a composite conductor with a morehighly conductive material such as copper on the inside of the heater toimprove the turndown ratio of the heater. Heat from heater 382 heatsfluids in or near wellbore 586 to reduce the viscosity of the fluids andincrease a production rate through conduit 366.

In certain embodiments, portions of heater 382 above the liquid level inwellbore 586 (such as the vertical portion of the wellbore depicted inFIGS. 109 and 110) have a lower maximum temperature than portions of theheater located below the liquid level. For example, portions of heater382 above the liquid level in wellbore 586 may have a maximumtemperature of 100° C. while portions of the heater located below theliquid level have a maximum temperature of 250° C. In certainembodiments, such a heater includes two or more ferromagnetic sectionswith different Curie temperatures to achieve the desired heatingpattern. Providing less heat to portions of wellbore 586 above theliquid level and closer to the surface may save energy.

In certain embodiments, heater 382 is electrically isolated on theheater's outside surface and allowed to move freely in conduit 366. Insome embodiments, electrically insulating centralizers are placed on theoutside of heater 382 to maintain a gap between conduit 366 and theheater.

In some embodiments, heater 382 is cycled (turned on and off) so thatfluids produced through conduit 366 are not overheated. In anembodiment, heater 382 is turned on for a specified amount of time untila temperature of fluids in or near wellbore 586 reaches a desiredtemperature (for example, the maximum temperature of the heater). Duringthe heating time (for example, 10 days, 20 days, or 30 days), productionthrough conduit 366 may be stopped to allow fluids in the formation to“soak” and obtain a reduced viscosity. After heating is turned off orreduced, production through conduit 366 is started and fluids from theformation are produced without excess heat being provided to the fluids.During production, fluids in or near wellbore 586 will cool down withoutheat from heater 382 being provided. When the fluids reach a temperatureat which production significantly slows down, production is stopped andheater 382 is turned back on to reheat the fluids. This process may berepeated until a desired amount of production is reached. In someembodiments, some heat at a lower temperature is provided to maintain aflow of the produced fluids. For example, low temperature heat (forexample, 100° C., 125° C., or 150° C.) may be provided in the upperportions of wellbore 586 to keep fluids from cooling to a lowertemperature.

FIG. 111 depicts an embodiment of a heating/production assembly that maybe located in a wellbore for gas lifting. Heating/production assembly588 may be located in a wellbore in the formation (for example, wellbore586 depicted in FIG. 109 or 110). Conduit 366 is located inside casing480. In an embodiment, conduit 366 is coiled tubing such as 6 cmdiameter coiled tubing. Casing 480 has a diameter between 10 cm and 25cm (for example, a diameter of 14 cm, 16 cm, or 18 cm). Heater 382 iscoupled to an end of conduit 366. In some embodiments, heater 382 islocated inside conduit 366. In some embodiments, heater 382 is aresistive portion of conduit 366. In some embodiments, heater 382 iscoupled to a length of conduit 366.

Opening 590 is located at or near a junction of heater 382 and conduit366. In some embodiments, opening 590 is a slot or a slit in conduit366. In some embodiments, opening 590 includes more than one opening inconduit 366. Opening 590 allows production fluids to flow into conduit366 from a wellbore. Perforated casing 592 allows fluids to flow intothe heating/production assembly 588. In certain embodiments, perforatedcasing 592 is a wire wrapped screen. In one embodiment, perforatedcasing 592 is a 9 cm diameter wire wrapped screen.

Perforated casing 592 may be coupled to casing 480 with packing material372. Packing material 372 inhibits fluids from flowing into casing 480from outside perforated casing 592. Packing material 372 may also beplaced inside casing 480 to inhibit fluids from flowing up the annulusbetween the casing and conduit 366. Seal assembly 594 is used to sealconduit 366 to packing material 372. Seal assembly 594 may fix aposition of conduit 366 along a length of a wellbore. In someembodiments, seal assembly 594 allows for unsealing of conduit 366 sothat the production conduit and heater 382 may be removed from thewellbore.

Feedthrough 596 is used to pass lead-in cable 494 to supply power toheater 382. Lead-in cable 494 may be secured to conduit 366 with clamp598. In some embodiments, lead-in cable 494 passes through packingmaterial 372 using a separate feedthrough.

A lifting gas (for example, natural gas, methane, carbon dioxide,propane, and/or nitrogen) may be provided to the annulus between conduit366 and casing 480. Valves 600 are located along a length of conduit 366to allow gas to enter the production conduit and provide for gas liftingof fluids in the production conduit. The lifting gas may mix with fluidsin conduit 366 to lower the density of the fluids and allow for gaslifting of the fluids out of the formation. In certain embodiments,valves 600 are located in an overburden section of a formation so thatgas lifting is provided in the overburden section. In some embodiments,fluids are produced through the annulus between conduit 366 and casing480 and a lifting gas may be supplied through valves 600.

In an embodiment, fluids are produced using a pump coupled to conduit366. The pump may be a submersible pump (for example, an electric or gaspowered submersible pump). In some embodiments, a heater is coupled toconduit 366 to maintain the reduced viscosity of fluids in the conduitand/or the pump.

In certain embodiments, an additional conduit such as an additionalcoiled tubing conduit is placed in the formation. Sensors may be placedin the additional conduit. For example, a production logging tool may beplaced in the additional conduit to identify locations of producingzones and/or to assess flow rates. In some embodiments, a temperaturesensor (for example, a distributed temperature sensor, a fiber opticsensor, and/or an array of thermocouples) is placed in the additionalconduit to determine a subsurface temperature profile.

Some embodiments of the heating/production assembly are used in a wellthat preexists (for example, the heating/production assembly isretrofitted for a preexisting production well, heater well, ormonitoring well). An example of the heating/production assembly that maybe used in the preexisting well is depicted in FIG. 112. Somepreexisting wells include a pump. The pump in the preexisting well maybe left in the heating/production well retrofitted with theheating/production assembly.

FIG. 112 depicts an embodiment of the heating/production assembly thatmay be located in the wellbore for gas lifting. In FIG. 112, conduit 366is located in outside production conduit 602. In an embodiment, outsideproduction conduit 602 is 11.4 cm diameter production tubing. Casing 480has a diameter of 24.4 cm. Perforated casing 592 has a diameter of 11.4cm. Seal assembly 594 seals conduit 366 inside outside productionconduit 602. In an embodiment, pump 378 is a jet pump such as abottomhole assembly jet pump.

FIG. 113 depicts another embodiment of a heating/production assemblythat may be located in a wellbore for gas lifting. Heater 382 is locatedinside perforated casing 592. Heater 382 is coupled to lead-in cable494. Production conduit 366 extends through packing material 372. Pump378 is located along conduit 366. In certain embodiments, pump 378 is ajet pump or a bean pump. Valves 600 are located along conduit 366 forsupplying lift gas to the conduit.

In some embodiments, heat is inhibited from transferring into conduit366. FIG. 114 depicts an embodiment of conduit 366 and heaters 382 thatinhibit heat transfer into the conduit. Heaters 382 are coupled toconduit 366. Heaters 382 include ferromagnetic sections 426 andnon-ferromagnetic sections 428. Ferromagnetic sections 426 provide heatat a temperature that reduces the viscosity of fluids in or near awellbore. Non-ferromagnetic sections 428 provide little or no heat. Incertain embodiments, ferromagnetic sections 426 and non-ferromagneticsections 428 are 6 m in length. In some embodiments, ferromagneticsections 426 and non-ferromagnetic sections 428 are between 3 m and 12 min length, between 4 m and 11 m in length, or between 5 m and 10 m inlength. In certain embodiments, non-ferromagnetic sections 428 includeperforations 604 to allow fluids to flow to conduit 366. In someembodiments, heater 382 is positioned so that perforations are notneeded to allow fluids to flow to conduit 366.

Conduit 366 may have perforations 604 to allow fluid to enter theconduit. Perforations 604 coincide with non-ferromagnetic sections 428of heater 382. Sections of conduit 366 that coincide with ferromagneticsections 426 include insulation conduit 606. Conduit 606 may be a vacuuminsulated tubular. For example, conduit 606 may be a vacuum insulatedproduction tubular available from Oil Tech Services, Inc. (Houston,Tex.). Conduit 606 inhibits heat transfer into conduit 366 fromferromagnetic sections 426. Limiting the heat transfer into conduit 366reduces heat loss and/or inhibits overheating of fluids in the conduit.In an embodiment, heater 382 provides heat along an entire length of theheater and conduit 366 includes conduit 606 along an entire length ofthe production conduit.

In certain embodiments, more than one wellbore 586 is used to produceheavy oils from a formation using the temperature limited heater. FIG.115 depicts an end view of an embodiment with wellbores 586 located inhydrocarbon layer 254. A portion of wellbores 586 are placedsubstantially horizontally in a triangular pattern in hydrocarbon layer254. In certain embodiments, wellbores 586 have a spacing of 30 m to 60m, 35 m to 55 m, or 40 m to 50 m. Wellbores 586 may include productionconduits and heaters previously described. Fluids may be heated andproduced through wellbores 586 at an increased production rate above acold production rate for the formation. Production may continue for aselected time (for example, 5 years to 10 years, 6 years to 9 years, or7 years to 8 years) until heat produced from each of wellbores 586begins to overlap (superposition of heat begins). At such a time, heatfrom lower wellbores (such as wellbores 586 near the bottom ofhydrocarbon layer 254) is continued, reduced, or turned off whileproduction is continued. Production in upper wellbores (such aswellbores 586 near the top of hydrocarbon layer 254) may be stopped sothat fluids in the hydrocarbon layer drain towards the lower wellbores.In some embodiments, power is increased to the upper wellbores and thetemperature raised above the Curie temperature to increase the heatinjection rate. Draining fluids in the formation in such a processincreases total hydrocarbon recovery from the formation.

Production well lift systems may be used to efficiently transportformation fluid from the bottom of the production wells to the surface.Production well lift systems may provide and maintain the maximumrequired well drawdown (minimum reservoir producing pressure) andproducing rates. The production well lift systems may operateefficiently over a wide range of high temperature/multiphase fluids(gas/vapor/steam/water/hydrocarbon liquids) and production ratesexpected during the life of a typical project.

FIG. 116 illustrates an embodiment of a dual concentric rod pump systemuse in production wells. The formation fluid enters wellbore 608 fromheated portion 610. Formation fluid may be transported to the surfacethrough inner conduit 612 and outer conduit 614. Inner conduit 612 andouter conduit 614 may be concentric. Concentric conduits may beadvantageous over dual (side by side) conduits in conventional oilfieldproduction wells. Inner conduit 612 may be used for production ofliquids. Outer conduit 614 may allow vapor and/or gaseous phaseformation fluids to flow to the surface along with some entrainedliquids.

The diameter of outer conduit 614 may be chosen to allow a desired rangeof flow rates and/or to minimize the pressure drop and flowing reservoirpressure. Reflux seal 616 at the base of outer conduit 614 may inhibithot produced gases and/or vapors from contacting the relatively coldwall of well casing 624 above heated portion 610. This minimizespotentially damaging and wasteful energy losses from heated portion 610via condensation and recycling of fluids. Reflux seal 616 may be adynamic seal, allowing outer conduit 614 to thermally expand andcontract while being fixed at surface 620. Reflux seal 616 may be aone-way seal designed to allow fluids to be pumped down annulus 618 fortreatment or for well kill operations. For example, down-facingelastomeric-type cups may be used in reflux seal 616 to inhibit fluidsfrom flowing upward through annulus 618. In some embodiments, refluxseal 616 is a “fixed” design, with a dynamic wellhead seal that allowsouter conduit 614 to move at surface 620, thereby reducing thermalstresses and cycling.

Conditions in any particular well or project could allow both ends ofouter conduit 614 to be fixed. Outer conduit 614 may require no orinfrequent retrieval for maintenance over the expected useful life ofthe production well. In some embodiments, utility bundle 622 is coupledto the outside of outer conduit 614. Utility bundle 622 may include, butis not limited to, conduits for monitoring, control, and/or treatmentequipment such as temperature/pressure monitoring devices, chemicaltreatment lines, diluent injection lines, and cold fluid injection linesfor cooling of the liquid pumping system. Coupling utility bundle 622 toouter conduit 614 may allow the utility bundle (and thus the potentiallycomplex and sensitive equipment included in this bundle) to remain inplace during retrieval and/or maintenance of inner conduit 612. Incertain embodiments, outer conduit 614 is removed one or more times overthe expected useful life of the production well.

Annulus 618 between well casing 624 and outer conduit 614 may provide aspace to run utility bundle 622 and instrumentation, as well as thermalinsulation to optimize and/or control temperature and/or behavior of theproduced fluid. In some embodiments, annulus 618 is filled with one ormore fluids or gases (pressurized or not) to allow regulation of theoverall thermal conductivity and resulting heat transfer between theoverburden and the formation fluid being produced. Using annulus 618 asa thermal barrier may allow: 1) optimization of temperature and/or phasebehavior of the fluid stream for subsequent processing of the fluidstream at the surface, and/or 2) optimization of multiphase behavior toenable maximum natural flow of fluids and liquid stream pumping. Theconcentric configuration of outer conduit 614 and inner conduit 612 isadvantageous in that the heat transfer/thermal effects on the fluidstreams are more uniform than a conventional dual (parallel tubing)configuration.

Inner conduit 612 may be used for production of liquids. Liquidsproduced from inner conduit 612 may include fluids in liquid form thatare not entrained with gas/vapor produced from outer conduit 614, aswell as liquids that condense in the outer conduit. In some embodiments,the base of inner conduit 612 is positioned below the base of heatedportion 610 (in sump 626) to assist in natural gravity separation of theliquid phase. Sump 626 may be a separation sump. Sump 626 may alsoprovide thermal benefits (for example, cooler pump operation and reducedliquid flashing in the pump) depending upon the depth of the sump andoverall fluid rates and/or temperatures.

Inner conduit 612 may include a pump system. In some embodiments, pumpsystem 628 is an oilfield-type reciprocating rod pump. Such pumps areavailable in a wide variety of designs and configurations. Reciprocatingrod pumps have the advantages of being widely available and costeffective. In addition, surveillance/evaluation analysis methods arewell-developed and understood for this system. In certain embodiments,the prime mover is advantageously located on the surface foraccessibility and maintenance. Location of the prime mover on thesurface also protects the prime mover from the extreme temperature/fluidenvironment of the wellbore. FIG. 116 depicts a conventionaloilfield-type beam-pumping unit on surface 620 for reciprocation of rodstring 630. Other types of pumps may be used including, but not limitedto, hydraulic pumps, long-stroke pumps, air-balance pumps,surface-driven rotary pumps, and MII pumps. A pump may be chosendepending on well conditions and desired pumping rates. In certainembodiments, inner conduit 612 is anchored to limit movement and wear ofthe inner conduit.

Concentric placement of outer conduit 614 and inner conduit 612 mayfacilitate maintenance of the inner conduit and the associated pumpsystem, including intervention and/or replacement of downholecomponents. The concentric design allows formaintenance/removal/replacement of inner conduit 612 without disturbingouter conduit 614 and related components, thus lowering overallexpenses, reducing well downtime, and/or improving overall projectperformance compared to a conventional parallel double conduitconfiguration. The concentric configuration may also be modified toaccount for unexpected changes in well condition over time. The pumpsystem can be quickly removed and both conduits may be utilized forflowing production in the event of lower liquid rates or much highervapor/gas rates than anticipated. Conversely, a larger or differentsystem can easily be installed in the inner conduit without affectingthe balance of the system components.

Various methods may be used to control the pump system to enhanceefficiency and well production. These methods may include, for example,the use of on/off timers, pump-off detection systems to measure surfaceloads and model the downhole conditions, direct fluid level sensingdevices, and sensors suitable for high-temperature applications(capillary tubing, etc.) to allow direct downhole pressure monitoring.In some embodiments, the pumping capacity is matched with availablefluid to be pumped from the well.

Various design options and/or configurations for the conduits and/or rodstring (including materials, physical dimensions, and connections) maybe chosen to enhance overall reliability, cost, ease of initialinstallation, and subsequent intervention and/or maintenance for a givenproduction well. For example, connections may be threaded, welded, ordesigned for a specific application. In some embodiments, sections ofone or more of the conduits are connected as the conduit is lowered intothe well. In certain embodiments, sections of one or more of theconduits are connected prior to insertion in the well, and the conduitis spooled (for example, at a different location) and later unspooledinto the well. The specific conditions within each production welldetermine equipment parameters such as equipment sizing, conduitdiameters, and sump dimensions for optimal operation and performance.

FIG. 117 illustrates an embodiment of the dual concentric rod pumpsystem including 2-phase separator 632 at the bottom of inner conduit612 to aid in additional separation and exclusion of gas/vapor phasefluids from rod pump 628. Use of 2-phase separator 632 may beadvantageous at higher vapor and gas/liquid ratios. Use of 2-phaseseparator 632 may help prevent gas locking and low pump efficiencies ininner conduit 612.

FIG. 118 depicts an embodiment of the dual concentric rod pump systemthat includes gas/vapor shroud 634 extending down into sump 626.Gas/vapor shroud 634 may force the majority of the produced fluid streamdown through the area surrounding sump 626, increasing the naturalliquid separation. Gas/vapor shroud 634 may include sized gas/vapor vent636 at the top of the heated zone to inhibit gas/vapor pressure frombuilding up and being trapped behind the shroud. Thus, gas/vapor shroud634 may increase overall well drawdown efficiency, and becomes moreimportant as the thickness of heated portion 610 increases. The size ofgas/vapor vent 636 may vary and can be determined based on the expectedfluid volumes and desired operating pressures for any particularproduction well.

FIG. 119 depicts an embodiment of a gas lift system for use inproduction wells. Conduit 638 provides a path for fluids of all phasesto be transported from heated portion 610 to surface 620. Packer/refluxseal assembly 640 is located above heated portion 610 to inhibitproduced fluids from entering annulus 618 between conduit 638 and wellcasing 624 above the heated portion. Packer/reflux seal assembly 640 mayreduce the refluxing of the fluid, thereby advantageously reducingenergy losses. In this configuration, packer/reflux seal assembly 640may substantially isolate the pressurized lift gas in annulus 618 abovethe packer/reflux seal assembly from heated portion 610. Thus, heatedportion 610 may be exposed to the desired minimum drawdown pressure,maximizing fluid inflow to the well. As an additional aid in maintaininga minimum drawdown pressure, sump 626 may be located in the wellborebelow heated portion 610. Produced fluids/liquids may therefore collectin the wellbore below heated portion 610 and not cause excessivebackpressure on the heated portion. This becomes more advantageous asthe thickness of heated portion 610 increases.

Fluids of all phases may enter the well from heated portion 610. Thesefluids are directed downward to sump 626. The fluids enter lift chamber642 through check valve 644 at the base of the lift chamber. Aftersufficient fluid has entered lift chamber 642, lift gas injection valve646 opens and allows pressurized lift gas to enter the top of the liftchamber. Crossover port 648 allows the lift gas to pass throughpacker/reflux seal assembly 640 into the top of lift chamber 642. Theresulting pressure increase in lift chamber 642 closes check valve 644at the base and forces the fluids into the bottom of diptube 650, upinto conduit 638, and out of the lift chamber. Lift gas injection valve646 remains open until sufficient lift gas has been injected to evacuatethe fluid in lift chamber 642 to a collection device. Lift gas injectionvalve 646 then closes and allows lift chamber 642 to fill with fluidagain. This “lift cycle” repeats (intermittent operation) as often asnecessary to maintain the desired drawdown pressure within heatedportion 610. Sizing of equipment, such as conduits, valves, and chamberlengths and/or diameters, is dependent upon the expected fluid ratesproduced from heated portion 610 and the desired minimum drawdownpressure to be maintained in the production well.

In some embodiments, the entire gas lift system may be retrievable fromthe well for repair, maintenance, and periodic design revisions due tochanging well conditions. However, the need for retrieving conduit 638,packer/reflux seal assembly 640, and lift chamber 642 may be relativelyinfrequent. In some embodiments, lift gas injection valve 646 isconfigured to be positioned in the formation and/or to be retrieved fromthe formation along with conduit 638. In certain embodiments, lift gasinjection valve 646 is configured to be separately retrievable viawireline or similar means without removing conduit 638 or other systemcomponents from the formation. Check valve 644 and/or diptube 650 may beindividually installed and/or retrieved in a similar manner. The optionto retrieve diptube 650 separately may allow re-sizing of gas/vapor vent636. The option to retrieve these individual components (items thatwould likely require the most frequent well intervention, repair, andmaintenance) greatly improves the attractiveness of the system from awell intervention and maintenance cost perspective.

Gas/vapor vent 636 may be located at the top of lift chamber 642 toallow gas and/or vapor entering the lift chamber from heated portion 610to continuously vent into conduit 638 and inhibit an excess buildup ofchamber pressure Inhibiting an excess buildup of chamber pressure mayincrease overall system efficiency. Gas/vapor vent 636 may be sized toavoid excessive bypassing of injected lift gas into conduit 638 duringthe lift cycle, thereby promoting flow of the injected lift gas aroundthe base of diptube 650.

The embodiment depicted in FIG. 119 includes a single lift gas injectionvalve 646 (rather than multiple intermediate “unloading” valvestypically used in gas lift applications). Having a single lift gasinjection valve greatly simplifies the downhole system design and/ormechanics, thereby reducing the complexity and cost, and increasing thereliability of the overall system. Having a single lift gas injectionvalve, however, does require that the available gas lift system pressurebe sufficient to overcome and displace the heaviest fluid that mightfill the entire wellbore, or some other means to initially “unload” thewell in that event. Unloading valves may be used in some embodimentswhere the production wells are deep in the formation, for example,greater than 900 m deep, greater than 1000 m deep, or greater than 1500m deep in the formation.

In some embodiments, the chamber/well casing internal diameter ratio iskept as high as possible to maximize volumetric efficiency of thesystem. Keeping the chamber/well casing internal diameter ratio as highas possible may allow overall drawdown pressure and fluid productioninto the well to be maximized while pressure imposed on the heatedportion is minimized.

Lift gas injection valve 646 and the gas delivery and control system maybe designed to allow large volumes of gas to be injected into liftchamber 642 in a relatively short period of time to maximize theefficiency and minimize the time period for fluid evacuation. This mayallow liquid fallback in conduit 638 to be decreased (or minimized)while overall well fluid production potential is increased (ormaximized).

Various methods may be used to allow control of lift gas injection valve646 and the amount of gas injected during each lift cycle. Lift gasinjection valve 646 may be designed to be self-controlled, sensitive toeither lift chamber pressure or casing pressure. That is, lift gasinjection valve 646 may be similar to tubing pressure-operated or casingpressure-operated valves routinely used in conventional oilfield gaslift applications. Alternatively, lift gas injection valve 646 may becontrolled from the surface via either electric or hydraulic signal.These methods may be supplemented by additional controls that regulatethe rate and/or pressure at which lift gas is injected into annulus 618at surface 620. Other design and/or installation options for gas liftsystems (for example, types of conduit connections and/or method ofinstallation) may be chosen from a range of approaches known in the art.

FIG. 120 illustrates an embodiment of a gas lift system that includes anadditional parallel production conduit. Conduit 652 may allow continualflow of produced gas and/or vapor, bypassing lift chamber 642. Bypassinglift chamber 642 may avoid passing large volumes of gas and/or vaporthrough the lift chamber, which may reduce the efficiency of the systemwhen the volumes of gas and/or vapor are large. In this embodiment, thelift chamber evacuates any liquids from the well accumulating in sump626 that do not flow from the well along with the gas/vapor phases. Sump626 would aid the natural separation of liquids for more efficientoperation.

FIG. 121 depicts an embodiment of a gas lift system including injectiongas supply conduit 654 from surface 620 down to lift gas injection valve646. There may be some advantages to this arrangement (for example,relating to wellbore integrity and/or barrier issues) compared to use ofthe casing annulus to transport the injection gas. While lift gasinjection valve 646 is positioned downhole for control, thisconfiguration may also facilitate the alternative option to control thelift gas injection entirely from surface 620. Controlling the lift gasinjection entirely from surface 620 may eliminate the need for downholeinjection valve 646 and reduce the need for and/or costs associated withwellbore intervention. Providing a separate lift gas conduit alsopermits the annulus around the production tubulars to be kept at a lowpressure, or even under a vacuum, thus decreasing heat transfer from theproduction tubulars. This reduces condensation in conduit 652 and thusreflux back into heated portion 610.

FIG. 122 depicts an embodiment of a gas lift system with an additionalcheck valve located at the top of the lift chamber/diptube. Check valve656 may be retrieved separately via wireline or other means to reducemaintenance and reduce the complexity and/or cost associated with wellintervention. Check valve 656 may inhibit liquid fallback from conduit638 from returning to lift chamber 642 between lift cycles. In addition,check valve 656 may allow lift chamber 642 to be evacuated by displacingthe chamber fluids and/or liquids only into the base of conduit 638 (theconduit remains full of fluid between cycles), potentially optimizinginjection gas usage and energy. In some embodiments, the injection gastubing pressure is bled down in this displacement mode to allow maximumdrawdown pressure to be achieved with the surface injection gas controldepicted in FIG. 122.

As depicted in FIG. 122, the downhole lift gas injection valve has beeneliminated, and injection gas control valve 658 is located above surface620. In some embodiments, the downhole valve is used in addition toinjection gas control valve 658. Using the downhole control valve alongwith injection gas control valve 658 may allow the injection gas tubingpressure to be retained in the displacement cycle mode.

FIG. 123 depicts an embodiment of a gas lift system that allows mixingof the gas/vapor stream into conduit 638 (without a separate conduit forgas and/or vapor), while bypassing lift chamber 642. Gas/vapor vent 636equipped with check valve 644 may allow continuous production of thegas/vapor phase fluids into conduit 638 above lift chamber 642 betweenlift cycles. Check valve 644 may be separately retrievable as previouslydescribed for the other operating components. The embodiment depicted inFIG. 123 may allow simplification of the downhole equipment arrangementthrough elimination of the separate conduit for gas/vapor production. Insome embodiments, lift gas injection is controlled via downhole gasinjection valve 660. In certain embodiments, lift gas injection iscontrolled at surface 620.

FIG. 124 depicts an embodiment of a gas lift system with checkvalve/vent assembly 662 below packer/reflux seal assembly 640,eliminating the flow through the packer/reflux seal assembly. With checkvalve 646 and gas/vapor vent 636 below packer/reflux seal assembly 640,the gas/vapor stream bypasses lift chamber 642 while retaining thesingle, commingled production stream to surface 620. Check valve 662 maybe independently retrievable, as previously described.

As depicted in FIG. 124, diptube 650 may be an integral part of conduit638 and lift chamber 642. With diptube 650 an integral part of conduit638 and lift chamber 642, check valve 644 at the bottom of the liftchamber may be more easily accessed (for example, via non-rigintervention methods including, but not limited to, wireline and coiltubing), and a larger diptube diameter may be used for higherliquid/fluid volumes. The retrievable diptube arrangement, as previouslydescribed, may be applied here as well, depending upon specific wellrequirements.

FIG. 125 depicts an embodiment of a gas lift system with a separate flowpath to surface 620 for the gas/vapor phase of the production stream viaa concentric conduit approach similar to that described previously forthe pumping system concepts. This embodiment eliminates the need for acheck valve/vent system to commingle the gas/vapor stream into theproduction tubing with the liquid stream from the chamber as depicted inFIGS. 123 and 124 while including advantages of the concentric innerconduit 612 and outer conduit 614 depicted in FIGS. 116-118.

FIG. 126 depicts an embodiment of a gas lift system with gas/vaporshroud 634 extending down into the sump 626. Gas/vapor shroud 634 andsump 626 provide the same advantages as described with respect to FIG.118.

In an embodiment, a temperature limited heater is used in a horizontalheater/production well. The temperature limited heater may provideselected amounts of heat to the “toe” and the “heel” of the horizontalportion of the well. More heat may be provided to the formation throughthe toe than through the heel, creating a “hot portion” at the toe and a“warm portion” at the heel. Formation fluids may be formed in the hotportion and produced through the warm portion, as shown in FIG. 127.

FIG. 127 depicts an embodiment of a heater well for selectively heatinga formation. Heat source 210 is placed in opening 252 in hydrocarbonlayer 254. In certain embodiments, opening 252 is a substantiallyhorizontal opening in hydrocarbon layer 254. Perforated casing 592 isplaced in opening 252. Perforated casing 592 provides support thatinhibits hydrocarbon and/or other material in hydrocarbon layer 254 fromcollapsing into opening 252. Perforations in perforated casing 592 allowfor fluid flow from hydrocarbon layer 254 into opening 252. Heat source210 may include hot portion 664. Hot portion 664 is a portion of heatsource 210 that operates at higher heat output than adjacent portions ofthe heat source. For example, hot portion 664 may output between 650 W/mand 1650 W/m, 650 W/m and 1500 W/m, or 800 W/m and 1500 W/m. Hot portion664 may extend from a “heel” of the heat source to the “toe” of the heatsource. The heel of the heat source is the portion of the heat sourceclosest to the point at which the heat source enters a hydrocarbonlayer. The toe of the heat source is the end of the heat source furthestfrom the entry of the heat source into a hydrocarbon layer.

In an embodiment, heat source 210 includes warm portion 666. Warmportion 666 is a portion of heat source 210 that operates at lower heatoutputs than hot portion 664. For example, warm portion 666 may outputbetween 30 W/m and 1000 W/m, 30 W/m and 750 W/m, or 100 W/m and 750 W/m.Warm portion 666 may be located closer to the heel of heat source 210.In certain embodiments, warm portion 666 is a transition portion (forexample, a transition conductor) between hot portion 664 and overburdenportion 668. Overburden portion 668 is located in overburden 370.Overburden portion 668 provides a lower heat output than warm portion666. For example, overburden portion 668 may output between 10 W/m and90 W/m, 15 W/m and 80 W/m, or 25 W/m and 75 W/m. In some embodiments,overburden portion 668 provides as close to no heat (0 W/m) as possibleto overburden 370. Some heat, however, may be used to maintain fluidsproduced through opening 252 in a vapor phase in overburden 370.

In certain embodiments, hot portion 664 of heat source 210 heatshydrocarbons to high enough temperatures to result in coke 670 formingin hydrocarbon layer 254. Coke 670 may occur in an area surroundingopening 252. Warm portion 666 may be operated at lower heat outputs sothat coke does not form at or near the warm portion of heat source 210.Coke 670 may extend radially from opening 252 as heat from heat source210 transfers outward from the opening. At a certain distance, however,coke 670 no longer forms because temperatures in hydrocarbon layer 254at the certain distance will not reach coking temperatures. The distanceat which no coke forms is a function of heat output (W/m from heatsource 210), type of formation, hydrocarbon content in the formation,and/or other conditions in the formation.

The formation of coke 670 inhibits fluid flow into opening 252 throughthe coking. Fluids in the formation may, however, be produced throughopening 252 at the heel of heat source 210 (for example, at warm portion666 of the heat source) where there is little or no coke formation. Thelower temperatures at the heel of heat source 210 reduce the possibilityof increased cracking of formation fluids produced through the heel.Fluids may flow in a horizontal direction through the formation moreeasily than in a vertical direction. Typically, horizontal permeabilityin a relatively permeable formation is approximately 5 to 10 timesgreater than vertical permeability. Thus, fluids flow along the lengthof heat source 210 in a substantially horizontal direction. Producingformation fluids through opening 252 is possible at earlier times thanproducing fluids through production wells in hydrocarbon layer 254. Theearlier production times through opening 252 is possible becausetemperatures near the opening increase faster than temperatures furtheraway due to conduction of heat from heat source 210 through hydrocarbonlayer 254. Early production of formation fluids may be used to maintainlower pressures in hydrocarbon layer 254 during start-up heating of theformation. Start-up heating of the formation is the time of heatingbefore production begins at production wells in the formation. Lowerpressures in the formation may increase liquid production from theformation. In addition, producing formation fluids through opening 252may reduce the number of production wells needed in the formation.

In some embodiments, a temperature limited heater is used to heat asurface pipeline such as a sulfur transfer pipeline. For example, asurface sulfur pipeline may be heated to a temperature of about 100° C.,about 110° C., or about 130° C. to inhibit solidification of fluids inthe pipeline. Higher temperatures in the pipeline (for example, aboveabout 130° C.) may induce undesirable degradation of fluids in thepipeline.

In some embodiments, a temperature limited heater positioned in awellbore may heat steam that is provided to the wellbore. The heatedsteam may be introduced into a portion of a formation. In certainembodiments, the heated steam may be used as a heat transfer fluid toheat a portion of a formation. In an embodiment, the temperature limitedheater includes ferromagnetic material with a selected Curietemperature. The use of a temperature limited heater may inhibit atemperature of the heater from increasing beyond a maximum selectedtemperature (for example, at or about the Curie temperature). Limitingthe temperature of the heater may inhibit potential burnout of theheater. The maximum selected temperature may be a temperature selectedto heat the steam to above or near 100% saturation conditions,superheated conditions, or supercritical conditions. Using a temperaturelimited heater to heat the steam may inhibit overheating of the steam inthe wellbore. Steam introduced into a formation may be used forsynthesis gas production, to heat the hydrocarbon containing formation,to carry chemicals into the formation, to extract chemicals from theformation, and/or to control heating of the formation.

A portion of a formation where steam is introduced or that is heatedwith steam may be at significant depths below the surface (for example,greater than about 1000 m, about 2500, or about 5000 m below thesurface). If steam is heated at the surface of a formation andintroduced to the formation through a wellbore, a quality of the heatedsteam provided to the wellbore at the surface may have to be relativelyhigh to accommodate heat losses to a wellbore casing and/or theoverburden as the steam travels down the wellbore. Heating the steam inthe wellbore may allow the quality of the steam to be significantlyimproved before the steam is provided to the formation. A temperaturelimited heater positioned in a lower section of the overburden and/oradjacent to a target zone of the formation may be used to controllablyheat steam to improve the quality of the steam injected into theformation and/or inhibit condensation along the length of the heater. Incertain embodiments, the temperature limited heater improves the qualityof the steam injected and/or inhibits condensation in the wellbore forlong steam injection wellbores (especially for long horizontal steaminjection wellbores).

A temperature limited heater positioned in a wellbore may be used toheat the steam to above or near 100% saturation conditions orsuperheated conditions. In some embodiments, a temperature limitedheater may heat the steam so that the steam is above or nearsupercritical conditions. The static head of fluid above the temperaturelimited heater may facilitate producing 100% saturation, superheated,and/or supercritical conditions in the steam. Supercritical or nearsupercritical steam may be used to strip hydrocarbon material and/orother materials from the formation. In certain embodiments, steamintroduced into a formation may have a high density (for example, aspecific gravity of about 0.8 or above). Increasing the density of thesteam may improve the ability of the steam to strip hydrocarbon materialand/or other materials from the formation.

Non-restrictive examples are set forth below.

FIGS. 128-135 depict experimental data for temperature limited heaters.FIG. 128 depicts electrical resistance (Ω) versus temperature (° C.) atvarious applied electrical currents for a 446 stainless steel rod with adiameter of 2.5 cm and a 410 stainless steel rod with a diameter of 2.5cm. Both rods had a length of 1.8 m. Curves 672-678 depict resistanceprofiles as a function of temperature for the 446 stainless steel rod at440 amps AC (curve 672), 450 amps AC (curve 674), 500 amps AC (curve676), and 10 amps DC (curve 678). Curves 680-686 depict resistanceprofiles as a function of temperature for the 410 stainless steel rod at400 amps AC (curve 680), 450 amps AC (curve 682), 500 amps AC (curve684), 10 amps DC (curve 686). For both rods, the resistance graduallyincreased with temperature until the Curie temperature was reached. Atthe Curie temperature, the resistance fell sharply. Above the Curietemperature, the resistance decreased slightly with increasingtemperature. Both rods show a trend of decreasing resistance withincreasing AC current. Accordingly, the turndown ratio decreased withincreasing current. Thus, the rods provide a reduced amount of heat nearand above the Curie temperature of the rods. In contrast, the resistancegradually increased with temperature through the Curie temperature withthe applied DC current.

FIG. 129 shows resistance profiles as a function of temperature atvarious applied electrical currents for a copper rod contained in aconduit of Sumitomo HCM12A (a high strength 410 stainless steel). TheSumitomo conduit had a diameter of 5.1 cm, a length of 1.8 m, and a wallthickness of about 0.1 cm. Curves 688-698 show that at all appliedcurrents (688: 300 amps AC; 690: 350 amps AC; 692: 400 amps AC; 694: 450amps AC; 696: 500 amps AC; 698: 550 amps AC), resistance increasedgradually with temperature until the Curie temperature was reached. Atthe Curie temperature, the resistance fell sharply. As the currentincreased, the resistance decreased, resulting in a smaller turndownratio.

FIG. 130 depicts electrical resistance versus temperature at variousapplied electrical currents for a temperature limited heater. Thetemperature limited heater included a 4/0 MGT-1000 furnace cable insidean outer conductor of ¾″ Schedule 80 Sandvik (Sweden) 4C54 (446stainless steel) with a 0.30 cm thick copper sheath welded onto theoutside of the Sandvik 4C54 and a length of 1.8 m. Curves 700 through718 show resistance profiles as a function of temperature for AC appliedcurrents ranging from 40 amps to 500 amps (700: 40 amps; 702: 80 amps;704: 120 amps; 706: 160 amps; 708: 250 amps; 710: 300 amps; 712: 350amps; 714: 400 amps; 716: 450 amps; 718: 500 amps). FIG. 131 depicts theraw data for curve 714. FIG. 132 depicts the data for selected curves710, 712, 714, 716, 718, and 720. At lower currents (below 250 amps),the resistance increased with increasing temperature up to the Curietemperature. At the Curie temperature, the resistance fell sharply. Athigher currents (above 250 amps), the resistance decreased slightly withincreasing temperature up to the Curie temperature. At the Curietemperature, the resistance fell sharply. Curve 720 shows resistance foran applied DC electrical current of 10 amps. Curve 720 shows a steadyincrease in resistance with increasing temperature, with little or nodeviation at the Curie temperature.

FIG. 133 depicts power versus temperature at various applied electricalcurrents for a temperature limited heater. The temperature limitedheater included a 4/0 MGT-1000 furnace cable inside an outer conductorof ¾″ Schedule 80 Sandvik (Sweden) 4C54 (446 stainless steel) with a0.30 cm thick copper sheath welded onto the outside of the Sandvik 4C54and a length of 1.8 m. Curves 722-730 depict power versus temperaturefor AC applied currents of 300 amps to 500 amps (722: 300 amps; 724: 350amps; 726: 400 amps; 728: 450 amps; 730: 500 amps). Increasing thetemperature gradually decreased the power until the Curie temperaturewas reached. At the Curie temperature, the power decreased rapidly.

FIG. 134 depicts electrical resistance (mΩ) versus temperature (° C.) atvarious applied electrical currents for a temperature limited heater.The temperature limited heater included a copper rod with a diameter of1.3 cm inside an outer conductor of 2.5 cm Schedule 80 410 stainlesssteel pipe with a 0.15 cm thick copper Everdur™ (DuPont Engineering,Wilmington, Del.) welded sheath over the 410 stainless steel pipe and alength of 1.8 m. Curves 732-742 show resistance profiles as a functionof temperature for AC applied currents ranging from 300 amps to 550 amps(732: 300 amps; 734: 350 amps; 736: 400 amps; 738: 450 amps; 740: 500amps; 742: 550 amps). For these AC applied currents, the resistancegradually increases with increasing temperature up to the Curietemperature. At the Curie temperature, the resistance falls sharply. Incontrast, curve 744 shows resistance for an applied DC electricalcurrent of 10 amps. This resistance shows a steady increase withincreasing temperature, and little or no deviation at the Curietemperature.

FIG. 135 depicts data of electrical resistance (mΩ) versus temperature(° C.) for a solid 2.54 cm diameter, 1.8 m long 410 stainless steel rodat various applied electrical currents. Curves 746, 748, 750, 752, and754 depict resistance profiles as a function of temperature for the 410stainless steel rod at 40 amps AC (curve 752), 70 amps AC (curve 754),140 amps AC (curve 746), 230 amps AC (curve 748), and 10 amps DC (curve750). For the applied AC currents of 140 amps and 230 amps, theresistance increased gradually with increasing temperature until theCurie temperature was reached. At the Curie temperature, the resistancefell sharply. In contrast, the resistance showed a gradual increase withtemperature through the Curie temperature for an applied DC current.

FIG. 136 depicts data of electrical resistance (milliohms (mΩ)) versustemperature (° C.) for a composite 0.75 inches (2.54 cm) diameter, 6foot (1.8 m) long Alloy 42-6 rod with a 0.375 inch diameter copper core(the rod has an outside diameter to copper diameter ratio of 2:1) atvarious applied electrical currents. Curves 756, 758, 760, 762, 764,766, 768, and 770 depict resistance profiles as a function oftemperature for the copper cored alloy 42-6 rod at 300 A AC (curve 756),350 A AC (curve 758), 400 A AC (curve 760), 450 A AC (curve 762), 500 AAC (curve 764), 550 A AC (curve 766), 600 A AC (curve 768), and 10 A DC(curve 770). For the applied AC currents, the resistance decreasedgradually with increasing temperature until the Curie temperature wasreached. As the temperature approaches the Curie temperature, theresistance decreased more sharply. In contrast, the resistance showed agradual increase with temperature for an applied DC current.

FIG. 137 depicts data of power output (watts per foot (W/ft.)) versustemperature (° C.) for a composite 10.75 inches (1.9 cm) diameter, 6foot (1.8 m) long Alloy 42-6 rod with a 0.375 inch diameter copper core(the rod has an outside diameter to copper diameter ratio of 2:1) atvarious applied electrical currents. Curves 772, 774, 776, 778, 780,782, 784, and 786 depict power as a function of temperature for thecopper cored alloy 42-6 rod at 300 A AC (curve 772), 350 A AC (curve774), 400 A AC (curve 776), 450 A AC (curve 778), 500 A AC (curve 780),550 A AC (curve 782), 600 A AC (curve 784), and 10 A DC (curve 786). Forthe applied AC currents, the power output decreased gradually withincreasing temperature until the Curie temperature was reached. As thetemperature approaches the Curie temperature, the power output decreasedmore sharply. In contrast, the power output showed a relatively flatprofile with temperature for an applied DC current.

FIG. 138 depicts data of electrical resistance (milliohms (mΩ)) versustemperature (° C.) for a composite 0.75″ diameter, 6 foot long Alloy 52rod with a 0.375″ diameter copper core at various applied electricalcurrents. Curves 788, 790, 792, 794, and 795 depict resistance profilesas a function of temperature for the copper cored Alloy 52 rod at 300 AAC (curve 788), 400 A AC (curve 790), 500 A AC (curve 792), 600 A AC(curve 794), and 10 A DC (curve 795). For the applied AC currents, theresistance increased gradually with increasing temperature until around320° C. After 320° C., the resistance began to decrease gradually,decreasing more sharply as the temperature approached the Curietemperature. At the Curie temperature, the AC resistance decreased verysharply. In contrast, the resistance showed a gradual increase withtemperature for an applied DC current. The turndown ratio for the 400 Aapplied AC current (curve 790) was 2.8.

FIG. 139 depicts data of power output (watts per foot (W/ft.)) versustemperature (° C.) for a composite 10.75″ diameter, 6 foot long Alloy 52rod with a 0.375″ diameter copper core at various applied electricalcurrents. Curves 796, 798, 800, and 802 depict power as a function oftemperature for the copper cored Alloy 52 rod at 300 A AC (curve 796),400 A AC (curve 798), 500 A AC (curve 800), and 600 A AC (curve 802).For the applied AC currents, the power output increased gradually withincreasing temperature until around 320° C. After 320° C., the poweroutput began to decrease gradually, decreasing more sharply as thetemperature approached the Curie temperature. At the Curie temperature,the power output decreased very sharply.

FIG. 140 depicts data for values of skin depth (cm) versus temperature(° C.) for a solid 2.54 cm diameter, 1.8 m long 410 stainless steel rodat various applied AC electrical currents. The skin depth was calculatedusing EQN. 6:

δ=R ₁ −R ₁×(1−(1/R _(AC) /R _(DC))^(1/2);  (6)

where δ is the skin depth, R₁ is the radius of the cylinder, R_(AC) isthe AC resistance, and R_(DC) is the DC resistance. In FIG. 140, curves804-822 show skin depth profiles as a function of temperature forapplied AC electrical currents over a range of 50 amps to 500 amps (804:50 amps; 806: 100 amps; 808: 150 amps; 810: 200 amps; 812: 250 amps;814: 300 amps; 816: 350 amps; 818: 400 amps; 820: 450 amps; 822: 500amps). For each applied AC electrical current, the skin depth graduallyincreased with increasing temperature up to the Curie temperature. Atthe Curie temperature, the skin depth increased sharply.

FIG. 141 depicts temperature (° C.) versus time (hrs) for a temperaturelimited heater. The temperature limited heater was a 1.83 m long heaterthat included a copper rod with a diameter of 1.3 cm inside a 2.5 cmSchedule XXH 410 stainless steel pipe and a 0.325 cm copper sheath. Theheater was placed in an oven for heating. Alternating current wasapplied to the heater when the heater was in the oven. The current wasincreased over two hours and reached a relatively constant value of 400amps for the remainder of the time. Temperature of the stainless steelpipe was measured at three points at 0.46 m intervals along the lengthof the heater. Curve 824 depicts the temperature of the pipe at a point0.46 m inside the oven and closest to the lead-in portion of the heater.Curve 826 depicts the temperature of the pipe at a point 0.46 m from theend of the pipe and furthest from the lead-in portion of the heater.Curve 828 depicts the temperature of the pipe at about a center point ofthe heater. The point at the center of the heater was further enclosedin a 0.3 m section of 2.5 cm thick Fiberfrax® (Unifrax Corp., NiagaraFalls, N.Y.) insulation. The insulation was used to create a low thermalconductivity section on the heater (a section where heat transfer to thesurroundings is slowed or inhibited (a “hot spot”)). The temperature ofthe heater increased with time as shown by curves 828, 826, and 824.Curves 828, 826, and 824 show that the temperature of the heaterincreased to about the same value for all three points along the lengthof the heater. The resulting temperatures were substantially independentof the added Fiberfrax® insulation. Thus, the operating temperatures ofthe temperature limited heater were substantially the same despite thedifferences in thermal load (due to the insulation) at each of the threepoints along the length of the heater. Thus, the temperature limitedheater did not exceed the selected temperature limit in the presence ofa low thermal conductivity section.

FIG. 142 depicts temperature (° C.) versus log time (hrs) data for a 2.5cm solid 410 stainless steel rod and a 2.5 cm solid 304 stainless steelrod. At a constant applied AC electrical current, the temperature ofeach rod increased with time. Curve 830 shows data for a thermocoupleplaced on an outer surface of the 304 stainless steel rod and under alayer of insulation. Curve 832 shows data for a thermocouple placed onan outer surface of the 304 stainless steel rod without a layer ofinsulation. Curve 834 shows data for a thermocouple placed on an outersurface of the 410 stainless steel rod and under a layer of insulation.Curve 836 shows data for a thermocouple placed on an outer surface ofthe 410 stainless steel rod without a layer of insulation. A comparisonof the curves shows that the temperature of the 304 stainless steel rod(curves 830 and 832) increased more rapidly than the temperature of the410 stainless steel rod (curves 834 and 836). The temperature of the 304stainless steel rod (curves 830 and 832) also reached a higher valuethan the temperature of the 410 stainless steel rod (curves 834 and836). The temperature difference between the non-insulated section ofthe 410 stainless steel rod (curve 836) and the insulated section of the410 stainless steel rod (curve 834) was less than the temperaturedifference between the non-insulated section of the 304 stainless steelrod (curve 832) and the insulated section of the 304 stainless steel rod(curve 830). The temperature of the 304 stainless steel rod wasincreasing at the termination of the experiment (curves 830 and 832)while the temperature of the 410 stainless steel rod had leveled out(curves 834 and 836). Thus, the 410 stainless steel rod (the temperaturelimited heater) provided better temperature control than the 304stainless steel rod (the non-temperature limited heater) in the presenceof varying thermal loads (due to the insulation).

A 6 foot temperature limited heater element was placed in a 6 foot 347Hstainless steel canister. The heater element was connected to thecanister in a series configuration. The heater element and canister wereplaced in an oven. The oven was used to raise the temperature of theheater element and the canister. At varying temperatures, a series ofelectrical currents were passed through the heater element and returnedthrough the canister. The resistance of the heater element and the powerfactor of the heater element were determined from measurements duringpassing of the electrical currents.

FIG. 143 depicts experimentally measured resistance versus temperatureat several currents for a temperature limited heater with a copper core,a carbon steel ferromagnetic conductor, and a 347H stainless steelsupport member. The ferromagnetic conductor was a low-carbon steel witha Curie temperature of 770° C. The ferromagnetic conductor wassandwiched between the copper core and the 347H support member. Thecopper core had a diameter of 0.5″. The ferromagnetic conductor had anoutside diameter of 0.765″. The support member had an outside diameterof 1.05″. The canister was a 3″ Schedule 160 347H stainless steelcanister.

Data 838 depicts resistance versus temperature for 300A at 60 Hz ACapplied current. Data 840 depicts resistance versus temperature for 400Aat 60 Hz AC applied current. Data 842 depicts resistance versustemperature for 500A at 60 Hz AC applied current. Curve 844 depictsresistance versus temperature for 10A DC applied current. The resistanceversus temperature data indicates that the AC resistance of thetemperature limited heater linearly increased up to a temperature nearthe Curie temperature of the ferromagnetic conductor. Near the Curietemperature, the AC resistance decreased rapidly until the AC resistanceequaled the DC resistance above the Curie temperature. The lineardependence of the AC resistance below the Curie temperature at leastpartially reflects the linear dependence of the AC resistance of 347H atthese temperatures. Thus, the linear dependence of the AC resistancebelow the Curie temperature indicates that the majority of the currentis flowing through the 347H support member at these temperatures.

FIG. 144 depicts experimentally measured resistance versus temperaturedata at several currents for a temperature limited heater with a coppercore, an iron-cobalt ferromagnetic conductor, and a 347H stainless steelsupport member. The iron-cobalt ferromagnetic conductor was aniron-cobalt conductor with 6% cobalt by weight and a Curie temperatureof 834° C. The ferromagnetic conductor was sandwiched between the coppercore and the 347H support member. The copper core had a diameter of0.465″. The ferromagnetic conductor had an outside diameter of 0.765″.The support member had an outside diameter of 1.05″. The canister was a3″ Schedule 160 347H stainless steel canister.

Data 846 depicts resistance versus temperature for 100A at 60 Hz ACapplied current. Data 848 depicts resistance versus temperature for 400Aat 60 Hz AC applied current. Curve 850 depicts resistance versustemperature for 10A DC. The AC resistance of this temperature limitedheater turned down at a higher temperature than the previous temperaturelimited heater. This was due to the added cobalt increasing the Curietemperature of the ferromagnetic conductor. The AC resistance wassubstantially the same as the AC resistance of a tube of 347H steelhaving the dimensions of the support member. This indicates that themajority of the current is flowing through the 347H support member atthese temperatures. The resistance curves in FIG. 144 are generally thesame shape as the resistance curves in FIG. 143.

FIG. 145 depicts experimentally measured power factor versus temperatureat two AC currents for the temperature limited heater with the coppercore, the iron-cobalt ferromagnetic conductor, and the 347H stainlesssteel support member. Curve 852 depicts power factor versus temperaturefor 100A at 60 Hz AC applied current. Curve 854 depicts power factorversus temperature for 400A at 60 Hz AC applied current. The powerfactor was close to unity (1) except for the region around the Curietemperature. In the region around the Curie temperature, the non-linearmagnetic properties and a larger portion of the current flowing throughthe ferromagnetic conductor produce inductive effects and distortion inthe heater that lowers the power factor. FIG. 145 shows that the minimumvalue of the power factor for this heater remained above 0.85 at alltemperatures in the experiment. Because only portions of the temperaturelimited heater used to heat a subsurface formation may be at the Curietemperature at any given point in time and the power factor for theseportions does not go below 0.85 during use, the power factor for theentire temperature limited heater would remain above 0.85 (for example,above 0.9 or above 0.95) during use.

From the data in the experiments for the temperature limited heater withthe copper core, the iron-cobalt ferromagnetic conductor, and the 347Hstainless steel support member, the turndown ratio was calculated as afunction of the maximum power delivered by the temperature limitedheater. The results of these calculations are depicted in FIG. 146. Thecurve in FIG. 146 shows that the turndown ratio remains above 2 forheater powers up to approximately 2000 W/m. This curve is used todetermine the ability of a heater to effectively provide heat output ina sustainable manner. A temperature limited heater with the curvesimilar to the curve in FIG. 146 would be able to provide sufficientheat output while maintaining temperature limiting properties thatinhibit the heater from overheating or malfunctioning.

A theoretical model has been used to predict the experimental results.The theoretical model is based on an analytical solution for the ACresistance of a composite conductor. The composite conductor has a thinlayer of ferromagnetic material, with a relative magnetic permeabilityμ₂/μ₀>>1, sandwiched between two non-ferromagnetic materials, whoserelative magnetic permeabilities, μ₁/μ₀ and μ₃/μ₀, are close to unityand within which skin effects are negligible. An assumption in the modelis that the ferromagnetic material is treated as linear. Also, the wayin which the relative magnetic permeability, μ₂/μ₀, is extracted frommagnetic data for use in the model is far from rigorous.

In the theoretical model, the three conductors, from innermost tooutermost, have radii a<b<c with electrical conductivities σ₁, σ₂, andσ₃, respectively. The electric and magnetic fields everywhere are of theharmonic form:

Electric Fields:

E ₁(r,t)=E _(S1)(r)e ^(jωt) ;r<a;  (7)

E ₂(r,t)=E _(S2)(r)e ^(jωt) ;a<r<b; and  (8)

E ₃(r,t)=E _(S3)(r)e ^(jωt) ;b<r<c.  (9)

Magnetic Fields:

H ₁(r,t)=H _(S1)(r)e ^(jωt) ;r<a;  (10)

H ₂(r,t)=H _(S2)(r)e ^(jωt) ;a<r<b; and  (11)

H ₃(r,t)=H _(S3)(r)e _(jωt) ;b<r<c.  (12)

The boundary conditions satisfied at the interfaces are:

E _(S1)(a)=E _(S2)(a);H _(S1)(a)=H _(S2)(a); and  (13)

E _(S2)(b)=E _(S3)(b);H _(S2)(b)=H _(S3)(b).  (14)

Current flows uniformly in the non-Curie conductors, so that:

H _(S1)(a)=_(S1)(a)(a/2)=1/2aσ ₁ E _(S1)(a); and  (15)

I−2πbH _(S3)(b)=π(c ² −b ²)J _(S3)(b)=π(c ² −b ²)σ₃ E _(S3)(b).  (16)

I denotes the total current flowing through the composite conductorsample. EQNS. 13 and 14 are used to express EQNS. 15 and 16 in terms ofboundary conditions pertaining to material 2 (the ferromagneticmaterial). This yields:

$\begin{matrix}{{{H_{S\; 2}(a)} = {\frac{1}{2}a\; \sigma_{1}{E_{S\; 2}(a)}}};{and}} & (17) \\{I = {{2\pi \; b\; {H_{S\; 2}(b)}} + {{\pi \left( {c^{2} - b^{2}} \right)}\sigma_{3}{{E_{S\; 2}(b)}.}}}} & (18)\end{matrix}$

E_(S2)(r) satisfies the equation:

$\begin{matrix}{{{{\frac{1}{r}\frac{}{r}\left( {r\frac{E_{S\; 2}}{r}} \right)} - {C^{2}E_{S\; 2}}} = 0},} & (19)\end{matrix}$

with

C ² =jωμ ₂σ₂.  (20)

Using the fact that:

$\begin{matrix}{{{H_{S\; 2}(r)} = {\frac{j}{\mu_{2}\omega}\frac{E_{S\; 2}}{r}}};} & (21)\end{matrix}$

the boundary conditions in EQNS. 17 and 18 are expressed in terms ofE_(S2) and its derivatives as follows:

$\begin{matrix}{{\left. {\frac{j}{\mu_{2}\omega}\frac{E_{S\; 2}}{r}} \right|_{a} = {\frac{1}{2}a\; \sigma_{1}{E_{S\; 2}(a)}}};{and}} & (22) \\{I = \left. {2\pi \; b\frac{j}{\mu_{2}\omega}\frac{E_{S\; 2}}{r}} \middle| {}_{b}{{+ {\pi \left( {c^{2} - b^{2}} \right)}}\sigma_{3}{{E_{S\; 2}(b)}.}} \right.} & (23)\end{matrix}$

The non-dimensional coordinate, x, is introduced via the equation:

$\begin{matrix}{r = {\frac{1}{2}\left( {a + b} \right){\left\{ {1 + {\frac{b - a}{a + b}\chi}} \right\}.}}} & (24)\end{matrix}$

χ is −1 for r=a, and χ is 1 for r=b. EQN. 19 is written in terms of χas:

$\begin{matrix}{{{{\left( {1 + {\beta\chi}} \right)^{- 1}\frac{}{\chi}\left\{ {\left( {1 + {\beta\chi}} \right)\frac{E_{S\; 2}}{\chi}} \right\}} - {\alpha^{2}\chi}} = 0},} & (25)\end{matrix}$

with

$\begin{matrix}{{\alpha = {\frac{1}{2}\left( {b - a} \right)C}};{and}} & (26) \\{\beta = {\left( {b - a} \right)/{\left( {b + a} \right).}}} & (27)\end{matrix}$

α can be expressed as:

α=α_(R)(1−i),  (28)

with

$\begin{matrix}{\alpha_{R}^{2} = {{\frac{1}{8}\left( {b - a} \right)^{2}\mu_{2}\sigma_{2}\omega} = {\frac{1}{4}{\left( {b - a} \right)^{2}/{\delta^{2}.}}}}} & (29)\end{matrix}$

EQNS. 22 and 23 are expressed as:

$\begin{matrix}{{\left. \frac{}{\chi} \middle| {}_{- 1}E_{a} \right. = {{- j}\; \gamma_{a}E_{a}}};{and}} & (30) \\{\left. \frac{}{\chi} \middle| {}_{1}E_{b} \right. = {{{j\gamma}_{b}E_{b}} - {j\; {\overset{\sim}{I}.}}}} & (31)\end{matrix}$

In EQNS. 30 and 31, the short-hand notation E_(a) and E_(b) is used forE_(S2)(a) and E_(S2)(b), respectively, and the dimensionless parametersγ_(a) and γ_(b) normalized current Ĩ have been introduced. Thesequantities are given by:

$\begin{matrix}{{{\gamma_{a} = {\frac{1}{4}{a\left( {b - a} \right)}\omega \; \mu_{2}\sigma_{1}}};}{{\gamma_{b} = {\frac{1}{2}\left( {c^{2} - b^{2}} \right)\left( {b - a} \right)\omega \; \mu_{2}{\sigma_{3}/b}}};{and}}} & (32) \\{\overset{\sim}{I} = {\frac{1}{2}\left( {b - a} \right)\omega \; \mu_{2}{I/{\left( {2\pi \; b} \right).}}}} & (33)\end{matrix}$

EQN. 32 can be expressed in terms of dimensionless parameters by usingEQN. 29. The results are:

γ_(a)=2(σ₁σ₂)aα _(R) ²/(b−a);γ_(b)=4(σ₃/σ₂)(c ² −b ²)α_(R) ²/{b(b−a)}.  (34)

An alternative way of writing EQN. 34 is:

γ_(a)=(σ₁σ₂)aα _(R)/δ;γ_(b)=2(σ₃/σ₂)(c ² −b ²)α_(R)/(δb).  (35)

The mean power per unit length generated in the material is given by:

$\begin{matrix}\begin{matrix}{P = {\frac{1}{2}\left\{ {{\sigma_{1}\pi \; a^{2}{E_{a}}^{2}} + {2{\pi\sigma}_{2}{\int_{a}^{b}\ {{{rr}}{{E_{S\; 2}(r)}}^{2}}}} + {\sigma_{3}{\pi \left( {c^{2} - b^{2}} \right)}{E_{b}}^{2}}} \right\}}} \\{= {\frac{1}{2}{\begin{Bmatrix}{{\sigma_{1}\pi \; a^{2}{E_{a}}^{2}} + {\frac{1}{2}{\pi \left( {b^{2} - a^{2}} \right)}\sigma_{2}{\int_{- 1}^{1}\ {{\chi}\left\{ {1 + {\beta\chi}} \right\} {{E_{S\; 2}(r)}}^{2}}}} +} \\{\sigma_{3}{\pi \left( {c^{2} - b^{2}} \right)}{E_{b}}^{2}}\end{Bmatrix}.}}}\end{matrix} & (36)\end{matrix}$

The AC resistance is then:

R _(AC) =P/(1/2|I| ²)  (37)

To obtain an approximate solution of EQN. 25, 13 is assumed to be smallenough to be neglected in EQN. 25. This assumption holds if thethickness of the ferromagnetic material (material 2) is much less thanits mean radius. The general solution then takes the form:

E _(S2) =Ae ^(αx) +Be ^(−αx).  (38)

Then:

E _(a) =Ae ^(−α) +Be ^(α); and  (39)

E _(b) =Ae ^(α) +Be ^(−α).  (40)

Substituting EQNS. 38-40 into EQNS. 30 and 31 yields the following setof equations for A and B:

α(Ae ^(−α) −Be ^(α))=−jγ _(a)(Ae ^(−α) +Be ^(α)); and  (41)

α(Ae ^(α) −Be ^(−α))=jγ _(b)(Ae ^(α) +Be ^(−α) a)−jĨ.  (42)

Rearranging EQN. 41 obtains an expression for B in terms of A:

$\begin{matrix}{B = {\frac{\alpha + {j\; \gamma_{a}}}{\alpha - {j\; \gamma_{a}}}^{{- 2}\alpha}{A.}}} & (43)\end{matrix}$

This may be written as:

$\begin{matrix}{{B = {\frac{\alpha_{R} - {j\; \gamma_{a}^{+}}}{\alpha_{R} + {j\; \gamma_{a}^{-}}}^{{{- 2}\alpha_{R}} + {2\; \alpha_{R}}}A}},} & (44)\end{matrix}$

with

γ₂ ^(±)=γ_(a)±α_(R).  (45)

If

A=|A|exp(iφ _(A))  (46)

and everything is referred back to the phase of A, then:

φ_(A)=0.  (47)

From EQN. 44:

B=|B|exp(iφ _(B)), with  (48)

|B|=(Γ₊/Γ⁻)exp(−2α_(R))|A|; and  (49)

φ_(B)=2α_(R)−φ₊−φ⁻; where  (50)

Γ_(±)={α_(R) ²+(γ_(a) ^(±))²}^(0.5); and  (51)

φ_(±)=tan⁻¹{φ_(±)/α_(R)}.  (52)

Then:

E _(a) =|A|exp(−α_(R) +iα _(R))+|B|exp{α_(R) +i(φ_(B)−α_(R))}; and  (53)

E _(a) =|A|exp(α_(R) −iα _(R))+|B|exp{−α_(R) +i(φ_(B)+α_(R))}.  (54)

Hence:

Re[E _(a)]=|A|exp(−α_(R))cos(α_(R))+|B|exp(α_(R))cos(φ_(B)−α_(R));  (55A)

Im[E _(a)]=|A|exp(−α_(R))sin(α_(R))+|B|exp(α_(R))sin(φ_(B)−α_(R));  (55B)

Re[E _(b) ]=|A|exp(α_(R))cos(α_(R))+|B|exp(−α_(R))cos(φ_(B)+α_(R));and  (55C)

Im[E _(a)]=−|A|exp(α_(R))sin(α_(R))+|B|exp(−α_(R))sin(φ_(B)+α_(R));  (55D)

The ratio of absolute values of currents flowing through the center andouter conductors is then given by:

$\begin{matrix}{\frac{I_{1}}{I_{3}} = {\frac{a^{2}\sigma_{1}}{\left( {c^{2} - b^{2}} \right)\sigma_{3}}{\sqrt{\frac{{{Re}^{2}\left\lbrack E_{a} \right\rbrack} + {{Im}^{2}\left\lbrack E_{a} \right\rbrack}}{{{Re}^{2}\left\lbrack E_{b} \right\rbrack} + {{Im}^{2}\left\lbrack E_{b} \right\rbrack}}}.}}} & (56)\end{matrix}$

The total current flowing through the center conductor is given by:

I ₂=σ₂π(b ² −a ²)(A+B)sin h(α)/α.  (57)

Now:

sin h(α)/α=(1+i){sin h(α_(R))cos(α_(R))−i cosh(α_(R))sin(α_(R))}/(2α_(R))=(S ⁺ +S ⁻ i), with  (58)

S ^(±)={sin h(α_(R))cos(α_(R)±cos h(α_(R))sin(α_(R))}/(4α_(R)).  (59)

Hence:

Re[I ₂]=σ₂π(b ² −a ²){{|A|+|B|cos(φ_(B))}S ⁺ −|B|sin(φ_(B))S ⁻};and  (60)

Im[I ₂]=σ₂π(b ² −a ²){{|A|+|B|cos(φ_(B))}S ⁻ −|B|sin(φ_(B))S ⁺}.  (61)

Root-mean-square current is therefore given by:

$\begin{matrix}{I_{rms}^{2} = {\frac{1}{2}{\left\{ {\left( {{{Re}\left\lbrack I_{1} \right\rbrack} + {{Re}\left\lbrack I_{2} \right\rbrack} + {{Re}\left\lbrack I_{3} \right\rbrack}} \right)^{2} + \left( {{{Im}\left\lbrack I_{1} \right\rbrack} + {{Im}\left\lbrack I_{2} \right\rbrack} + {{Im}\left\lbrack I_{3} \right\rbrack}} \right)^{2}} \right\}.}}} & (62)\end{matrix}$

Furthermore, EQNS. 40-42 are used to evaluate the second term on theright-hand side of EQN. 29 (neglecting the term in β). The result is:

$\begin{matrix}{P = {\frac{1}{2}{\left\{ {{\sigma_{1}\pi \; \alpha^{2}{E_{a}}^{2}} + {{\pi \left( {c^{2} - b^{2}} \right)}\sigma_{3}{E_{b}}^{2}} + {{\pi \left( {b^{2} - a^{2}} \right)}{\sigma_{2}\left\lbrack {{\left( {{A}^{2} + {B^{2}}} \right){{\sinh \left( {2\sigma_{R}} \right)}/\left( {2\alpha_{R}} \right)}} + {2{A}{B}{{\sin \left( {\varphi_{B} + {2\alpha_{R}}} \right)}/\left( {\varphi_{B} + {2\alpha_{R}}} \right)}}} \right\rbrack}}} \right\}.}}} & (63)\end{matrix}$

Dividing EQN. 63 by EQN. 62 yields an expression for the AC resistance(cf. EQN. 37).

Given values for the dimensions a, b and c, and σ₁, σ₂ and σ₃, which areknown functions of temperature, and assuming a value for the relativemagnetic permeability of the ferromagnetic material (material 2), orequivalently, the skin depth δ, A=1 can be set and the AC resistance perunit length R_(AC) can be calculated. The ratio of the root-mean squarecurrent flowing through the inner conductor (material 1) and theferromagnetic material (material 2) to the total can also be calculated.For a given total RMS current, then, the RMS current flowing throughmaterials 1 and 2 can be calculated, which gives the magnetic field atthe surface of material 2. Using magnetic data for material 2, a valuefor μ₂/μ₀ can be deduced and hence a value for δ can be deduced.Plotting this skin depth against the original skin depth produces a pairof curves that cross at the true δ.

Magnetic data was obtained for carbon steel as a ferromagnetic material.B versus H curves, and hence relative permeabilities, were obtained fromthe magnetic data at various temperatures up to 1100° F. and magneticfields up to 2000e (oersteds). A correlation was found that fitted thedata well through the maximum permeability and beyond. FIG. 147 depictsexamples of relative magnetic permeability (y-axis) versus magneticfield (Oe) for both the found correlations and raw data for carbonsteel. Data 856 is raw data for carbon steel at 400° F. Data 858 is rawdata for carbon steel at 1000° F. Curve 860 is the found correlation forcarbon steel at 400° F. Curve 862 is the found correlation for carbonsteel at 1000° F.

For the dimensions and materials of the copper/carbon steel/347H heaterelement in the experiments above, the theoretical calculations describedabove were carried out to calculate magnetic field at the outer surfaceof the carbon steel as a function of skin depth. Results of thetheoretical calculations were presented on the same plot as skin depthversus magnetic field from the correlations applied to the magnetic datafrom FIG. 147. The theoretical calculations and correlations were doneat four temperatures (200° F., 500° F., 800° F., and 1100° F.) and fivetotal root-mean-square (RMS) currents (100 A, 200 A, 300 A, 400 A, and500 A).

FIG. 148 shows the resulting plots of skin depth versus magnetic fieldfor all four temperatures and 400 A current. Curve 864 is thecorrelation from magnetic data at 200° F. Curve 866 is the correlationfrom magnetic data at 500° F. Curve 868 is the correlation from magneticdata at 800° F. Curve 870 is the correlation from magnetic data at 1100°F. Curve 872 is the theoretical calculation at the outer surface of thecarbon steel as a function of skin depth at 200° F. Curve 874 is thetheoretical calculation at the outer surface of the carbon steel as afunction of skin depth at 500° F. Curve 876 is the theoreticalcalculation at the outer surface of the carbon steel as a function ofskin depth at 800° F. Curve 878 is the theoretical calculation at theouter surface of the carbon steel as a function of skin depth at 1100°F.

The skin depths obtained from the intersections of the same temperaturecurves in FIG. 148 were input into the equations described above and theAC resistance per unit length was calculated. The total AC resistance ofthe entire heater, including that of the canister, was subsequentlycalculated. A comparison between the experimental and numerical(calculated) results is shown in FIG. 149 for currents of 300 A(experimental data 880 and numerical curve 882), 400 A (experimentaldata 884 and numerical curve 886), and 500 A (experimental data 888 andnumerical curve 890). Though the numerical results exhibit a steepertrend than the experimental results, the theoretical model captures theclose bunching of the experimental data, and the overall values arequite reasonable given the assumptions involved in the theoreticalmodel. For example, one assumption involved the use of a permeabilityderived from a quasistatic B-H curve to treat a dynamic system.

One feature of the theoretical model describing the flow of alternatingcurrent in the three-part temperature limited heater is that the ACresistance does not fall off monotonically with increasing skin depth.FIG. 150 shows the AC resistance (mΩ) per foot of the heater element asa function of skin depth (in.) at 1100° F. calculated from thetheoretical model. The AC resistance may be maximized by selecting theskin depth that is at the peak of the non-monotonical portion of theresistance versus skin depth profile (for example, at about 0.23 in. inFIG. 150).

FIG. 151 shows the power generated per unit length (W/ft.) in eachheater component (curve 892 (copper core), curve 894 (carbon steel),curve 896 (347H outer layer), and curve 898 (total)) versus skin depth(in.). As expected, the power dissipation in the 347H falls off whilethe power dissipation in the copper core increases as the skin depthincreases. The maximum power dissipation in the carbon steel occurs atthe skin depth of about 0.23 in. and is expected to correspond to theminimum in the power factor, shown in FIG. 145. The current density inthe carbon steel behaves like a damped wave of wavelength λ=2πδ and theeffect of this wavelength on the boundary conditions at thecopper/carbon steel and carbon steel/347H interface may be behind thestructure in FIG. 150. For example, the local minimum in AC resistanceis close to the value at which the thickness of the carbon steel layercorresponds to λ/4.

Formulae may be developed that describe the shapes of the AC resistanceversus temperature profiles of temperature limited heaters for use insimulating the performance of the heaters in a particular embodiment.The data in FIGS. 143 and 144 show that the resistances initially riselinearly, then drop off increasingly steeply towards the DC lines. Theresistance versus temperature profile of each heater can be describedby:

R _(AC) =A _(AC) +B _(AC) T;T<<T _(C); and  (64)

R _(AC) =R _(DC) =A _(DC) +B _(DC) T;T>>T _(C).  (65)

Note that A_(DC) and B_(DC) are independent of current, while A_(AC) andB_(AC) depend on the current. Choosing as a form crossing over betweenEQNS. 64 and 65 results in the following expression for R_(AC):

$\begin{matrix}{{{R_{AC} = {{{\frac{1}{2}\left\{ {1 + {\tanh \left\{ {\alpha \left( {T_{0} - T} \right)} \right\}}} \right\} \left\{ {A_{AC} + {B_{AC}T}} \right\}} + {\frac{1}{2}\left\{ {1 - {\tanh \left\{ {\alpha \left( {T_{0} - T} \right)} \right\}}} \right\} \left\{ {A_{DC} + {B_{DC}T}} \right\} T}} \leq T_{0}}};{and}}{R_{AC} = {{{\frac{1}{2}\left\{ {1 + {\tanh \left\{ {\beta \left( {T_{0} - T} \right)} \right\}}} \right\} \left\{ {A_{AC} + {B_{AC}T}} \right\}} + {\frac{1}{2}\left\{ {1 - {\tanh \left\{ {\beta \left( {T_{0} - T} \right)} \right\}}} \right\} \left\{ {A_{DC} + {B_{DC}T}} \right\} T}} \geq {T_{0}.}}}} & (66)\end{matrix}$

Since A_(AC) and B_(AC) are functions of current, then:

A _(AC) =A _(AC) ⁽⁰⁾ +A _(AC) ⁽¹⁾ I;B _(AC) =B _(AC) ⁽⁰⁾ +B _(AC) ⁽¹⁾I.  (67)

The parameter α is also a function of current, and exhibits thequadratic dependence:

α=α₀+α₁ I+α ₂ I ².  (68)

The parameters β, T₀, as well as A_(DC) and B_(DC) are independent ofcurrent. Values of the parameters for the copper/carbon steel/347Hheaters in the above experiments are listed in TABLE 2.

TABLE 2 copper/carbon Parameter Unit steel/347H A_(DC) mΩ 0.6783 B_(DC)mΩ/° F.  6.53 × 10⁻⁴ A_(AC) ⁽⁰⁾ mΩ 3.6358 A_(AC) ⁽¹⁾ mΩ/A −1.247 × 10⁻³B_(AC) ⁽⁰⁾ mΩ/° F. 2.3575 × 10⁻³ B_(AC) ⁽¹⁾ mΩ/(° F. A)  −2.28 × 10⁻⁷ α₀1/° F. 0.2 α₁ 1/(° F. A)  −7.9 × 10⁻⁴ α₂ 1/(° F. A²)    8 × 10⁻⁷ β 1/°F. 0.017 T₀ ° F. 1350

FIGS. 152A-C compare the results of the theoretical calculations inEQNS. 66-68 with the experimental data at 300 A (FIG. 152A), 400 A (FIG.152B) and 500 A (FIG. 152C). FIG. 152A depicts resistance (mΩ) versustemperature (° C.) at 300 A. Data 900 is the experimental data at 300 A.Curve 902 is the theoretical calculation at 300 A. Curve 904 is a plotof resistance versus temperature at 10 A DC. FIG. 152B depictsresistance (mΩ) versus temperature (° C.) at 400 A. Data 906 is theexperimental data at 400 A. Curve 908 is the theoretical calculation at400 A. Curve 910 is a plot of resistance versus temperature at 10 A DC.FIG. 152C depicts resistance (mΩ) versus temperature (° C.) at 500 A.Data 912 is the experimental data at 500 A. Curve 914 is the theoreticalcalculation at 500 A. Curve 916 is a plot of resistance versustemperature at 10 A DC. Note that, to obtain the resistance per foot,for example, in simulation work, the resistances given by thetheoretical calculations must be divided by six.

A numerical simulation (FLUENT available from Fluent USA, Lebanon, N.H.)was used to compare operation of temperature limited heaters with threeturndown ratios. The simulation was done for heaters in an oil shaleformation (Green River oil shale). Simulation conditions were:

-   -   61 m length conductor-in-conduit Curie heaters (center conductor        (2.54 cm diameter), conduit outer diameter 7.3 cm)    -   downhole heater test field richness profile for an oil shale        formation    -   16.5 cm (6.5 inch) diameter wellbores at 9.14 m spacing between        wellbores on triangular spacing    -   200 hours power ramp-up time to 820 watts/m initial heat        injection rate    -   constant current operation after ramp up    -   Curie temperature of 720.6° C. for heater    -   formation will swell and touch the heater canisters for oil        shale richnesses at least 0.14 L/kg (35 gals/ton)

FIG. 153 displays temperature (° C.) of a center conductor of aconductor-in-conduit heater as a function of formation depth (m) for atemperature limited heater with a turndown ratio of 2:1. Curves 918-940depict temperature profiles in the formation at various times rangingfrom 8 days after the start of heating to 675 days after the start ofheating (918: 8 days, 920: 50 days, 922: 91 days, 924: 133 days, 926:216 days, 928: 300 days, 930: 383 days, 932: 466 days, 934: 550 days,936: 591 days, 938: 633 days, 940: 675 days). At a turndown ratio of2:1, the Curie temperature of 720.6° C. was exceeded after 466 days inthe richest oil shale layers. FIG. 154 shows the corresponding heaterheat flux (W/m) through the formation for a turndown ratio of 2:1 alongwith the oil shale richness (1/kg) profile (curve 942). Curves 944-980show the heat flux profiles at various times from 8 days after the startof heating to 633 days after the start of heating (944: 8 days; 946: 50days; 950: 91 days; 952: 133 days; 954: 175 days; 956: 216 days; 958:258 days; 960: 300 days; 962: 341 days; 964: 383 days; 968: 425 days;970: 466 days; 972: 508 days; 974: 550 days; 976: 591 days; 978: 633days; 980: 675 days). At a turndown ratio of 2:1, the center conductortemperature exceeded the Curie temperature in the richest oil shalelayers.

FIG. 155 displays heater temperature (° C.) as a function of formationdepth (m) for a turndown ratio of 3:1. Curves 982-1004 show temperatureprofiles through the formation at various times ranging from 12 daysafter the start of heating to 703 days after the start of heating (982:12 days; 984: 33 days; 986: 62 days; 988: 102 days; 990: 146 days; 992:205 days; 994: 271 days; 996: 354 days; 998: 467 days; 1000: 605 days;1002: 662 days; 1004: 703 days). At a turndown ratio of 3:1, the Curietemperature was approached after 703 days. FIG. 156 shows thecorresponding heater heat flux (W/m) through the formation for aturndown ratio of 3:1 along with the oil shale richness (1/kg) profile(curve 1006). Curves 1008-1028 show the heat flux profiles at varioustimes from 12 days after the start of heating to 605 days after thestart of heating (1008: 12 days, 1010: 32 days, 1012: 62 days, 1014: 102days, 1016: 146 days, 1018: 205 days, 1020: 271 days, 1022: 354 days,1024: 467 days, 1026: 605 days, 1028: 749 days). The center conductortemperature never exceeded the Curie temperature for the turndown ratioof 3:1. The center conductor temperature also showed a relatively flattemperature profile for the 3:1 turndown ratio.

FIG. 157 shows heater temperature (° C.) as a function of formationdepth (m) for a turndown ratio of 4:1. Curves 1030-1050 show temperatureprofiles through the formation at various times ranging from 12 daysafter the start of heating to 467 days after the start of heating (1030:12 days; 1032: 33 days; 1034: 62 days; 1036: 102 days, 1038: 147 days;1040: 205 days; 1042: 272 days; 1044: 354 days; 1046: 467 days; 1048:606 days, 1050: 678 days). At a turndown ratio of 4:1, the Curietemperature was not exceeded even after 678 days. The center conductortemperature never exceeded the Curie temperature for the turndown ratioof 4:1. The center conductor showed a temperature profile for the 4:1turndown ratio that was somewhat flatter than the temperature profilefor the 3:1 turndown ratio. These simulations show that the heatertemperature stays at or below the Curie temperature for a longer time athigher turndown ratios. For this oil shale richness profile, a turndownratio of at least 3:1 may be desirable.

Simulations have been performed to compare the use of temperaturelimited heaters and non-temperature limited heaters in an oil shaleformation. Simulation data was produced for conductor-in-conduit heatersplaced in 16.5 cm (6.5 inch) diameter wellbores with 12.2 m (40 feet)spacing between heaters using a formation simulator (for example, STARSfrom Computer Modeling Group, LTD., Houston, Tex.) and a near wellboresimulator (for example, ABAQUS from ABAQUS, Inc., Providence, R.I.).Standard conductor-in-conduit heaters included 304 stainless steelconductors and conduits. Temperature limited conductor-in-conduitheaters included a metal with a Curie temperature of 760° C. forconductors and conduits. Results from the simulations are depicted inFIGS. 158-160.

FIG. 158 depicts heater temperature (° C.) at the conductor of aconductor-in-conduit heater versus depth (m) of the heater in theformation for a simulation after 20,000 hours of operation. Heater powerwas set at 820 watts/meter until 760° C. was reached, and the power wasreduced to inhibit overheating. Curve 1052 depicts the conductortemperature for standard conductor-in-conduit heaters. Curve 1052 showsthat a large variance in conductor temperature and a significant numberof hot spots developed along the length of the conductor. Thetemperature of the conductor had a minimum value of 490° C. Curve 1054depicts conductor temperature for temperature limitedconductor-in-conduit heaters. As shown in FIG. 158, temperaturedistribution along the length of the conductor was more controlled forthe temperature limited heaters. In addition, the operating temperatureof the conductor was 730° C. for the temperature limited heaters. Thus,more heat input would be provided to the formation for a similar heaterpower using temperature limited heaters.

FIG. 159 depicts heater heat flux (W/m) versus time (yrs) for theheaters used in the simulation for heating oil shale. Curve 1056 depictsheat flux for standard conductor-in-conduit heaters. Curve 1058 depictsheat flux for temperature limited conductor-in-conduit heaters. As shownin FIG. 159, heat flux for the temperature limited heaters wasmaintained at a higher value for a longer period of time than heat fluxfor standard heaters. The higher heat flux may provide more uniform andfaster heating of the formation.

FIG. 160 depicts cumulative heat input (kJ/m) (kilojoules per meter)versus time (yrs) for the heaters used in the simulation for heating oilshale. Curve 1060 depicts cumulative heat input for standardconductor-in-conduit heaters. Curve 1062 depicts cumulative heat inputfor temperature limited conductor-in-conduit heaters. As shown in FIG.160, cumulative heat input for the temperature limited heaters increasedfaster than cumulative heat input for standard heaters. The fasteraccumulation of heat in the formation using temperature limited heatersmay decrease the time needed for retorting the formation. Onset ofretorting of the oil shale formation may begin around an averagecumulative heat input of 1.1×10⁸ kJ/meter. This value of cumulative heatinput is reached around 5 years for temperature limited heaters andbetween 9 and 10 years for standard heaters.

Calculations may be made to determine the effect of a thermallyconductive fluid in an annulus of a temperature limited heater. Theequations below (EQNS. 69-79) are used to relate a heater center rodtemperature in a heated section to a conduit temperature adjacent to theheater center rod. In this example, the heater center rod is a 347Hstainless steel tube with outer radius b. The conduit is made of 347 Hstainless steel and has inner radius R. The center heater rod and theconduit are at uniform temperatures T_(H) and T_(c), respectively. T_(c)is maintained constant and a constant heat rate, Q, per unit length issupplied to the center heater rod. T_(H) is the value at which the rateof heat per unit length transferred to the conduit by conduction andradiation balances the rate of heat generated, Q. Conduction across agap between the center heater rod and inner surface of the conduit isassumed to take place in parallel with radiation across the gap. Forsimplicity, radiation across the gap is assumed to be radiation across avacuum. The equations are thus:

Q=Q _(C) +Q _(R);  (69)

where Q_(C) and Q_(R) represent the conductive and radiative componentsof the heat flux across the gap. Denoting the inner radius of theconduit by R, conductive heat transport satisfies the equation:

$\begin{matrix}{{Q_{C} = {{- 2}\pi \; r\; k_{g}\frac{T}{r}}};{b \leq r \leq R};} & (70)\end{matrix}$

subject to the boundary conditions:

T(b)=T _(H) ;T(R)=T _(C).  (71)

The thermal conductivity of the gas in the gap, k_(g), is well describedby the equation:

k _(g) =a _(g) +b _(g) T  (72)

Substituting EQN. 72 into EQN. 70 and integrating subject to theboundary conditions in EQN. 71 gives:

$\begin{matrix}{{{{\frac{Q_{C}}{2\pi}{\ln \left( {R/b} \right)}} = {k_{g}^{({eff})}\left( {T_{H} - T_{C}} \right)}};}{with}} & (73) \\{k_{g}^{({eff})} = {a_{g} + {\frac{1}{2}{{b_{g}\left( {T_{H} + T_{C}} \right)}.}}}} & (74)\end{matrix}$

The rate of radiative heat transport across the gap per unit length,Q_(R), is given by:

Q _(R)=2πσbε _(R)ε_(bR) {T _(H) ⁴ −T _(C) ⁴};  (75)

where

ε_(bR)=ε_(b)/{ε_(R)+(b/R)ε_(b)(1−ε_(R))}.  (76)

In EQNS. 75 and 76, ε_(b) and ε_(R) denote the emissivities of thecenter heater rod and inner surface of the conduit, respectively, and σis the Stefan-Boltzmann constant.

Substituting EQNS. 73 and 75 back into EQN. 69, and rearranging gives:

$\begin{matrix}{\frac{Q}{2\pi} = {\frac{k_{g}^{eff}\left( {T_{H} - T_{C}} \right)}{\ln \; \left( {R/b} \right)} + {\sigma \; b\; ɛ_{R}ɛ_{b\; R}{\left\{ {T_{H}^{4} - T_{C}^{4}} \right\}.}}}} & (77)\end{matrix}$

To solve EQN. 77, t is denoted as the ratio of radiative to conductiveheat flux across the gap:

$\begin{matrix}{t = {\frac{\sigma \; b\; ɛ_{R}ɛ_{b\; R}\left\{ {T_{H}^{2} + T_{C}^{2}} \right\} \left( {T_{H} + T_{C}} \right){\ln \left( {R/b} \right)}}{k_{g}^{eff}}.}} & (78)\end{matrix}$

Then EQN. 77 can be written in the form:

$\begin{matrix}{\frac{Q}{2\pi} = {\frac{k_{g}^{eff}\left( {T_{H} - T_{C}} \right)}{\ln \; \left( {R/b} \right)}{\left\{ {1 + t} \right\}.}}} & (79)\end{matrix}$

EQNS. 79 and 77 are solved iteratively for T_(H) given Q and T_(C). Thenumerical values of the parameters σ, a_(g), and b_(g) are given inTABLE 3. A list of heater dimensions are given in TABLE 4.

The emissivities ε_(S) and ε_(a) may be taken to be in the range0.4-0.8.

TABLE 3 Material Parameters Used in the Calculations Parameter σ a_(g)(air) b_(g) (air) a_(g) (He) b_(g) (He) Unit Wm⁻²K⁻⁴ Wm⁻¹K⁻¹ Wm⁻¹K⁻²Wm⁻¹K⁻¹ Wm⁻¹K⁻² Value 5.67 × 0.01274 5.493 × 0.07522 2.741 × 10⁻⁸ 10⁻⁵10⁻⁴

TABLE 4 Set of Heater Dimensions Dimension Inches Meters Heater rodouter radius b ½ × 0.75 9.525 × 10⁻³ Conduit inner radius R ½ × 1.7712.249 × 10⁻²

FIG. 161 shows heater rod temperature (° C.) as a function of the power(W/m) generated within the heater rod for a base case in which both theheater rod and conduit emissivities were 0.8, and a low emissivity casein which the heater rod emissivity was lowered to 0.4. The conduittemperature was set at 260° C. Cases in which the annular space isfilled with air and with helium are compared in FIG. 161. Plot 1064 isfor the base case in air. Plot 1066 is for the base case in helium. Plot1068 is for the low emissivity case in air. Plot 1070 is for the lowemissivity case in helium. FIGS. 162-168 repeat the same cases forconduit temperatures of 315° C. to 649° C. inclusive, with incrementalsteps of 55° C. in each figure. Note that the temperature scale in FIGS.166-168 is offset by 111° C. with respect to the scale in FIGS. 161-165.FIGS. 161-168 show that helium in the annular space, which has a higherthermal conductivity than air, reduces the rod temperature for similarpower generation.

FIG. 169 shows a plot of center heater rod (with 0.8 emissivity)temperature (vertical axis) versus conduit temperature (horizontal axis)for various heater powers with air or helium in the annulus. FIG. 170shows a plot of center heater rod (with 0.4 emissivity) temperature(vertical axis) versus conduit temperature (horizontal axis) for variousheater powers with air or helium in the annulus. Plots 1072 are for airand a heater power of 500 W/m. Plots 1074 are for air and a heater powerof 833 W/m. Plots 1076 are for air and a heater power of 1167 W/m. Plots1078 are for helium and a heater power of 500 W/m. Plots 1080 are forhelium and a heater power of 833 W/m. Plots 1082 are for helium and aheater power of 1167 W/m. FIGS. 169 and 170 show that helium in theannular space, as compared to air in the annulus, reduces temperaturedifference between the heater and the canister.

FIG. 171 depicts spark gap breakdown voltages (V) versus pressure (atm)at different temperatures for a conductor-in-conduit heater with air inthe annulus. FIG. 172 depicts spark gap breakdown voltages (V) versuspressure (atm) at different temperatures for a conductor-in-conduitheater with helium in the annulus. FIGS. 171 and 172 show breakdownvoltages for a conductor-in-conduit heater with a 2.5 cm diameter centerconductor and a 7.6 cm gap to the inner radius of the conduit. Plot 1084is for a temperature of 300 K. Plot 1086 is for a temperature of 700 K.Plot 1088 is for a temperature of 1050 K. 480 V RMS is shown as atypical applied voltage. FIGS. 171 and 172 show that helium has a sparkgap breakdown voltage smaller than the spark gap breakdown voltage forair at 1 atm. Thus, the pressure of helium may need to be increased toachieve spark gap breakdown voltages on the order of breakdown voltagesfor air.

FIG. 173 depicts leakage current (mA) (milliamps) versus voltage (V) foralumina and silicon nitride centralizers at selected temperatures.Leakage current was measured between a conductor and a conduit of a 0.91m conductor-in-conduit section with two centralizers. Theconductor-in-conduit was placed horizontally in a furnace. Plot 1090depicts data for alumina centralizers at a temperature of 760° C. Plot1092 depicts data for alumina centralizers at a temperature of 815° C.Plot 1094 depicts data for gas pressure sintered reaction bonded siliconnitride centralizers at a temperature of 760° C. Plot 1096 depicts datafor gas pressure sintered reaction bonded silicon nitride at atemperature of 871° C. FIG. 173 shows that the leakage current ofalumina increases substantially from 760° C. to 815° C. while theleakage current of gas pressure sintered reaction bonded silicon nitrideremains relatively low from 760° C. to 871° C.

FIG. 174 depicts leakage current (mA) versus temperature (° C.) for twodifferent types of silicon nitride. Plot 1098 depicts leakage currentversus temperature for highly polished, gas pressure sintered reactionbonded silicon nitride. Plot 1100 depicts leakage current versustemperature for doped densified silicon nitride. FIG. 174 shows theimproved leakage current versus temperature characteristics of gaspressure sintered reaction bonded silicon nitride versus doped siliconnitride.

Using silicon nitride centralizers allows for smaller diameter andhigher temperature heaters. A smaller gap is needed between a conductorand a conduit because of the excellent electrical characteristics of thesilicon nitride. Silicon nitride centralizers may allow higher operatingvoltages (for example, up to at least 1500 V, 2000 V, 2500 V, or 15 kV)to be used in heaters due to the electrical characteristics of thesilicon nitride. Operating at higher voltages allows longer lengthheaters to be utilized (for example, lengths up to at least 500 m, 1000m, or 1500 m at 2500 V). In some embodiments, boron nitride is used as amaterial for centralizers or other electrical insulators. Boron nitrideis a better thermal conductor and has better electrical properties thansilicon nitride. Boron nitride does not absorb water readily (boronnitride is substantially non-hygroscopic). Boron nitride is available inat least a hexagonal form and a face centered cubic form. A hexagonalcrystalline formation of boron nitride has several desired properties,including, but not limited to, a high thermal conductivity and a lowfriction coefficient.

A downhole heater assembly may include 5, 10, 20, 40, or more heaterscoupled together. For example, a heater assembly may include between 10and 40 heaters. Heaters in a downhole heater assembly may be coupled inseries. In some embodiments, heaters in a heater assembly may be spacedfrom about 7.6 m to about 30.5 m apart. For example, heaters in a heaterassembly may be spaced about 15 m apart. Spacing between heaters in aheater assembly may be a function of heat transfer from the heaters tothe formation. For example, a spacing between heaters may be chosen tolimit temperature variation along a length of a heater assembly toacceptable limits. A heater assembly may advantageously providesubstantially uniform heating over a relatively long length of anopening in a formation. Heaters in a heater assembly may include, butare not limited to, electrical heaters (e.g., insulated conductorheaters, conductor-in-conduit heaters, pipe-in-pipe heaters), flamelessdistributed combustors, natural distributed combustors, and/oroxidizers. In some embodiments, heaters in a downhole heater assemblymay include only oxidizers.

FIG. 175 depicts a schematic of an embodiment of downhole oxidizerassembly 1102 including oxidizers 1104. In some embodiments, oxidizerassembly 1102 may include oxidizers 1104 and flameless distributedcombustors. Oxidizer assembly 1102 may be lowered into an opening in aformation and positioned as desired. In some embodiments, a portion ofthe opening in the formation may be substantially parallel to thesurface of the Earth. In some embodiments, the opening of the formationmay be otherwise angled with respect to the surface of the Earth. In anembodiment, the opening may include a significant vertical portion and aportion otherwise angled with respect to the surface of the Earth. Incertain embodiments, the opening may be a branched opening. Oxidizerassemblies may branch from common fuel and/or oxidizer conduits in acentral portion of the opening.

Fuel 1106 may be supplied to oxidizers 1104 through fuel conduit 1108.In some embodiments, fuel conduit 1108 may include a catalytic surface(e.g., a catalytic inner surface) to decrease an ignition temperature offuel 1106. Oxidizing fluid 1110 may be supplied to oxidizer assembly1102 through oxidizer conduit 1112. In some embodiments, fuel conduit1108 and/or oxidizers 1104 may be positioned concentrically, orsubstantially concentrically, in oxidizer conduit 1112. In someembodiments, fuel conduit 1108 and/or oxidizers 1104 may be arrangedother than concentrically with respect to oxidizer conduit 1112. Incertain branched opening embodiments, fuel conduit 1108 and/or oxidizerconduit 1112 may have a weld or coupling to allow placement of oxidizerassemblies 1102 in branches of the opening.

An ignition source may be positioned in or proximate oxidizers 1104 toinitiate combustion. In some embodiments, an ignition source may heatthe fuel and/or the oxidizing fluid supplied to a particular heater to atemperature sufficient to support ignition of the fuel. The fuel may beoxidized with the oxidizing fluid in oxidizers 1104 to generate heat.Oxidation products may mix with oxidizing fluid downstream of the firstoxidizer in oxidizer conduit 1112. Exhaust gas 1114 may includeunreacted oxidizing fluid and unreacted fuel as well as oxidationproducts. In some embodiments, a portion of exhaust gas 1114 may beprovided to downstream oxidizer 1104. In some embodiments, a portion ofexhaust gas 1114 may return to the surface through outer conduit 1116.As the exhaust gas returns to the surface through outer conduit 1116,heat from exhaust gas 1114 may be transferred to the formation.Returning exhaust gas 1114 through outer conduit 1116 may providesubstantially uniform heating along oxidizer assembly 1102 due to heatfrom the exhaust gas integrating with the heat provided from individualoxidizers of the oxidizer assembly. In some embodiments, oxidizing fluid1110 may be introduced through outer conduit 1116 and exhaust gas 1114may be returned through oxidizer conduit 1112. In certain embodiments,heat integration may occur along an extended vertical portion of anopening.

Fuel supplied to an oxidizer assembly may include, but is not limitedto, hydrogen, methane, ethane, and/or other hydrocarbons. In certainembodiments, fuel used to initiate combustion may be enriched todecrease the temperature required for ignition. In some embodiments,hydrogen (H₂) or other hydrogen rich fluids may be used to enrich fuelinitially supplied to the oxidizers. After ignition of the oxidizers,enrichment of the fuel may be stopped.

After oxidizer ignition, steps may be taken to reduce coking of fuel inthe fuel conduit. For example, steam may be added to the fuel to inhibitcoking in the fuel conduit. In some embodiments, the fuel may be methanethat is mixed with steam in a molar ratio of up to 1:1. In someembodiments, coking may be inhibited by decreasing a residence time offuel in the fuel conduit. In some embodiments, coking may be inhibitedby insulating portions of the fuel conduit that pass through hightemperature zones proximate oxidizers.

Oxidizing fluid supplied to an oxidizer assembly may include, but is notlimited to, air, oxygen enriched air, and/or hydrogen peroxide.Depletion of oxygen in oxidizing fluid may occur toward a terminal endof an oxidizer assembly. In an embodiment, a flow of oxidizing fluid maybe increased (e.g., by using compression to provide excess oxidizingfluid) such that sufficient oxygen is present for operation of theterminal oxidizer. In some embodiments, oxidizing fluid may be enrichedby increasing an oxygen content of the oxidizing fluid prior tointroduction of the oxidizing fluid to the oxidizers. Oxidizing fluidmay be enriched by methods including, but not limited to, adding oxygento the oxidizing fluid, adding an additional oxidant such as hydrogenperoxide to the oxidizing fluid (e.g., air) and/or flowing oxidizingfluid through a membrane that allows preferential diffusion of oxygen.

FIG. 176 depicts an embodiment of ignition system 1118 positioned in across-sectional representation of an oxidizer. Ignition system 1118 maybe positioned in guide tube 1120. Ignition system 1118 may include glowplug 1122, insulator 1124, transition piece 1126, follower 1128, andcable 1130. Glow plug 1122 may be a Kyocera glow available from KyoceraCorporation (Kyoto, Japan). A length of ignition system 1118 from an endof follower 1128 to an end of glow plug 1122 may be about 5 cm to about20 cm. In an embodiment, a length of ignition system 1118 from an end offollower 1128 to an end of glow plug 1122 may be about 9.14 cm.Insulator 1124 may be a ceramic insulator made of alumina, boronnitride, silicon nitride, or other ceramic material. When electricity issupplied to ignition system 1118 through cable 1130, a tip of glow plug1122 may reach a temperature sufficient to ignite a fuel and oxidizingfluid mixture in oxidizer 1104. Cable 1130 may be a mineral insulatedcable. A weld (e.g., a gas tungsten argon weld) may be formed where anouter metal layer of cable 1130 enters follower 1128.

FIG. 177 depicts a cross-sectional representation of an embodiment oftransition piece 1126. Transition piece 1126 may include ground wire1132, ceramic 1134, guide tube 1136, and metal body 1138. Ground wire1132 may electrically couple metal body 1138 to a first terminal of aglow plug. Guide tube 1136 may allow a conductor of a cable to beelectrically coupled to a second terminal of the glow plug. Guide tube1136 and ground wire 1132 may be welded to terminals of the glow plug(e.g., using gas tungsten argon welding). In some embodiments, metalbody 1138 may include threading 1140. Threading 1140 may mate withthreading of a follower. In some embodiments, the metal body may becoupled to the follower by a crush fit, friction fit, interference fit,or other type of coupling.

FIG. 178 depicts a cross-sectional representation of ignition system1118 without a cable. Ignition system 1118 without a cable may beassembled and treated (e.g., fired) prior to insertion of a cable.Preform 1142 may be positioned between follower 1128 and transitionpiece 1126. Preform 1142 may be made of alumina, silicon nitride, boronnitride, or other ceramic material. Preform 1142 may direct a conductorof a cable to guide tube 1136 of transition piece 1126 when theconductor is being coupled to glow plug 1122. Preform 1142 may supportthe conductor and inhibit the conductor from establishing an electricalconnection with follower 1128 or transition piece 1126. Guide tube 1136may direct the conductor of the cable to a terminal of glow plug 1122.When preform 1142 is positioned between follower 1128 and transitionpiece 1126, the follower may be welded to the transition piece.Insulator 1124 may electrically isolate glow plug 1122. Insulator 1124may be coupled to transition piece 1126 and glow plug 1122 using hightemperature cement 1144.

In certain embodiments, fuel may be reacted with catalytic material(e.g., palladium, platinum, or other known oxidation catalysts) toprovide an ignition source in a downhole oxidizer assembly. The catalystmaterial may be, but is not limited to molybdenum, molybdenum oxides,nickel, nickel oxides, vanadium, vanadium oxides, chromium, chromiumoxides, manganese, manganese oxides, palladium, palladium oxides,platinum, platinum oxides, rhodium, rhodium oxides, iridium, iridiumoxides, or combinations thereof. FIG. 179 depicts catalytic material1146 proximate oxidizer 1104 in a downhole oxidizer assembly. Tubing1148 may supply fuel 1106 (e.g., H₂) through branches 1150 to one ormore orifices 1152 proximate catalytic material 1146. The fuel suppliedto catalytic material 1146 may react with the catalytic material atambient or close to downhole conditions. Fuel supplied to catalyticmaterial 1146 may cause the catalytic material to glow or flame. Thecontent and quantity of the fuel supplied to the catalytic material maybe controlled to inhibit development of a flame. A flame may beinhibited to prevent equipment and catalyst degradation due to excessiveheat. Glowing catalytic material 1146 may ignite a mixture in oxidizer1104 proximate the catalytic material. In some embodiments, oxidizersand catalytic material 1146 may be placed in series along a fuel conduitin an oxidizer assembly in any order. Fuel supplied to the catalyticmaterial may be controlled by a valve or valve system so that fuel issupplied to the catalytic material only when the fuel is needed.

FIG. 180 depicts an embodiment of catalytic igniter system 1154.Catalytic igniter system 1154 may include oxidant line 1156, fuel line1158, manifold 1160, coaxial tubing 1162, mixing zone 1164, shield 1166,and/or catalytic material 1146. In an embodiment, oxidant line 1156 andfuel line 1158 may be 0.48 cm tubing. Oxidant line 1156 may carry air oranother oxidizing fluid. Fuel line 1158 may carry hydrogen or anotherfuel. In certain embodiments, an oxidizing fluid to fuel ratio may rangefrom about 0.8 to 2. In an embodiment, an oxidizing fluid to fuel ratiomay be about 1.2 (e.g., 0.156 L/s air and 0.127 L/s hydrogen). Manifold1160 may direct fuel down a center conduit (e.g., a 0.48 cm centerconduit) and oxidant in an annulus between the center conduit and anouter conduit (e.g., a 0.79 cm outer conduit). The oxidant and fuel maymix in mixing zone 1164 before flowing to catalytic material 1146.Catalytic material 1146 may be a packed bed in shield 1166. The packedbed of catalytic material 1146 may be from about 0.64 cm to about 5 cmlong. Shield 1166 may have openings that allow reaction product to exitfrom catalytic igniter system 1154.

FIG. 181 depicts a cross-sectional representation of an embodiment ofoxidizer 1104. Oxidizer 1104 may include igniter guide tube 1168.Catalytic igniter system 1154, depicted in FIG. 180, may be positionedin igniter guide tube 1168. In some embodiments, shield 1166, whichencloses the catalytic material of the catalytic igniter system, mayextend beyond an end of igniter guide tube 1168. When oxidizer and fuelare supplied through oxidant line 1156 and fuel line 1158, a temperatureof shield 1166 may rise to a temperature sufficient to initializecombustion of a fuel and oxidizing fluid mixture supplied to oxidizer1104. Fuel may be supplied to oxidizer 1104 through fuel conduit 1108.Oxidizing fluid may enter oxidizer 1104 through oxidizer orifices 1170.

In some in situ conversion process embodiments, a closed loopcirculation system is used to heat the formation. FIG. 182 depicts aschematic representation of a system for heating a formation using aclosed loop circulation system. The system may be used to heathydrocarbons that are relatively deep in the ground and that arerelatively large in extent. In some embodiments, the hydrocarbons may be100 m, 200 m, 300 m or more below the surface. The closed loopcirculation system may also be used to heat hydrocarbons that are not asdeep in the ground. The hydrocarbons may extend lengthwise up to 500 m,750 m, 1000 m, or more. The closed loop circulation system may becomeeconomically viable in formations where the length of the hydrocarbonsto be treated is long compared to the thickness of the overburden. Theratio of the hydrocarbon extent to be heated by heaters to theoverburden thickness may be at least 3, at least 5, or at least 10.

In some embodiments, heaters 382 may be formed in the formation bydrilling a first wellbore and then drilling a second wellbore thatconnects with the first wellbore so that piping placed in the wellboresforms a U-shaped heater 382. Heaters 382 are connected to heat transferfluid circulation system 1172 by piping. Gas at high pressure may beused as the heat transfer fluid in the closed loop circulation system.In some embodiments, the heat transfer fluid is carbon dioxide. Carbondioxide is chemically stable at the required temperatures and pressuresand has a relatively high molecular weight that results in a highvolumetric heat capacity. Other fluids such as steam, air, and/ornitrogen may also be used. The pressure of the heat transfer fluidentering the formation may be 3000 kPa or higher. The use of highpressure heat transfer fluid allows the heat transfer fluid to have agreater density, and therefore a greater capacity to transfer heat.Also, the pressure drop across the heaters is less for a system wherethe heat transfer fluid enters the heaters at a first pressure for agiven mass flow rate than when the heat transfer fluid enters theheaters at a second pressure at the same mass flow rate when the firstpressure is greater than the second pressure.

Heat transfer fluid circulation system 1172 may include furnace 1174,first heat exchanger 1176, second heat exchanger 1178, and compressor1180. Furnace 1174 heats the heat transfer fluid to a high temperature.In the embodiment depicted in FIG. 182, furnace 1174 heats the heattransfer fluid to a temperature in a range from about 700° C. to about920° C., from about 770° C. to about 870° C., or from about 800° C. toabout 850° C. In an embodiment, furnace 1174 heats the heat transferfluid to a temperature of about 820° C. The heat transfer fluid flowsfrom furnace 1174 to heaters 382. Heat transfers from heaters 382 toformation 314 adjacent to the heaters. The temperature of the heattransfer fluid exiting formation 314 may be in a range from about 350°C. to about 580° C., from about 400° C. to about 530° C., or from about450° C. to about 500° C. In an embodiment, the temperature of the heattransfer fluid exiting formation 314 is about 480° C. The metallurgy ofthe piping used to form heat transfer fluid circulation system 1172 maybe varied to significantly reduce costs of the piping. High temperaturesteel may be used from furnace 1174 to a point where the temperature issufficiently low so that less expensive steel can be used from thatpoint to first heat exchanger 1176. Several different steel grades maybe used to form the piping of heat transfer fluid circulation system1172.

Heat transfer fluid from furnace 1174 of heat transfer fluid circulationsystem 1172 passes through overburden 370 of formation 314 tohydrocarbon layer 254. Portions of heaters 382 extending throughoverburden 370 may be insulated. Inlet portions of heaters 382 inhydrocarbon layer 254 may have tapering insulation to reduce overheatingof the hydrocarbon layer near the inlet of the heater into thehydrocarbon layer.

After exiting formation 314, the heat transfer fluid passes throughfirst heat exchanger 1176 and second heat exchanger 1178 to compressor1180. First heat exchanger 1176 transfers heat between heat transferfluid exiting formation 314 and heat transfer fluid exiting compressor1180 to raise the temperature of the heat transfer fluid that entersfurnace 1174 and reduce the temperature of the fluid exiting formation314. Second heat exchanger 1178 further reduces the temperature of theheat transfer fluid before the heat transfer fluid enters compressor1180.

FIG. 183 depicts a plan view of an embodiment of wellbore openings inthe formation that is to be heated using the closed loop circulationsystem. Heat transfer fluid entries 1182 into formation 314 alternatewith heat transfer fluid exits 1184. Alternating heat transfer fluidentries 1182 with heat transfer fluid exits 1184 may allow for moreuniform heating of the hydrocarbons in formation 314.

In this patent, certain U.S. patents, U.S. patent applications, andother materials (e.g., articles) have been incorporated by reference.The text of such U.S. patents, U.S. patent applications, and othermaterials is, however, only incorporated by reference to the extent thatno conflict exists between such text and the other statements anddrawings set forth herein. In the event of such conflict, then any suchconflicting text in such incorporated by reference U.S. patents, U.S.patent applications, and other materials is specifically notincorporated by reference in this patent.

Further modifications and alternative embodiments of various aspects ofthe invention may be apparent to those skilled in the art in view ofthis description. Accordingly, this description is to be construed asillustrative only and is for the purpose of teaching those skilled inthe art the general manner of carrying out the invention. It is to beunderstood that the forms of the invention shown and described hereinare to be taken as the presently preferred embodiments. Elements andmaterials may be substituted for those illustrated and described herein,parts and processes may be reversed, and certain features of theinvention may be utilized independently, all as would be apparent to oneskilled in the art after having the benefit of this description of theinvention. Changes may be made in the elements described herein withoutdeparting from the spirit and scope of the invention as described in thefollowing claims. In addition, it is to be understood that featuresdescribed herein independently may, in certain embodiments, be combined.

Reference Number Table REFERENCE OLD # NEW# region 500 200 200 region502 202 202 region 504 204 204 graphite 506 206 206 barrier wells 517208 208 heat sources 508 210 210 supply lines 510 212 212 productionwells 512 214 214 collection piping 514 216 216 treatment facilities 516218 218 ICP gas pg1 220 220 Unit pg2 222 222 Gs pg3 224 224 Hydr reactorpg4 226 226 Inlet hydrogen pg5 228 228 Heavy byproducts pg6 230 230 Gspg7 232 232 H2 sep unit pg8 234 234 H2 rich stream pg9 236 236 Gs  pg10238 238 Ox unit  pg11 240 240 Inlet stream  pg12 242 242 Gs  pg13 244244 Dehydration unit  pg14 246 246 Pipeline gas  pg15 248 248 Water pg16 250 250 opening 640 252 252 hydrocarbon layer 556 254 254 casing642 256 256 magnetic string 644 258 258 Magnet segments 646 260 260drilling apparatus 648 262 262 conduit 652 264 264 sections 654 266 266Fasteners 656 268 268 magnets 658 270 270 distance 660 272 272 opening650 274 274 magnetic fields 662 276 276 freeze wells 564 278 278 Freezewell casing 572 280 280 inlet conduit 574 282 282 spacers 576 284 284wellcap 578 286 286 cold side conduit 580 288 288 warm side conduit 582290 290 Refrigeration system z1 292 292 treatment area 571 294 294 Hscompressor z2 296 296 Hs condenser z3 298 298 Hs expansion valve z4 300300 heat exchanger z5 302 302 Ls compressor z6 304 304 Ls expansionvalve z7 306 306 Ls heat exchanger z8 308 308 Storage vessel z9 310 310pump  z10 312 312 formation 554 314 314 Storage vessel  z11 316 316 pump z12 318 318 Double Barrier system H8  320 320 contained zone H00 322322 first barrier H02 324 324 second barrier H04 326 326 Inter-barrierzone H06 328 328 Partition H32 330 330 pumping/monitor wells H20 332 332outer zone H18 334 334 fluid bearing zones H10 336 336 impermeable zonesH12 338 338 paths H16 340 340 breach H24 342 342 arrow H28 344 344 fluidH14 346 346 Initial level H21 348 348 Fluid levels H22 350 350 Datasystem cq1 352 352 Laser cq2 354 354 Analyzer cq3 356 356 Fiber opticcable cq4 358 358 Monitor wells cq6 360 360 heater well 566 362 362 Heatinterceptor wells hi1 364 364 production conduit 910 366 366 Collectiondevice 1414 368 368 overburden 560 370 370 packing material 838 372 372riser 1416 374 374 Seal 1417 376 376 pump 1420 378 378 conduit 1418 380380 heater 880 382 382 shroud assembly 1422 384 384 Openings 1423 386386 cool zone 1424 388 388 Conduit 1425 390 390 Wellbore 60 392 392Explosive system 1426 394 394 explosive section 1428 396 396 lean layers558 398 398 rich layers 712 400 400 zones 1430 402 402 Heater 714 404404 Liner 728 406 406 openings 734 408 408 weight 1432 410 410 Ingot 772412 412 chamber 774 414 414 Induction coil 776 416 416 Inner conductor778 418 418 Outer conductor 780 420 420 inner conductor 782 422 422 Weldbead 784 424 424 ferromagnetic section 786 426 426 non-ferromagneticsection 788 428 428 Inner conductor 790 430 430 Electrical insulator 792432 432 Outer conductor 794 434 434 conductive section 796 436 436conductive layer 798 438 438 jacket 800 440 440 insulation layer 802 442442 heating section 804 444 444 Endcap 806 446 446 overburden section808 448 448 conductive layer 810 450 450 ferromagnetic conductor 812 452452 Core 814 454 454 middle conductor 1460 456 456 core couplingmaterial 816 458 458 Inner conductor coupling material 818 460 460Coupling material 820 462 462 support member 1462 464 464 conductor 822466 466 conduit 824 468 468 low resistance sections 826 470 470centralizer 828 472 472 wellhead 830 474 474 power cable 832 476 476sliding connector 834 478 478 overburden casing 836 480 480 Surface orground 840 482 482 conduit 842 484 484 scraper 850 486 486 point 852 488488 centralizer 854 490 490 spring bow 856 492 492 lead-in cable 1472494 494 Connector AP110 496 496 rod AP104 498 498 isolation sub AP102500 500 return cable AP112 502 502 contactor AP106 504 504 liner AP100506 506 strap AP108 508 508 Fiber optic sleeve 1404 510 510 plug 1480512 512 insulated conductor 844 514 514 air gap 848 516 516 Electricalconductor NC600 518 518 NC506 520 520 NC508 522 NC510 524 NC512 526NC500 528 528 NC502 530 530 NC504 532 532 NC505 534 534 NC400 536 536Coiled tubing rig NC404 538 538 straps NC405 540 540 contactor sectionNC402 542 542 centralizers 870 544 544 connector 872 546 546 coupling874 548 548 casing 876 550 550 spacers 878 552 552 leg 882 554 554terminal block 884 556 556 insulation material 886 558 558 termination888 560 560 legs 890 562 562 legs 892 564 564 legs 894 566 566 Heatingelement 898 568 568 contacting element 896 570 570 section 900 572 572opening IW100 574 574 Contactor IW102 576 576 solution 904 578 578wellbore 902 580 580 neutral point 906 582 582 Wellbore IW106 584 584wellbore 908 586 586 Heating/production assembly 1464 588 588 opening1466 590 590 perforated casing 916 592 592 seal assembly 1468 594 594feedthrough 1470 596 596 clamp 1474 598 598 valves 1476 600 600production conduit 1478 602 602 perforations 912 604 604 insulationconduit 914 606 606 Wellbore LS02 608 608 Heated portion LS04 610 610Inner conduit LS06 612 612 Outer conduit LS08 614 614 Reflux seal LS10616 616 Annulus LS12 618 618 Surface LS14 620 620 Utility bundle LS18622 622 Well casing LS16 624 624 Sump LS20 626 626 Pump system LS22 628628 Rod string LS24 630 630 2-phase separator LS26 632 632 Gas/vaporshroud LS30 634 634 Gas vapor vent LS28 636 636 Conduit LS32 638 638Packer/reflux seal assembly LS34 640 640 Lift chamber LS36 642 642 Checkvalve LS38 644 644 Lift gas injection valve LS40 646 646 Crossover portLS42 648 648 Diptube LS44 650 650 Conduit 2 LS33 652 652 Injection gassupply conduit LS46 654 654 Check valve 2 LS39 656 656 Injection gascontrol valve LS48 658 658 Downhole gas injection valve LS50 660 660Check valve/vent assembly LS52 662 662 hot portion 918 664 664 warmportion 920 666 666 overburden portion 922 668 668 coke 924 670 670curve 926 672 672 curve 928 674 674 curve 930 676 676 curve 932 678 678curve 934 680 680 curve 936 682 682 curve 938 684 684 curve 940 686 686curve 942 688 688 curve 944 690 690 curve 946 692 692 curve 948 694 694curve 950 696 696 curve 952 698 698 curve 954 700 700 curve 956 702 702curve 958 704 704 curve 960 706 706 curve 962 708 708 curve 964 710 710curve 966 712 712 curve 968 714 714 curve 970 716 716 curve 972 718 718curve 974 720 720 curve 976 722 722 curve 978 724 724 curve 980 726 726curve 982 728 728 curve 984 730 730 curve 986 732 732 curve 988 734 734curve 990 736 736 curve 992 738 738 curve 994 740 740 curve 996 742 742curve 998 744 744 curve 1000 746 746 curve 1002 748 748 curve 1004 750750 curve 1006 752 752 curve 1008 754 754 Curve 1010 756 756 Curve 1012758 758 Curve 1014 760 760 Curve 1016 762 762 Curve 1018 764 764 Curve1020 766 766 Curve 1022 768 768 Curve 1024 770 770 Curve 1026 772 772Curve 1028 774 774 Curve 1030 776 776 Curve 1032 778 778 Curve 1034 780780 Curve 1036 782 782 Curve 1038 784 784 Curve 1040 786 786 curve GL100788 curve GL102 790 curve GL104 792 curve GL106 794 curve GL108 795curve GL110 796 curve GL112 798 curve GL114 800 curve GL116 802 curve1042 804 804 curve 1044 806 806 curve 1046 808 808 curve 1048 810 810curve 1050 812 812 curve 1052 814 814 curve 1054 816 816 curve 1056 818818 curve 1058 820 820 curve 1060 822 822 curve 1062 824 824 curve 1064826 826 curve 1066 828 828 curve 1068 830 830 curve 1070 832 832 curve1072 834 834 curve 1074 836 836 data NC926 838 data NC928 840 data NC930842 curve NC932 844 data NC934 846 data NC936 848 curve NC938 850 curveNC940 852 curve NC942 854 NC100 856 NC102 858 NC104 860 NC106 862 NC108864 NC110 866 NC112 868 NC114 870 NC116 872 NC118 874 NC120 876 NC122878 NC124 880 NC126 882 NC128 884 NC130 886 NC132 888 NC134 890 NC136892 NC138 894 NC140 896 NC142 898 NC144 900 NC146 902 NC148 904 NC150906 NC152 908 NC154 910 NC156 912 NC158 914 NC160 916 curve 1076 918 918curve 1078 920 920 curve 1080 922 922 curve 1082 924 924 curve 1084 926926 curve 1086 928 928 curve 1088 930 930 curve 1090 932 932 curve 1092934 934 curve 1094 936 936 curve 1096 938 938 curve 1098 940 940 curve1100 942 942 curve 1102 944 944 curve 1104 946 946 curve 1106 950 950curve 1108 952 952 curve 1110 954 954 curve 1112 956 956 curve 1114 958958 curve 1116 960 960 curve 1118 962 962 curve 1120 964 964 curve 1122968 968 curve 1124 970 970 curve 1126 972 972 curve 1128 974 974 curve1130 976 976 curve 1132 978 978 curve 1134 980 980 curve 1136 982 982curve 1138 984 984 curve 1140 986 986 curve 1142 988 988 curve 1144 990990 curve 1146 992 992 curve 1148 994 994 curve 1150 996 996 curve 1152998 998 curve 1154 1000 1000 curve 1156 1002 1002 curve 1158 1004 1004curve 1160 1006 1006 curve 1162 1008 1008 curve 1164 1010 1010 curve1166 1012 1012 curve 1168 1014 1014 curve 1170 1016 1016 curve 1172 10181018 curve 1174 1020 1020 curve 1176 1022 1022 curve 1178 1024 1024curve 1180 1026 1026 curve 1182 1028 1028 curve 1184 1030 1030 curve1186 1032 1032 curve 1188 1034 1034 curve 1190 1036 1036 curve 1192 10381038 curve 1194 1040 1040 curve 1196 1042 1042 curve 1198 1044 1044curve 1200 1046 1046 curve 1202 1048 1048 curve 1204 1050 1050 Curve1206 1052 1052 Curve 1208 1054 1054 Curve 1210 1056 1056 Curve 1212 10581058 Curve 1214 1060 1060 Curve 1216 1062 1062 Plot 1434 1064 1064 14361066 1066 1438 1068 1068 1440 1070 1070 1442 1072 1072 1444 1074 10741446 1076 1076 1448 1078 1078 1450 1080 1080 1452 1082 1082 1454 10841084 1456 1086 1086 1458 1088 1088 Plot 858 1090 1090 Plot 860 1092 1092Plot 862 1094 1094 Plot 864 1096 1096 Plot 866 1098 1098 Plot 868 11001100 Oxidizer assembly 1268 1102 1102 Oxidizer 1270 1104 1104 Fuel 12721106 1106 Fuel conduit 1274 1108 1108 Oxidizing fluid 1276 1110 1110Oxidizer conduit 1278 1112 1112 Exhaust gas 1280 1114 1114 Outer conduit1282 1116 1116 Ignition system 1322 1118 1118 Guide tube 1324 1120 1120Glow plug 1326 1122 1122 Insulator 1328 1124 1124 Transition piece 13301126 1126 follower 1332 1128 1128 cable 1334 1130 1130 Ground wire 13361132 1132 Ceramic 1338 1134 1134 Guide tube 1340 1136 1136 Metal body1342 1138 1138 Threading 1344 1140 1140 Preform 1346 1142 1142 High tempcement 1348 1144 1144 Catalyst 1370 1146 1146 Tubing 1364 1148 1148Branches 1366 1150 1150 Orifices 1368 1152 1152 Catalytic ignitionsystem 1372 1154 1154 Oxidant line 1374 1156 1156 Fuel line 1376 11581158 Manifold 1378 1160 1160 Coaxial tubing 1380 1162 1162 Mixing zone1382 1164 1164 Shield 1384 1166 1166 Igniter guide tube 1386 1168 1168Oxidizer orifices 1310 1170 1170 circulation system q50 1172 1172furnace q51 1174 1174 first heat exchanger q52 1176 1176 second heatexchanger q53 1178 1178 compressor q54 1180 1180 entries q55 1182 1182exits q56 1184 1184

1-536. (canceled)
 537. A heater device comprising: a skin effectcomponent having at least one insulated electrical core conductor inelectrical communication with an adjacent and substantially parallel,elongated ferromagnetic shape having a reduction and localization of thedepth and width of the effective conductor path in the cross-section ofthe ferromagnetic wall; and, an inorganic ceramic insulation component.538. The heater device of claim 537, wherein the inorganic ceramicinsulation component comprises magnesium oxide.
 539. A heating process,comprising the steps of: providing a heater device comprising a skineffect component having at least one insulated electrical core conductorin electrical communication with an adjacent and substantially parallel,elongated ferromagnetic shape having a reduction and localization of thedepth and width of the effective conductor path in the cross-section ofthe ferromagnetic wall and an inorganic ceramic insulation component;and, applying electrical current through the electrical core therebyheating the ferromagnetic shape.